Catalytic direct hydrocarboxylation of styrenes with CO2 and H2
Hydrocarboxylation of olefins with CO2 provides a useful approach for the synthesis of aliphatic carboxylic acids. Here, the authors report a rhodium-catalysed hydrocarboxylation of styrenes with CO2, using hydrogen as the terminal reductant.
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Nature Portfolio
2022-12-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-022-35293-3 |
| _version_ | 1811204121448939520 |
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| author | Yushu Jin Joaquim Caner Shintaro Nishikawa Naoyuki Toriumi Nobuharu Iwasawa |
| author_facet | Yushu Jin Joaquim Caner Shintaro Nishikawa Naoyuki Toriumi Nobuharu Iwasawa |
| author_sort | Yushu Jin |
| collection | DOAJ |
| description | Hydrocarboxylation of olefins with CO2 provides a useful approach for the synthesis of aliphatic carboxylic acids. Here, the authors report a rhodium-catalysed hydrocarboxylation of styrenes with CO2, using hydrogen as the terminal reductant. |
| first_indexed | 2024-04-12T03:07:00Z |
| format | Article |
| id | doaj.art-44a35dba9633462294fcd523c895939c |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-04-12T03:07:00Z |
| publishDate | 2022-12-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-44a35dba9633462294fcd523c895939c2022-12-22T03:50:28ZengNature PortfolioNature Communications2041-17232022-12-011311810.1038/s41467-022-35293-3Catalytic direct hydrocarboxylation of styrenes with CO2 and H2Yushu Jin0Joaquim Caner1Shintaro Nishikawa2Naoyuki Toriumi3Nobuharu Iwasawa4Department of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-kuDepartment of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-kuDepartment of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-kuDepartment of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-kuDepartment of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-kuHydrocarboxylation of olefins with CO2 provides a useful approach for the synthesis of aliphatic carboxylic acids. Here, the authors report a rhodium-catalysed hydrocarboxylation of styrenes with CO2, using hydrogen as the terminal reductant.https://doi.org/10.1038/s41467-022-35293-3 |
| spellingShingle | Yushu Jin Joaquim Caner Shintaro Nishikawa Naoyuki Toriumi Nobuharu Iwasawa Catalytic direct hydrocarboxylation of styrenes with CO2 and H2 Nature Communications |
| title | Catalytic direct hydrocarboxylation of styrenes with CO2 and H2 |
| title_full | Catalytic direct hydrocarboxylation of styrenes with CO2 and H2 |
| title_fullStr | Catalytic direct hydrocarboxylation of styrenes with CO2 and H2 |
| title_full_unstemmed | Catalytic direct hydrocarboxylation of styrenes with CO2 and H2 |
| title_short | Catalytic direct hydrocarboxylation of styrenes with CO2 and H2 |
| title_sort | catalytic direct hydrocarboxylation of styrenes with co2 and h2 |
| url | https://doi.org/10.1038/s41467-022-35293-3 |
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