Biodiesel Production on Monometallic Pt, Pd, Ru, and Ag Catalysts Supported on Natural Zeolite
Biodiesel production from rapeseed oil and methanol via transesterification reaction facilitated by various monometallic catalyst supported on natural zeolite (NZ) was investigated. The physicochemical characteristics of the synthesized catalysts were studied by X-ray diffraction (XRD), Brunauer–Emm...
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author | Pawel Mierczynski Magdalena Mosińska Lukasz Szkudlarek Karolina Chalupka Misa Tatsuzawa Marwa Al Maskari Waldemar Maniukiewicz Satriyo K. Wahono Krasimir Vasilev Malgorzata I. Szynkowska-Jozwik |
author_facet | Pawel Mierczynski Magdalena Mosińska Lukasz Szkudlarek Karolina Chalupka Misa Tatsuzawa Marwa Al Maskari Waldemar Maniukiewicz Satriyo K. Wahono Krasimir Vasilev Malgorzata I. Szynkowska-Jozwik |
author_sort | Pawel Mierczynski |
collection | DOAJ |
description | Biodiesel production from rapeseed oil and methanol via transesterification reaction facilitated by various monometallic catalyst supported on natural zeolite (NZ) was investigated. The physicochemical characteristics of the synthesized catalysts were studied by X-ray diffraction (XRD), Brunauer–Emmett–Teller method (BET), temperature-programmed-reduction in hydrogen (H<sub>2</sub>-TPR), temperature-programmed-desorption of ammonia (NH<sub>3</sub>-TPD), Scanning Electron Microscope equipped with EDX detector (SEM-EDS), and X-ray photoelectron spectroscopy (XPS) methods. The highest activity and methyl ester yields were obtained for the Pt/NZ catalyst. This catalyst showed the highest triglycerides conversion of 98.9% and fatty acids methyl esters yields of 94.6%. The activity results also confirmed the high activity of the carrier material (NZ) itself in the investigated reaction. Support material exhibited 90.5% of TG conversion and the Fatty Acid Methyl Esters yield (FAME) of 67.2%. Introduction of noble metals improves the TG conversion and FAME yield values. Increasing of the metal loading from 0.5 to 2 wt.% improves the reactivity properties of the investigated catalysts. |
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id | doaj.art-446c2e7e30674f1d8e693dbebaba5af3 |
institution | Directory Open Access Journal |
issn | 1996-1944 |
language | English |
last_indexed | 2024-03-10T13:47:18Z |
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spelling | doaj.art-446c2e7e30674f1d8e693dbebaba5af32023-11-21T02:28:06ZengMDPI AGMaterials1996-19442020-12-011414810.3390/ma14010048Biodiesel Production on Monometallic Pt, Pd, Ru, and Ag Catalysts Supported on Natural ZeolitePawel Mierczynski0Magdalena Mosińska1Lukasz Szkudlarek2Karolina Chalupka3Misa Tatsuzawa4Marwa Al Maskari5Waldemar Maniukiewicz6Satriyo K. Wahono7Krasimir Vasilev8Malgorzata I. Szynkowska-Jozwik9Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, PolandInstitute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, PolandInstitute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, PolandInstitute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, PolandDepartment of Chemistry, Graduate School of Science, Tokyo University of Science, Tokyo 162-8601, JapanPetroleum and Chemical Engineering Department, Sultan Qaboos University, P.O. Box 33, Muscat P.C 123, OmanInstitute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, PolandResearch Division for Natural Product Technology, Indonesian Institutes of Sciences, Jl. Jogja–Wonosari km 32, Gading, Playen, Gunungkidul, Yogyakarta 55861, IndonesiaAcademic Unit of STEM, University of South Australia, Mawson Lakes, Adelaide, SA 5095, AustraliaInstitute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, PolandBiodiesel production from rapeseed oil and methanol via transesterification reaction facilitated by various monometallic catalyst supported on natural zeolite (NZ) was investigated. The physicochemical characteristics of the synthesized catalysts were studied by X-ray diffraction (XRD), Brunauer–Emmett–Teller method (BET), temperature-programmed-reduction in hydrogen (H<sub>2</sub>-TPR), temperature-programmed-desorption of ammonia (NH<sub>3</sub>-TPD), Scanning Electron Microscope equipped with EDX detector (SEM-EDS), and X-ray photoelectron spectroscopy (XPS) methods. The highest activity and methyl ester yields were obtained for the Pt/NZ catalyst. This catalyst showed the highest triglycerides conversion of 98.9% and fatty acids methyl esters yields of 94.6%. The activity results also confirmed the high activity of the carrier material (NZ) itself in the investigated reaction. Support material exhibited 90.5% of TG conversion and the Fatty Acid Methyl Esters yield (FAME) of 67.2%. Introduction of noble metals improves the TG conversion and FAME yield values. Increasing of the metal loading from 0.5 to 2 wt.% improves the reactivity properties of the investigated catalysts.https://www.mdpi.com/1996-1944/14/1/48biodiesel productionmonometallic catalystzeoliteFAME |
spellingShingle | Pawel Mierczynski Magdalena Mosińska Lukasz Szkudlarek Karolina Chalupka Misa Tatsuzawa Marwa Al Maskari Waldemar Maniukiewicz Satriyo K. Wahono Krasimir Vasilev Malgorzata I. Szynkowska-Jozwik Biodiesel Production on Monometallic Pt, Pd, Ru, and Ag Catalysts Supported on Natural Zeolite Materials biodiesel production monometallic catalyst zeolite FAME |
title | Biodiesel Production on Monometallic Pt, Pd, Ru, and Ag Catalysts Supported on Natural Zeolite |
title_full | Biodiesel Production on Monometallic Pt, Pd, Ru, and Ag Catalysts Supported on Natural Zeolite |
title_fullStr | Biodiesel Production on Monometallic Pt, Pd, Ru, and Ag Catalysts Supported on Natural Zeolite |
title_full_unstemmed | Biodiesel Production on Monometallic Pt, Pd, Ru, and Ag Catalysts Supported on Natural Zeolite |
title_short | Biodiesel Production on Monometallic Pt, Pd, Ru, and Ag Catalysts Supported on Natural Zeolite |
title_sort | biodiesel production on monometallic pt pd ru and ag catalysts supported on natural zeolite |
topic | biodiesel production monometallic catalyst zeolite FAME |
url | https://www.mdpi.com/1996-1944/14/1/48 |
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