High sensitivity hydrogen analysis in zircaloy-4 using helium-assisted excitation laser-induced breakdown spectroscopy
Abstract High-sensitivity detection of hydrogen (H) contained in zircaloy-4, a commonly used material for nuclear fuel containers, is crucial in a nuclear power plant. Currently, H detection is performed via gas chromatography, which is an offline and destructive method. In this study, we developed...
| Main Authors: | , , , , , , , , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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Nature Portfolio
2021-11-01
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| Series: | Scientific Reports |
| Online Access: | https://doi.org/10.1038/s41598-021-01601-y |
| _version_ | 1819040745209724928 |
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| author | Marincan Pardede Indra Karnadi Rinda Hedwig Ivan Tanra Javed Iqbal Mangasi Alion Marpaung Maria Margaretha Suliyanti Eric Jobiliong Syahrun Nur Abdulmadjid Nasrullah Idris Ali Khumaeni Muhandis Shiddiq Mario Gracio Anduinta Rhizma Zener Sukra Lie Muhammad Bilal Davy Putra Kurniawan Tjung Jie Lie Koo Hendrik Kurniawan Kiichiro Kagawa |
| author_facet | Marincan Pardede Indra Karnadi Rinda Hedwig Ivan Tanra Javed Iqbal Mangasi Alion Marpaung Maria Margaretha Suliyanti Eric Jobiliong Syahrun Nur Abdulmadjid Nasrullah Idris Ali Khumaeni Muhandis Shiddiq Mario Gracio Anduinta Rhizma Zener Sukra Lie Muhammad Bilal Davy Putra Kurniawan Tjung Jie Lie Koo Hendrik Kurniawan Kiichiro Kagawa |
| author_sort | Marincan Pardede |
| collection | DOAJ |
| description | Abstract High-sensitivity detection of hydrogen (H) contained in zircaloy-4, a commonly used material for nuclear fuel containers, is crucial in a nuclear power plant. Currently, H detection is performed via gas chromatography, which is an offline and destructive method. In this study, we developed a technique based on metastable excited-state He-assisted excitation to achieve excellent quality of H emission spectra in double-pulse orthogonal laser-induced breakdown spectroscopy (LIBS). The production of metastable excited-state He atoms is optimized by using LiF as sub-target material. The results show a narrow full-width-at-half-maximum of 0.5 Å for the H I 656.2 nm emission line, with a detection limit as low as 0.51 mg/kg. Thus, using this novel online method, H in zircaloy-4 can be detected efficiently, even at very low concentrations. |
| first_indexed | 2024-12-21T09:13:59Z |
| format | Article |
| id | doaj.art-4439f8c74afa40989646c96e47dae667 |
| institution | Directory Open Access Journal |
| issn | 2045-2322 |
| language | English |
| last_indexed | 2024-12-21T09:13:59Z |
| publishDate | 2021-11-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Scientific Reports |
| spelling | doaj.art-4439f8c74afa40989646c96e47dae6672022-12-21T19:09:10ZengNature PortfolioScientific Reports2045-23222021-11-0111111010.1038/s41598-021-01601-yHigh sensitivity hydrogen analysis in zircaloy-4 using helium-assisted excitation laser-induced breakdown spectroscopyMarincan Pardede0Indra Karnadi1Rinda Hedwig2Ivan Tanra3Javed Iqbal4Mangasi Alion Marpaung5Maria Margaretha Suliyanti6Eric Jobiliong7Syahrun Nur Abdulmadjid8Nasrullah Idris9Ali Khumaeni10Muhandis Shiddiq11Mario Gracio Anduinta Rhizma12Zener Sukra Lie13Muhammad Bilal14Davy Putra Kurniawan15Tjung Jie Lie16Koo Hendrik Kurniawan17Kiichiro Kagawa18Department of Electrical Engineering, University of Pelita HarapanDepartment of Electrical Engineering, Krida Wacana Christian UniversityComputer Engineering Department, Faculty of Engineering, Bina Nusantara UniversityDepartment of Electrical Engineering, Krida Wacana Christian UniversityDepartment of Physics, University of Azad, Jammu & KashmirFaculty of Mathematics and Natural Sciences, Jakarta State UniversityResearch Center for Physics, Indonesia Institute of ScienceDepartment of Industrial Engineering, University of Pelita HarapanDepartment of Physics, Faculty of Mathematics and Natural Sciences, Syiah Kuala University, DarussalamDepartment of Physics, Faculty of Mathematics and Natural Sciences, Syiah Kuala University, DarussalamDepartment of Physics, Faculty of Mathematics and Natural Sciences, Diponegoro UniversityResearch Center for Physics, Indonesia Institute of ScienceDepartment of Electrical Engineering, University of Pelita HarapanAutomotive & Robotics Program, Computer Engineering Department, Binus ASO School of Engineering, Bina Nusantara UniversityLaser Matter Interaction Laboratory, Department of Physics, Faculty of Sciences, University of Agriculture FaisalabadResearch Center of Maju Makmur Mandiri FoundationResearch Center of Maju Makmur Mandiri FoundationResearch Center of Maju Makmur Mandiri FoundationResearch Center of Maju Makmur Mandiri FoundationAbstract High-sensitivity detection of hydrogen (H) contained in zircaloy-4, a commonly used material for nuclear fuel containers, is crucial in a nuclear power plant. Currently, H detection is performed via gas chromatography, which is an offline and destructive method. In this study, we developed a technique based on metastable excited-state He-assisted excitation to achieve excellent quality of H emission spectra in double-pulse orthogonal laser-induced breakdown spectroscopy (LIBS). The production of metastable excited-state He atoms is optimized by using LiF as sub-target material. The results show a narrow full-width-at-half-maximum of 0.5 Å for the H I 656.2 nm emission line, with a detection limit as low as 0.51 mg/kg. Thus, using this novel online method, H in zircaloy-4 can be detected efficiently, even at very low concentrations.https://doi.org/10.1038/s41598-021-01601-y |
| spellingShingle | Marincan Pardede Indra Karnadi Rinda Hedwig Ivan Tanra Javed Iqbal Mangasi Alion Marpaung Maria Margaretha Suliyanti Eric Jobiliong Syahrun Nur Abdulmadjid Nasrullah Idris Ali Khumaeni Muhandis Shiddiq Mario Gracio Anduinta Rhizma Zener Sukra Lie Muhammad Bilal Davy Putra Kurniawan Tjung Jie Lie Koo Hendrik Kurniawan Kiichiro Kagawa High sensitivity hydrogen analysis in zircaloy-4 using helium-assisted excitation laser-induced breakdown spectroscopy Scientific Reports |
| title | High sensitivity hydrogen analysis in zircaloy-4 using helium-assisted excitation laser-induced breakdown spectroscopy |
| title_full | High sensitivity hydrogen analysis in zircaloy-4 using helium-assisted excitation laser-induced breakdown spectroscopy |
| title_fullStr | High sensitivity hydrogen analysis in zircaloy-4 using helium-assisted excitation laser-induced breakdown spectroscopy |
| title_full_unstemmed | High sensitivity hydrogen analysis in zircaloy-4 using helium-assisted excitation laser-induced breakdown spectroscopy |
| title_short | High sensitivity hydrogen analysis in zircaloy-4 using helium-assisted excitation laser-induced breakdown spectroscopy |
| title_sort | high sensitivity hydrogen analysis in zircaloy 4 using helium assisted excitation laser induced breakdown spectroscopy |
| url | https://doi.org/10.1038/s41598-021-01601-y |
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