Nanostructured polyethersulfone nanocomposite membranes for dual protein and dye separation: Lower antifouling with lanthanum (III) vanadate nanosheets as a novel nanofiller
A novel polyethersulfone (PES) nanocomposite membrane incorporated with lanthanum vanadate (LaVO3) nanosheets was fabricated based on phase inversion approach. The morphology and the performance of the fabricated nanocomposite membranes were systematically studied by ATR-FTIR, SEM, AFM, porosity, wa...
| Main Authors: | , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2021-02-01
|
| Series: | Polymer Testing |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S0142941820322698 |
| _version_ | 1818916063054659584 |
|---|---|
| author | Vahid Vatanpour Yaghoub Mansourpanah Seyed Soroush Mousavi Khadem Sirus Zinadini Nadir Dizge Mohammad Reza Ganjali Somayeh Mirsadeghi Morteza Rezapour Mohammad Reza Saeb Hassan Karimi-Male |
| author_facet | Vahid Vatanpour Yaghoub Mansourpanah Seyed Soroush Mousavi Khadem Sirus Zinadini Nadir Dizge Mohammad Reza Ganjali Somayeh Mirsadeghi Morteza Rezapour Mohammad Reza Saeb Hassan Karimi-Male |
| author_sort | Vahid Vatanpour |
| collection | DOAJ |
| description | A novel polyethersulfone (PES) nanocomposite membrane incorporated with lanthanum vanadate (LaVO3) nanosheets was fabricated based on phase inversion approach. The morphology and the performance of the fabricated nanocomposite membranes were systematically studied by ATR-FTIR, SEM, AFM, porosity, water contact angle, antifouling and rejection measurements. The resulting membranes showed an asymmetric structure with finger-like pores in which the surface roughness declined by adding different dosages of LaVO3 nanosheets. Contact angle measurements proved that the hydrophilicity of the nanocomposite membranes significantly increased. Furthermore, the water flux of the resulting nanocomposite membranes markedly enhanced due to the nanosheets incorporation. Moreover, nanocomposite membranes showed remarkable antifouling properties (flux recovery ratio ~85%) in contrast with the bare PES (flux recovery ratio ~60%). The high retention of Solazol Red SP-3B (~99%) and Bovine serum albumin (BSA) (~99%) as well as the high permeation flux of the fabricated membrane unveiled the multifunctional character of the nanocomposite membrane for purification of dyes and proteins. |
| first_indexed | 2024-12-20T00:12:13Z |
| format | Article |
| id | doaj.art-451cba3a3d1d49638ef3fca7fbe590ff |
| institution | Directory Open Access Journal |
| issn | 0142-9418 |
| language | English |
| last_indexed | 2024-12-20T00:12:13Z |
| publishDate | 2021-02-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Polymer Testing |
| spelling | doaj.art-451cba3a3d1d49638ef3fca7fbe590ff2022-12-21T20:00:28ZengElsevierPolymer Testing0142-94182021-02-0194107040Nanostructured polyethersulfone nanocomposite membranes for dual protein and dye separation: Lower antifouling with lanthanum (III) vanadate nanosheets as a novel nanofillerVahid Vatanpour0Yaghoub Mansourpanah1Seyed Soroush Mousavi Khadem2Sirus Zinadini3Nadir Dizge4Mohammad Reza Ganjali5Somayeh Mirsadeghi6Morteza Rezapour7Mohammad Reza Saeb8Hassan Karimi-Male9Department of Applied Chemistry, Faculty of Chemistry, Kharazmi University, Tehran, Iran; Corresponding author.Membrane Research Laboratory, Lorestan University, Khorramabad, 68137-17133, IranCenter of Excellence in Electrochemistry, School of Chemistry, College of Science, University of Tehran, Tehran, IranWater and Wastewater Research Center (WWRC), Department of Applied Chemistry, Faculty of Chemistry, Razi University, Kermanshah, IranDepartment of Environmental Engineering, Mersin University, Mersin, 33343, TurkeyCenter of Excellence in Electrochemistry, School of Chemistry, College of Science, University of Tehran, Tehran, Iran; Biosensor Research Center, Endocrinology and Metabolism Molecular-Cellular Sciences Institute, Tehran University of Medical Sciences, Tehran, Iran; Corresponding author. Center of Excellence in Electrochemistry, School of Chemistry, College of Science, University of Tehran, Tehran, Iran.Endocrinology and Metabolism Center, Endocrinology and Metabolism Clinical Medical Institute, Tehran University of Medical Science, 1411713137, Tehran, IranIP Department, Research Institute of Petroleum Industry (RIPI), Tehran, P.O.BOX, 14665-137, IranCenter of Excellence in Electrochemistry, School of Chemistry, College of Science, University of Tehran, Tehran, IranSchool of Resources and Environment, University of Electronic Science and Technology of China, P.O. Box, 611731, Xiyuan Ave, Chengdu, PR ChinaA novel polyethersulfone (PES) nanocomposite membrane incorporated with lanthanum vanadate (LaVO3) nanosheets was fabricated