Cobalt Iron-Metal Organic Framework Coordinated to CMC Aerogel by Solvothermal Method and Application to Tetracycline Antibiotics Adsorption
In order to minimize the adverse impacts on the aquatic environment after treatment process, several attempts have been made to develop biodegradable, easy-to-recover, and environmentally friendly materials. The metal-organic framework material (CoFe-MOF) was developed in the CMC aerogel matrix by s...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
2022-12-01
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| Series: | Bulletin of Chemical Reaction Engineering & Catalysis |
| Subjects: | |
| Online Access: | https://journal.bcrec.id/index.php/bcrec/article/view/16281 |
| _version_ | 1797677879315660800 |
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| author | Thi Kim Ngan Tran Van Phuoc Nguyen A Chau Tran Thi Hong Nhan Le Thi Thanh Ngan Tran |
| author_facet | Thi Kim Ngan Tran Van Phuoc Nguyen A Chau Tran Thi Hong Nhan Le Thi Thanh Ngan Tran |
| author_sort | Thi Kim Ngan Tran |
| collection | DOAJ |
| description | In order to minimize the adverse impacts on the aquatic environment after treatment process, several attempts have been made to develop biodegradable, easy-to-recover, and environmentally friendly materials. The metal-organic framework material (CoFe-MOF) was developed in the CMC aerogel matrix by solvothermal method and applied in tetracycline antibiotic (TCC) adsorption. The morphological and structural properties of the materials were analyzed by scanning electron microscope (SEM), x-ray diffraction (XRD), Fourier Transform Infra Red (FT-IR), and (Brunauer-Emmett-Teller) (BET) to identify the crystals formed relative to the pristine MOF. The effects of various factors of the adsorption process such as time, pH, amount of adsorbent, and initial concentration of antibiotics were investigated. Results have shown that the adsorption capacity was 188.7 mg.g-1 at pH 4, the initial TCC concentration of 80 g.L-1 and equilibration time of 120 min. The experimental data describing the antibiotic adsorption process follows the Pseudo-second-order kinetic model and the Langmuir isothermal model. The CoFe-MOF aerogel material can recover and reuse all four cycles, thus it can be considered as a promising material for environmental remediation and other applications. Copyright © 2022 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). |
| first_indexed | 2024-03-11T22:51:32Z |
| format | Article |
| id | doaj.art-4463bc99d76643c5bcd79874fe01718d |
| institution | Directory Open Access Journal |
| issn | 1978-2993 |
| language | English |
| last_indexed | 2024-03-11T22:51:32Z |
| publishDate | 2022-12-01 |
| publisher | Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) |
| record_format | Article |
| series | Bulletin of Chemical Reaction Engineering & Catalysis |
| spelling | doaj.art-4463bc99d76643c5bcd79874fe01718d2023-09-22T03:27:23ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932022-12-0117487288110.9767/bcrec.17.4.16281.872-8817269Cobalt Iron-Metal Organic Framework Coordinated to CMC Aerogel by Solvothermal Method and Application to Tetracycline Antibiotics AdsorptionThi Kim Ngan Tran0Van Phuoc Nguyen1A Chau Tran2Thi Hong Nhan Le3Thi Thanh Ngan Tran4Faculty of Food and Environmental Engineering, Nguyen Tat Thanh University, Ho Chi Minh City 700000, Viet NamFaculty of Food and Environmental Engineering, Nguyen Tat Thanh University, Ho Chi Minh City 700000, Viet NamFaculty of Chemical Engineering and Food Technology, Nong Lam University, Ho Chi Minh City 700000, Viet NamFaculty of Chemical Engineering, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet, District 10, Ho Chi Minh City, Viet NamFaculty of Chemical Engineering, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet, District 10, Ho Chi Minh City, Viet NamIn order to minimize the adverse impacts on the aquatic environment after treatment process, several attempts have been made to develop biodegradable, easy-to-recover, and environmentally friendly materials. The metal-organic framework material (CoFe-MOF) was developed in the CMC aerogel matrix by solvothermal method and applied in tetracycline antibiotic (TCC) adsorption. The morphological and structural properties of the materials were analyzed by scanning electron microscope (SEM), x-ray diffraction (XRD), Fourier Transform Infra Red (FT-IR), and (Brunauer-Emmett-Teller) (BET) to identify the crystals formed relative to the pristine MOF. The effects of various factors of the adsorption process such as time, pH, amount of adsorbent, and initial concentration of antibiotics were investigated. Results have shown that the adsorption capacity was 188.7 mg.g-1 at pH 4, the initial TCC concentration of 80 g.L-1 and equilibration time of 120 min. The experimental data describing the antibiotic adsorption process follows the Pseudo-second-order kinetic model and the Langmuir isothermal model. The CoFe-MOF aerogel material can recover and reuse all four cycles, thus it can be considered as a promising material for environmental remediation and other applications. Copyright © 2022 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).https://journal.bcrec.id/index.php/bcrec/article/view/16281aerogelmofsadsorptionantibioticsslovothermal |
| spellingShingle | Thi Kim Ngan Tran Van Phuoc Nguyen A Chau Tran Thi Hong Nhan Le Thi Thanh Ngan Tran Cobalt Iron-Metal Organic Framework Coordinated to CMC Aerogel by Solvothermal Method and Application to Tetracycline Antibiotics Adsorption Bulletin of Chemical Reaction Engineering & Catalysis aerogel mofs adsorption antibiotics slovothermal |
| title | Cobalt Iron-Metal Organic Framework Coordinated to CMC Aerogel by Solvothermal Method and Application to Tetracycline Antibiotics Adsorption |
| title_full | Cobalt Iron-Metal Organic Framework Coordinated to CMC Aerogel by Solvothermal Method and Application to Tetracycline Antibiotics Adsorption |
| title_fullStr | Cobalt Iron-Metal Organic Framework Coordinated to CMC Aerogel by Solvothermal Method and Application to Tetracycline Antibiotics Adsorption |
| title_full_unstemmed | Cobalt Iron-Metal Organic Framework Coordinated to CMC Aerogel by Solvothermal Method and Application to Tetracycline Antibiotics Adsorption |
| title_short | Cobalt Iron-Metal Organic Framework Coordinated to CMC Aerogel by Solvothermal Method and Application to Tetracycline Antibiotics Adsorption |
| title_sort | cobalt iron metal organic framework coordinated to cmc aerogel by solvothermal method and application to tetracycline antibiotics adsorption |
| topic | aerogel mofs adsorption antibiotics slovothermal |
| url | https://journal.bcrec.id/index.php/bcrec/article/view/16281 |
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