1′-Methyl-4′-(4-methylphenyl)dispiro[indane-2,3′-pyrrolidine-2′,3′′-indoline]-1,2′′-dione

In the title molecule, C27H24N2O2, the pyrrolidin-2-one ring is almost planar (r.m.s. deviation = 0.003 Å), the pyrrolidine ring has an envelope conformation (the N atom is the flap atom) and the cyclopentanone ring is twisted about the Cq—Cm bond (q = quater...

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Bibliographic Details
Main Authors: A. M. Moustafa, Adel S. Girgis, S. M. Shalaby, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2012-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812028012
Description
Summary:In the title molecule, C27H24N2O2, the pyrrolidin-2-one ring is almost planar (r.m.s. deviation = 0.003 Å), the pyrrolidine ring has an envelope conformation (the N atom is the flap atom) and the cyclopentanone ring is twisted about the Cq—Cm bond (q = quaternary and m = methylene). The ketone O atoms are directed to opposite sides of the molecule. Supramolecular chains along the a axis are formed in the crystal packing mediated by N—H...N and C—H...O interactions. These are connected into layers in the ab plane via C—H...π interactions.
ISSN:1600-5368