based on phase inversion approach. The morphology and the performance of the fabricated nanocomposite membranes were systematically studied by ATR-FTIR, SEM, AFM, porosity, water contact angle, antifouling and rejection measurements. The resulting membranes showed an asymmetric structure with finger-like pores in which the surface roughness declined by adding different dosages of LaVO3 nanosheets. Contact angle measurements proved that the hydrophilicity of the nanocomposite membranes significantly increased. Furthermore, the water flux of the resulting nanocomposite membranes markedly enhanced due to the nanosheets incorporation. Moreover, nanocomposite membranes showed remarkable antifouling properties (flux recovery ratio ~85%) in contrast with the bare PES (flux recovery ratio ~60%). The high retention of Solazol Red SP-3B (~99%) and Bovine serum albumin (BSA) (~99%) as well as the high permeation flux of the fabricated membrane unveiled the multifunctional character of the nanocomposite membrane for purification of dyes and proteins.http://www.sciencedirect.com/science/article/pii/S0142941820322698Vanadate nanosheetsNanocomposite membraneDye removalProtein separationFlux recovery |
| spellingShingle | Vahid Vatanpour Yaghoub Mansourpanah Seyed Soroush Mousavi Khadem Sirus Zinadini Nadir Dizge Mohammad Reza Ganjali Somayeh Mirsadeghi Morteza Rezapour Mohammad Reza Saeb Hassan Karimi-Male Nanostructured polyethersulfone nanocomposite membranes for dual protein and dye separation: Lower antifouling with lanthanum (III) vanadate nanosheets as a novel nanofiller Polymer Testing Vanadate nanosheets Nanocomposite membrane Dye removal Protein separation Flux recovery |
| title | Nanostructured polyethersulfone nanocomposite membranes for dual protein and dye separation: Lower antifouling with lanthanum (III) vanadate nanosheets as a novel nanofiller |
| title_full | Nanostructured polyethersulfone nanocomposite membranes for dual protein and dye separation: Lower antifouling with lanthanum (III) vanadate nanosheets as a novel nanofiller |
| title_fullStr | Nanostructured polyethersulfone nanocomposite membranes for dual protein and dye separation: Lower antifouling with lanthanum (III) vanadate nanosheets as a novel nanofiller |
| title_full_unstemmed | Nanostructured polyethersulfone nanocomposite membranes for dual protein and dye separation: Lower antifouling with lanthanum (III) vanadate nanosheets as a novel nanofiller |
| title_short | Nanostructured polyethersulfone nanocomposite membranes for dual protein and dye separation: Lower antifouling with lanthanum (III) vanadate nanosheets as a novel nanofiller |
| title_sort | nanostructured polyethersulfone nanocomposite membranes for dual protein and dye separation lower antifouling with lanthanum iii vanadate nanosheets as a novel nanofiller |
| topic | Vanadate nanosheets Nanocomposite membrane Dye removal Protein separation Flux recovery |
| url | http://www.sciencedirect.com/science/article/pii/S0142941820322698 |
| work_keys_str_mv | AT vahidvatanpour nanostructuredpolyethersulfonenanocompositemembranesfordualproteinanddyeseparationlowerantifoulingwithlanthanumiiivanadatenanosheetsasanovelnanofiller AT yaghoubmansourpanah nanostructuredpolyethersulfonenanocompositemembranesfordualproteinanddyeseparationlowerantifoulingwithlanthanumiiivanadatenanosheetsasanovelnanofiller AT seyedsoroushmousavikhadem nanostructuredpolyethersulfonenanocompositemembranesfordualproteinanddyeseparationlowerantifoulingwithlanthanumiiivanadatenanosheetsasanovelnanofiller AT siruszinadini nanostructuredpolyethersulfonenanocompositemembranesfordualproteinanddyeseparationlowerantifoulingwithlanthanumiiivanadatenanosheetsasanovelnanofiller AT nadirdizge nanostructuredpolyethersulfonenanocompositemembranesfordualproteinanddyeseparationlowerantifoulingwithlanthanumiiivanadatenanosheetsasanovelnanofiller AT mohammadrezaganjali nanostructuredpolyethersulfonenanocompositemembranesfordualproteinanddyeseparationlowerantifoulingwithlanthanumiiivanadatenanosheetsasanovelnanofiller AT somayehmirsadeghi nanostructuredpolyethersulfonenanocompositemembranesfordualproteinanddyeseparationlowerantifoulingwithlanthanumiiivanadatenanosheetsasanovelnanofiller AT mortezarezapour nanostructuredpolyethersulfonenanocompositemembranesfordualproteinanddyeseparationlowerantifoulingwithlanthanumiiivanadatenanosheetsasanovelnanofiller AT mohammadrezasaeb nanostructuredpolyethersulfonenanocompositemembranesfordualproteinanddyeseparationlowerantifoulingwithlanthanumiiivanadatenanosheetsasanovelnanofiller AT hassankarimimale nanostructuredpolyethersulfonenanocompositemembranesfordualproteinanddyeseparationlowerantifoulingwithlanthanumiiivanadatenanosheetsasanovelnanofiller |