Improving cost-efficiency for MPs density separation by zinc chloride reuse

The methodology used to extract and quantify microplastics (MPs) in aquatic systems are still not standardized. Salt saturated solutions, such as sodium chloride (NaCl), zinc chloride (ZnCl2) and/or sodium iodide (NaI), are normally added to separate dense plastics from aquatic samples. However, the...

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Main Authors: M.O. Rodrigues, A.M.M. Gonçalves, F.J.M. Gonçalves, N. Abrantes
Format: Article
Language:English
Published: Elsevier 2020-01-01
Series:MethodsX
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2215016120300054
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author M.O. Rodrigues
A.M.M. Gonçalves
F.J.M. Gonçalves
N. Abrantes
author_facet M.O. Rodrigues
A.M.M. Gonçalves
F.J.M. Gonçalves
N. Abrantes
author_sort M.O. Rodrigues
collection DOAJ
description The methodology used to extract and quantify microplastics (MPs) in aquatic systems are still not standardized. Salt saturated solutions, such as sodium chloride (NaCl), zinc chloride (ZnCl2) and/or sodium iodide (NaI), are normally added to separate dense plastics from aquatic samples. However, the most effective reagents are also the most expensive (e.g. ZnCl2 and NaI). To decrease this cost, a reuse process of the salt solutions should be applied. The reuse process has been widely investigated for the NaI solution neglecting the ZnCl2. Hence, the aim of this study was to present a simple methodology to reuse the ZnCl2 solution ensuring the efficiency of the product. Results of the present study showed that ZnCl2 solution could be reused at least five times maintaining an efficiency above 95 %. • The ZnCl2 reuse decreases the cost of the methodology. • The efficiency of ZnCl2 solution after five filtrations remains above 95 % (all polymers are detected and recovered). • The use of this salt solution is the most cost-effective methodology to isolate MPs from aquatic samples.
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spelling doaj.art-45305a08587b4bbd99d1903d4d3da32b2022-12-21T19:02:21ZengElsevierMethodsX2215-01612020-01-017100785Improving cost-efficiency for MPs density separation by zinc chloride reuseM.O. Rodrigues0A.M.M. Gonçalves1F.J.M. Gonçalves2N. Abrantes3Department of Biology & CESAM, University of Aveiro, 3810-193, Aveiro, Portugal; Corresponding author.Department of Biology & CESAM, University of Aveiro, 3810-193, Aveiro, Portugal; MARE, Department of Life Sciences, Faculty of Sciences and Technology, University of Coimbra, 3004-517, Coimbra, PortugalDepartment of Biology & CESAM, University of Aveiro, 3810-193, Aveiro, PortugalDepartment of Environment and Planning & CESAM, University of Aveiro, 3810-193, Aveiro, PortugalThe methodology used to extract and quantify microplastics (MPs) in aquatic systems are still not standardized. Salt saturated solutions, such as sodium chloride (NaCl), zinc chloride (ZnCl2) and/or sodium iodide (NaI), are normally added to separate dense plastics from aquatic samples. However, the most effective reagents are also the most expensive (e.g. ZnCl2 and NaI). To decrease this cost, a reuse process of the salt solutions should be applied. The reuse process has been widely investigated for the NaI solution neglecting the ZnCl2. Hence, the aim of this study was to present a simple methodology to reuse the ZnCl2 solution ensuring the efficiency of the product. Results of the present study showed that ZnCl2 solution could be reused at least five times maintaining an efficiency above 95 %. • The ZnCl2 reuse decreases the cost of the methodology. • The efficiency of ZnCl2 solution after five filtrations remains above 95 % (all polymers are detected and recovered). • The use of this salt solution is the most cost-effective methodology to isolate MPs from aquatic samples.http://www.sciencedirect.com/science/article/pii/S2215016120300054MicroplasticsSeparation methodologyZinc chlorideAquatic systemsReuse process
spellingShingle M.O. Rodrigues
A.M.M. Gonçalves
F.J.M. Gonçalves
N. Abrantes
Improving cost-efficiency for MPs density separation by zinc chloride reuse
MethodsX
Microplastics
Separation methodology
Zinc chloride
Aquatic systems
Reuse process
title Improving cost-efficiency for MPs density separation by zinc chloride reuse
title_full Improving cost-efficiency for MPs density separation by zinc chloride reuse
title_fullStr Improving cost-efficiency for MPs density separation by zinc chloride reuse
title_full_unstemmed Improving cost-efficiency for MPs density separation by zinc chloride reuse
title_short Improving cost-efficiency for MPs density separation by zinc chloride reuse
title_sort improving cost efficiency for mps density separation by zinc chloride reuse
topic Microplastics
Separation methodology
Zinc chloride
Aquatic systems
Reuse process
url http://www.sciencedirect.com/science/article/pii/S2215016120300054
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