Syntheses and structural characterizations of the first coordination polymers assembled from the Ni(cyclam)2+ cation and the benzene-1,3,5-tricarboxylate linker

Syntheses and structural characterizations of the first coordination polymers assembled from the Ni(cyclam)2+ cation and the benzene-1,3,5-tricarboxylate linker

The asymmetric unit of catena-poly[[[(1,4,8,11-tetraazacyclotetradecane-κ4N1,N4,N8,N11)nickel(II)]-μ2-5-carboxybenzene-1,3-dicarboxylato-κ2O1:O3] octahydrate], {[Ni(C9H4O6)(C10H24N4)]·8H2O}n (I), consists of a macrocyclic Ni2+ cation, a carboxylate dianion and eight highly disordered water molecules...

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Bibliographic Details
Main Authors: Sergey P. Gavrish, Sergiu Shova, Yaroslaw D. Lampeka
Format: Article
Language:English
Published: International Union of Crystallography 2022-11-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
coordination polymers
cyclam
nickel
benzenetricarboxylate
hydrogen bonds
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989022009860

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