Synthesis, Crystal Structure and Antimicrobial Activity of A Linear Trinuclear Nickel(II) Complex with Schiff Base Ligand
A new linear trinuclear Schiff base nickel(II) complex, [Ni{NiL(μ2-η1:η1-OAc)(OH2)}2]·H2O, where L is the dianionic form of N,N’-bis(5-chloro-2-hydroxybenzylidene)-1,3-propanediamine (H2L), was synthesized and characterized by elemental analyses, IR spectroscopy, and X-ray single-crystal determinati...
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| Format: | Article |
| Language: | English |
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Slovenian Chemical Society
2019-06-01
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| Series: | Acta Chimica Slovenica |
| Subjects: | |
| Online Access: | https://journals.matheo.si/index.php/ACSi/article/view/5019 |
| _version_ | 1819111360813858816 |
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| author | Cui-Lin Zhang Xiao-Yang Qiu Shu-Juan Liu |
| author_facet | Cui-Lin Zhang Xiao-Yang Qiu Shu-Juan Liu |
| author_sort | Cui-Lin Zhang |
| collection | DOAJ |
| description | A new linear trinuclear Schiff base nickel(II) complex, [Ni{NiL(μ2-η1:η1-OAc)(OH2)}2]·H2O, where L is the dianionic form of N,N’-bis(5-chloro-2-hydroxybenzylidene)-1,3-propanediamine (H2L), was synthesized and characterized by elemental analyses, IR spectroscopy, and X-ray single-crystal determination. There are three bridges across the Ni-Ni atom pairs, involving two phenolate O atoms of a Schiff base ligand, and an O–C–O moiety of a μ2-η1:η1-OAc group. The Ni atoms have octahedral coordination. The acetate bridges linking the central and terminal nickel atoms are mutually trans. The adjacent Ni∙∙∙Ni distances are 3.047(1) Å. The complex was evaluated for its antibacterial (Bacillus subtilis, Staphylococcus aureus, Escherichia coli, and Pseudomonas aeruginosa) and antifungal (Candida albicans and Aspergillus niger) activities by MTT (3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide) method. |
| first_indexed | 2024-12-22T03:56:23Z |
| format | Article |
| id | doaj.art-43d7cddda6b84ad9b0d3f97dbcc20fdc |
| institution | Directory Open Access Journal |
| issn | 1318-0207 1580-3155 |
| language | English |
| last_indexed | 2024-12-22T03:56:23Z |
| publishDate | 2019-06-01 |
| publisher | Slovenian Chemical Society |
| record_format | Article |
| series | Acta Chimica Slovenica |
| spelling | doaj.art-43d7cddda6b84ad9b0d3f97dbcc20fdc2022-12-21T18:39:52ZengSlovenian Chemical SocietyActa Chimica Slovenica1318-02071580-31552019-06-0166248448910.17344/acsi.2019.5019707Synthesis, Crystal Structure and Antimicrobial Activity of A Linear Trinuclear Nickel(II) Complex with Schiff Base LigandCui-Lin Zhang0Xiao-Yang Qiu1Shu-Juan Liu2Ningbo UniversityNingbo UniversityNingbo UniversityA new linear trinuclear Schiff base nickel(II) complex, [Ni{NiL(μ2-η1:η1-OAc)(OH2)}2]·H2O, where L is the dianionic form of N,N’-bis(5-chloro-2-hydroxybenzylidene)-1,3-propanediamine (H2L), was synthesized and characterized by elemental analyses, IR spectroscopy, and X-ray single-crystal determination. There are three bridges across the Ni-Ni atom pairs, involving two phenolate O atoms of a Schiff base ligand, and an O–C–O moiety of a μ2-η1:η1-OAc group. The Ni atoms have octahedral coordination. The acetate bridges linking the central and terminal nickel atoms are mutually trans. The adjacent Ni∙∙∙Ni distances are 3.047(1) Å. The complex was evaluated for its antibacterial (Bacillus subtilis, Staphylococcus aureus, Escherichia coli, and Pseudomonas aeruginosa) and antifungal (Candida albicans and Aspergillus niger) activities by MTT (3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide) method.https://journals.matheo.si/index.php/ACSi/article/view/5019Nickel(II) complexTrinuclear complexSchiff baseCrystal structureAntibacterial activity |
| spellingShingle | Cui-Lin Zhang Xiao-Yang Qiu Shu-Juan Liu Synthesis, Crystal Structure and Antimicrobial Activity of A Linear Trinuclear Nickel(II) Complex with Schiff Base Ligand Acta Chimica Slovenica Nickel(II) complex Trinuclear complex Schiff base Crystal structure Antibacterial activity |
| title | Synthesis, Crystal Structure and Antimicrobial Activity of A Linear Trinuclear Nickel(II) Complex with Schiff Base Ligand |
| title_full | Synthesis, Crystal Structure and Antimicrobial Activity of A Linear Trinuclear Nickel(II) Complex with Schiff Base Ligand |
| title_fullStr | Synthesis, Crystal Structure and Antimicrobial Activity of A Linear Trinuclear Nickel(II) Complex with Schiff Base Ligand |
| title_full_unstemmed | Synthesis, Crystal Structure and Antimicrobial Activity of A Linear Trinuclear Nickel(II) Complex with Schiff Base Ligand |
| title_short | Synthesis, Crystal Structure and Antimicrobial Activity of A Linear Trinuclear Nickel(II) Complex with Schiff Base Ligand |
| title_sort | synthesis crystal structure and antimicrobial activity of a linear trinuclear nickel ii complex with schiff base ligand |
| topic | Nickel(II) complex Trinuclear complex Schiff base Crystal structure Antibacterial activity |
| url | https://journals.matheo.si/index.php/ACSi/article/view/5019 |
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