Chlorido[5-methoxy-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol disolvate
In the title complex, [CuCl(C8H8N2OS)(C18H15P)2]·2CH3OH, the CuI ion is coordinated by one chloride anion, one S atom from the 5-methoxy-1H-benzimidazole-2(3H)-thione ligand and two P atoms from two triphenylphosphine ligands in a distorted tetrahedral geometry. One of the N-bound H atoms is involve...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814001251 |
| _version_ | 1818959196436037632 |
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| author | Qing-Xuan Meng |
| author_facet | Qing-Xuan Meng |
| author_sort | Qing-Xuan Meng |
| collection | DOAJ |
| description | In the title complex, [CuCl(C8H8N2OS)(C18H15P)2]·2CH3OH, the CuI ion is coordinated by one chloride anion, one S atom from the 5-methoxy-1H-benzimidazole-2(3H)-thione ligand and two P atoms from two triphenylphosphine ligands in a distorted tetrahedral geometry. One of the N-bound H atoms is involved in an intramolecular N—H...Cl hydrogen bond, while another one interacts with the solvent methanol molecule via an N—H...O hydrogen bond. Intermolecular O—H...Cl and O—H...O hydrogen bonds link two further complex molecules and four solvent molecules into a centrosymmetric structural unit. The short distance of 3.624 (4) Å between the centroids of the five- and the six-membered rings of two benzimidazole fragments indicates the presence of π–π interactions. |
| first_indexed | 2024-12-20T11:37:48Z |
| format | Article |
| id | doaj.art-43ed19ba8d744d138663fba60ab08e13 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:37:48Z |
| publishDate | 2014-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-43ed19ba8d744d138663fba60ab08e132022-12-21T19:42:02ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-02-01702m60m6010.1107/S1600536814001251cv5442Chlorido[5-methoxy-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol disolvateQing-Xuan Meng0Daxing High School Attached to CNU, Beijing 102600, People's Republic of ChinaIn the title complex, [CuCl(C8H8N2OS)(C18H15P)2]·2CH3OH, the CuI ion is coordinated by one chloride anion, one S atom from the 5-methoxy-1H-benzimidazole-2(3H)-thione ligand and two P atoms from two triphenylphosphine ligands in a distorted tetrahedral geometry. One of the N-bound H atoms is involved in an intramolecular N—H...Cl hydrogen bond, while another one interacts with the solvent methanol molecule via an N—H...O hydrogen bond. Intermolecular O—H...Cl and O—H...O hydrogen bonds link two further complex molecules and four solvent molecules into a centrosymmetric structural unit. The short distance of 3.624 (4) Å between the centroids of the five- and the six-membered rings of two benzimidazole fragments indicates the presence of π–π interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536814001251 |
| spellingShingle | Qing-Xuan Meng Chlorido[5-methoxy-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol disolvate Acta Crystallographica Section E |
| title | Chlorido[5-methoxy-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol disolvate |
| title_full | Chlorido[5-methoxy-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol disolvate |
| title_fullStr | Chlorido[5-methoxy-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol disolvate |
| title_full_unstemmed | Chlorido[5-methoxy-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol disolvate |
| title_short | Chlorido[5-methoxy-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol disolvate |
| title_sort | chlorido 5 methoxy 1h benzimidazole 2 3h thione κs bis triphenylphosphane κp copper i methanol disolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814001251 |
| work_keys_str_mv | AT qingxuanmeng chlorido5methoxy1hbenzimidazole23hthioneksbistriphenylphosphanekpcopperimethanoldisolvate |