Phase Formation, Microstructure and Mechanical Properties of Mg<sub>67</sub>Ag<sub>33</sub> as Potential Biomaterial

The phase and microstructure formation as well as mechanical properties of the rapidly solidified Mg<sub>67</sub>Ag<sub>33</sub> (at. %) alloy were investigated. Owing to kinetic constraints effective during rapid cooling, the formation of equilibrium phases is suppressed. In...

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Main Authors: Konrad Kosiba, Konda Gokuldoss Prashanth, Sergio Scudino
Format: Article
Language:English
Published: MDPI AG 2021-03-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/11/3/461
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author Konrad Kosiba
Konda Gokuldoss Prashanth
Sergio Scudino
author_facet Konrad Kosiba
Konda Gokuldoss Prashanth
Sergio Scudino
author_sort Konrad Kosiba
collection DOAJ
description The phase and microstructure formation as well as mechanical properties of the rapidly solidified Mg<sub>67</sub>Ag<sub>33</sub> (at. %) alloy were investigated. Owing to kinetic constraints effective during rapid cooling, the formation of equilibrium phases is suppressed. Instead, the microstructure is mainly composed of oversaturated hexagonal closest packed Mg-based dendrites surrounded by a mixture of phases, as probed by X-ray diffraction, electron microscopy and energy dispersive X-ray spectroscopy. A possible non-equilibrium phase diagram is suggested. Mainly because of the fine-grained dendritic and interdendritic microstructure, the material shows appreciable mechanical properties, such as a compressive yield strength and Young’s modulus of 245 ± 5 MPa and 63 ± 2 GPa, respectively. Due to this low Young’s modulus, the Mg<sub>67</sub>Ag<sub>33</sub> alloy has potential for usage as biomaterial and challenges ahead, such as biomechanical compatibility, biodegradability and antibacterial properties are outlined.
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spelling doaj.art-443878156ee348c7ba1ad59db788851b2023-11-21T10:03:11ZengMDPI AGMetals2075-47012021-03-0111346110.3390/met11030461Phase Formation, Microstructure and Mechanical Properties of Mg<sub>67</sub>Ag<sub>33</sub> as Potential BiomaterialKonrad Kosiba0Konda Gokuldoss Prashanth1Sergio Scudino2Leibniz IFW Dresden, Institute for Complex Materials, Helmholtzstrasse 20, 01069 Dresden, GermanyDepartment of Mechanical and Industrial Engineering, Tallinn University of Technology, Ehitajate tee 5, 19086 Tallinn, EstoniaLeibniz IFW Dresden, Institute for Complex Materials, Helmholtzstrasse 20, 01069 Dresden, GermanyThe phase and microstructure formation as well as mechanical properties of the rapidly solidified Mg<sub>67</sub>Ag<sub>33</sub> (at. %) alloy were investigated. Owing to kinetic constraints effective during rapid cooling, the formation of equilibrium phases is suppressed. Instead, the microstructure is mainly composed of oversaturated hexagonal closest packed Mg-based dendrites surrounded by a mixture of phases, as probed by X-ray diffraction, electron microscopy and energy dispersive X-ray spectroscopy. A possible non-equilibrium phase diagram is suggested. Mainly because of the fine-grained dendritic and interdendritic microstructure, the material shows appreciable mechanical properties, such as a compressive yield strength and Young’s modulus of 245 ± 5 MPa and 63 ± 2 GPa, respectively. Due to this low Young’s modulus, the Mg<sub>67</sub>Ag<sub>33</sub> alloy has potential for usage as biomaterial and challenges ahead, such as biomechanical compatibility, biodegradability and antibacterial properties are outlined.https://www.mdpi.com/2075-4701/11/3/461Mg–Ag-based alloymetastable phase formationmicrostructuremechanical propertiesbiomaterial
spellingShingle Konrad Kosiba
Konda Gokuldoss Prashanth
Sergio Scudino
Phase Formation, Microstructure and Mechanical Properties of Mg<sub>67</sub>Ag<sub>33</sub> as Potential Biomaterial
Metals
Mg–Ag-based alloy
metastable phase formation
microstructure
mechanical properties
biomaterial
title Phase Formation, Microstructure and Mechanical Properties of Mg<sub>67</sub>Ag<sub>33</sub> as Potential Biomaterial
title_full Phase Formation, Microstructure and Mechanical Properties of Mg<sub>67</sub>Ag<sub>33</sub> as Potential Biomaterial
title_fullStr Phase Formation, Microstructure and Mechanical Properties of Mg<sub>67</sub>Ag<sub>33</sub> as Potential Biomaterial
title_full_unstemmed Phase Formation, Microstructure and Mechanical Properties of Mg<sub>67</sub>Ag<sub>33</sub> as Potential Biomaterial
title_short Phase Formation, Microstructure and Mechanical Properties of Mg<sub>67</sub>Ag<sub>33</sub> as Potential Biomaterial
title_sort phase formation microstructure and mechanical properties of mg sub 67 sub ag sub 33 sub as potential biomaterial
topic Mg–Ag-based alloy
metastable phase formation
microstructure
mechanical properties
biomaterial
url https://www.mdpi.com/2075-4701/11/3/461
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AT kondagokuldossprashanth phaseformationmicrostructureandmechanicalpropertiesofmgsub67subagsub33subaspotentialbiomaterial
AT sergioscudino phaseformationmicrostructureandmechanicalpropertiesofmgsub67subagsub33subaspotentialbiomaterial