Metal-ligand cooperative iridium complex catalyzed C-alkylation of oxindole and 1,3-dimethylbarbituric acid using alcohols

A general and high-efficiency C-alkylation of oxindoles and barbituric acids has been developed by a Cp∗Ir complex [Cp∗Ir (2,2′-bpyO)(OH)]Na with a bipyridine-based functional ligand. In particular, H2O was selected as the solvent instead of the organic solvent in this catalytic system. Through mild...

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Bibliographic Details
Main Authors: Ao Song, Yunbo Liu, Xuan Jin, Dianrun Su, Zhaopeng Li, Shengsheng Yu, Lingbao Xing, Xiangchao Xu, Rongzhou Wang, Feng Li
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2023-08-01
Series:Green Synthesis and Catalysis
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666554922000746