Identification of Dynamic Active Sites Among Cu Species Derived from MOFs@CuPc for Electrocatalytic Nitrate Reduction Reaction to Ammonia
Highlights Cu species with tunable loading supported on N-doped TiO2/C were successfully fabricated utilizing MOFs@CuPc precursors via the pre-anchor and post-pyrolysis strategy. Cu species with tunable loading supported on N-doped TiO2/C were successfully fabricated utilizing MOFs@CuPc precursors v...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
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SpringerOpen
2023-04-01
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| Series: | Nano-Micro Letters |
| Subjects: | |
| Online Access: | https://doi.org/10.1007/s40820-023-01091-9 |
| _version_ | 1797557065354313728 |
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| author | Xue-Yang Ji Ke Sun Zhi-Kun Liu Xinghui Liu Weikang Dong Xintao Zuo Ruiwen Shao Jun Tao |
| author_facet | Xue-Yang Ji Ke Sun Zhi-Kun Liu Xinghui Liu Weikang Dong Xintao Zuo Ruiwen Shao Jun Tao |
| author_sort | Xue-Yang Ji |
| collection | DOAJ |
| description | Highlights Cu species with tunable loading supported on N-doped TiO2/C were successfully fabricated utilizing MOFs@CuPc precursors via the pre-anchor and post-pyrolysis strategy. Cu species with tunable loading supported on N-doped TiO2/C were successfully fabricated utilizing MOFs@CuPc precursors via the pre-anchor and post-pyrolysis strategy. Restructured CuN4&Cu4 performed the highest NH3 yield (88.2 mmol h−1 gcata −1) and FE (~94.3%) at − 0.75 V due to optimal adsorption of NO3 − and rapid conversion of the key intermediates. |
| first_indexed | 2024-03-10T17:11:55Z |
| format | Article |
| id | doaj.art-44bdd6f98f53409f817714aea2826f0a |
| institution | Directory Open Access Journal |
| issn | 2311-6706 2150-5551 |
| language | English |
| last_indexed | 2024-03-10T17:11:55Z |
| publishDate | 2023-04-01 |
| publisher | SpringerOpen |
| record_format | Article |
| series | Nano-Micro Letters |
| spelling | doaj.art-44bdd6f98f53409f817714aea2826f0a2023-11-20T10:37:44ZengSpringerOpenNano-Micro Letters2311-67062150-55512023-04-0115111510.1007/s40820-023-01091-9Identification of Dynamic Active Sites Among Cu Species Derived from MOFs@CuPc for Electrocatalytic Nitrate Reduction Reaction to AmmoniaXue-Yang Ji0Ke Sun1Zhi-Kun Liu2Xinghui Liu3Weikang Dong4Xintao Zuo5Ruiwen Shao6Jun Tao7Key Laboratory of Cluster Science of Ministry of Education, School of Chemistry and Chemical Engineering, Liangxiang Campus, Beijing Institute of TechnologyKey Laboratory of Cluster Science of Ministry of Education, School of Chemistry and Chemical Engineering, Liangxiang Campus, Beijing Institute of TechnologyKey Laboratory of Cluster Science of Ministry of Education, School of Chemistry and Chemical Engineering, Liangxiang Campus, Beijing Institute of TechnologyDepartment of Chemistry, Sungkyunkwan University (SKKU)Beijing Advanced Innovation Center for Intelligent Robots and Systems and Institute of Engineering Medicine, Beijing Institute of TechnologyKey Laboratory of Bio-inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry, Beihang UniversityBeijing Advanced Innovation Center for Intelligent Robots and Systems and Institute of Engineering Medicine, Beijing Institute of TechnologyKey Laboratory of Cluster Science of Ministry of Education, School of Chemistry and Chemical Engineering, Liangxiang Campus, Beijing Institute of TechnologyHighlights Cu species with tunable loading supported on N-doped TiO2/C were successfully fabricated utilizing MOFs@CuPc precursors via the pre-anchor and post-pyrolysis strategy. Cu species with tunable loading supported on N-doped TiO2/C were successfully fabricated utilizing MOFs@CuPc precursors via the pre-anchor and post-pyrolysis strategy. Restructured CuN4&Cu4 performed the highest NH3 yield (88.2 mmol h−1 gcata −1) and FE (~94.3%) at − 0.75 V due to optimal adsorption of NO3 − and rapid conversion of the key intermediates.https://doi.org/10.1007/s40820-023-01091-9Metal–organic frameworksCopper phthalocyanineElectrocatalytic nitrate reduction reaction |
| spellingShingle | Xue-Yang Ji Ke Sun Zhi-Kun Liu Xinghui Liu Weikang Dong Xintao Zuo Ruiwen Shao Jun Tao Identification of Dynamic Active Sites Among Cu Species Derived from MOFs@CuPc for Electrocatalytic Nitrate Reduction Reaction to Ammonia Nano-Micro Letters Metal–organic frameworks Copper phthalocyanine Electrocatalytic nitrate reduction reaction |
| title | Identification of Dynamic Active Sites Among Cu Species Derived from MOFs@CuPc for Electrocatalytic Nitrate Reduction Reaction to Ammonia |
| title_full | Identification of Dynamic Active Sites Among Cu Species Derived from MOFs@CuPc for Electrocatalytic Nitrate Reduction Reaction to Ammonia |
| title_fullStr | Identification of Dynamic Active Sites Among Cu Species Derived from MOFs@CuPc for Electrocatalytic Nitrate Reduction Reaction to Ammonia |
| title_full_unstemmed | Identification of Dynamic Active Sites Among Cu Species Derived from MOFs@CuPc for Electrocatalytic Nitrate Reduction Reaction to Ammonia |
| title_short | Identification of Dynamic Active Sites Among Cu Species Derived from MOFs@CuPc for Electrocatalytic Nitrate Reduction Reaction to Ammonia |
| title_sort | identification of dynamic active sites among cu species derived from mofs cupc for electrocatalytic nitrate reduction reaction to ammonia |
| topic | Metal–organic frameworks Copper phthalocyanine Electrocatalytic nitrate reduction reaction |
| url | https://doi.org/10.1007/s40820-023-01091-9 |
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