Modification of perovskite and dye-sensitized solar cells with plasmonic nanoparticles

Dye-sensitized solar cells and perovskite solar cells can operate under conditions of low and diffuse solar radiation. This makes them promising candidates for replacing the silicon-based photoconverters which dominate at the market. The efficiency of such devices is largely determined by the morpho...

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Main Authors: D.A. Ryzhkova, A.A. Cherepovskaya
Format: Article
Language:Russian
Published: Tver State University 2024-12-01
Series:Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов
Subjects:
Online Access:https://physchemaspects.ru/2024/doi-10-26456-pcascnn-2024-16-711/?lang=en
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author D.A. Ryzhkova
A.A. Cherepovskaya
author_facet D.A. Ryzhkova
A.A. Cherepovskaya
author_sort D.A. Ryzhkova
collection DOAJ
description Dye-sensitized solar cells and perovskite solar cells can operate under conditions of low and diffuse solar radiation. This makes them promising candidates for replacing the silicon-based photoconverters which dominate at the market. The efficiency of such devices is largely determined by the morphology of electron-conducting photoelectrodes. One of the strategies for increasing it is the embedding of Ag and Au nanoparticles into the photoelectrode layer. Due to the phenomenon of the surface plasmon resonance, they enhance the scattering of the supplied light and affect the mechanism of electron transfer to the conduction band of the semiconductor. This leads to an increase in the electric current generated by the solar cell. The present work examines the influence of a number of parameters of embedded nanoparticles on the efficiency of photoconverters, such as size, shape and dielectric environment. It is shown that the use of bimetallic compounds Ag-Au, Ag-Cu and heterogeneous structures of various types allows achieving a higher efficiency of solar cells compared to devices modified with monometallic nanoparticles.
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spelling doaj.art-43ed95ea448c4fcf9706d3ce73f9f5332024-12-30T07:22:47ZrusTver State UniversityФизико-химические аспекты изучения кластеров, наноструктур и наноматериалов2226-44422658-43602024-12-011671171910.26456/pcascnn/2024.16.711Modification of perovskite and dye-sensitized solar cells with plasmonic nanoparticlesD.A. Ryzhkova0A.A. Cherepovskaya1Khakass State UniversityKhakass State UniversityDye-sensitized solar cells and perovskite solar cells can operate under conditions of low and diffuse solar radiation. This makes them promising candidates for replacing the silicon-based photoconverters which dominate at the market. The efficiency of such devices is largely determined by the morphology of electron-conducting photoelectrodes. One of the strategies for increasing it is the embedding of Ag and Au nanoparticles into the photoelectrode layer. Due to the phenomenon of the surface plasmon resonance, they enhance the scattering of the supplied light and affect the mechanism of electron transfer to the conduction band of the semiconductor. This leads to an increase in the electric current generated by the solar cell. The present work examines the influence of a number of parameters of embedded nanoparticles on the efficiency of photoconverters, such as size, shape and dielectric environment. It is shown that the use of bimetallic compounds Ag-Au, Ag-Cu and heterogeneous structures of various types allows achieving a higher efficiency of solar cells compared to devices modified with monometallic nanoparticles. https://physchemaspects.ru/2024/doi-10-26456-pcascnn-2024-16-711/?lang=endye-sensitized solar cellsperovskite solar cellsnanoparticlessilvergoldsurface plasmon resonancebimetallic nanoparticlescore-shell structure
spellingShingle D.A. Ryzhkova
A.A. Cherepovskaya
Modification of perovskite and dye-sensitized solar cells with plasmonic nanoparticles
Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов
dye-sensitized solar cells
perovskite solar cells
nanoparticles
silver
gold
surface plasmon resonance
bimetallic nanoparticles
core-shell structure
title Modification of perovskite and dye-sensitized solar cells with plasmonic nanoparticles
title_full Modification of perovskite and dye-sensitized solar cells with plasmonic nanoparticles
title_fullStr Modification of perovskite and dye-sensitized solar cells with plasmonic nanoparticles
title_full_unstemmed Modification of perovskite and dye-sensitized solar cells with plasmonic nanoparticles
title_short Modification of perovskite and dye-sensitized solar cells with plasmonic nanoparticles
title_sort modification of perovskite and dye sensitized solar cells with plasmonic nanoparticles
topic dye-sensitized solar cells
perovskite solar cells
nanoparticles
silver
gold
surface plasmon resonance
bimetallic nanoparticles
core-shell structure
url https://physchemaspects.ru/2024/doi-10-26456-pcascnn-2024-16-711/?lang=en
work_keys_str_mv AT daryzhkova modificationofperovskiteanddyesensitizedsolarcellswithplasmonicnanoparticles
AT aacherepovskaya modificationofperovskiteanddyesensitizedsolarcellswithplasmonicnanoparticles