Dibromidobis{1-[4-(pyridin-4-yl)phenyl]ethanone-κN}mercury(II)
In the title compound, [HgBr2(C13H11NO)2], the HgII atom adopts a four-coordinated HgN2Br2 geometry, formed by two pyridine N atoms from two ligands and two bromide anions. The complex is located on a twofold axis. The coordination geometry is close to forming a see-saw (SS-4) polyhedron, the symmet...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811049993 |
| _version_ | 1819294000762322944 |
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| author | Wen-Shen Zhang Zhi-Juan Liu Feng Xu Qi-Ning Xun |
| author_facet | Wen-Shen Zhang Zhi-Juan Liu Feng Xu Qi-Ning Xun |
| author_sort | Wen-Shen Zhang |
| collection | DOAJ |
| description | In the title compound, [HgBr2(C13H11NO)2], the HgII atom adopts a four-coordinated HgN2Br2 geometry, formed by two pyridine N atoms from two ligands and two bromide anions. The complex is located on a twofold axis. The coordination geometry is close to forming a see-saw (SS-4) polyhedron, the symmetry-related organic ligands being almost perpendicular; the dihedral angles between the two pyridine rings and between the two benzene rings are 85.5 (4) and 87.7 (4)°, respectively. Within the organic ligand, the pyridine ring is nearly coplanar with the benzene ring [dihedral angle = 13.1 (8)°]. In the crystal, the molecular complexes are connected through weak intermolecular C—H...Br contacts. |
| first_indexed | 2024-12-24T04:19:22Z |
| format | Article |
| id | doaj.art-454a56f3073f4c059491288e8caeb242 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T04:19:22Z |
| publishDate | 2011-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-454a56f3073f4c059491288e8caeb2422022-12-21T17:15:50ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712m1849m184910.1107/S1600536811049993Dibromidobis{1-[4-(pyridin-4-yl)phenyl]ethanone-κN}mercury(II)Wen-Shen ZhangZhi-Juan LiuFeng XuQi-Ning XunIn the title compound, [HgBr2(C13H11NO)2], the HgII atom adopts a four-coordinated HgN2Br2 geometry, formed by two pyridine N atoms from two ligands and two bromide anions. The complex is located on a twofold axis. The coordination geometry is close to forming a see-saw (SS-4) polyhedron, the symmetry-related organic ligands being almost perpendicular; the dihedral angles between the two pyridine rings and between the two benzene rings are 85.5 (4) and 87.7 (4)°, respectively. Within the organic ligand, the pyridine ring is nearly coplanar with the benzene ring [dihedral angle = 13.1 (8)°]. In the crystal, the molecular complexes are connected through weak intermolecular C—H...Br contacts.http://scripts.iucr.org/cgi-bin/paper?S1600536811049993 |
| spellingShingle | Wen-Shen Zhang Zhi-Juan Liu Feng Xu Qi-Ning Xun Dibromidobis{1-[4-(pyridin-4-yl)phenyl]ethanone-κN}mercury(II) Acta Crystallographica Section E |
| title | Dibromidobis{1-[4-(pyridin-4-yl)phenyl]ethanone-κN}mercury(II) |
| title_full | Dibromidobis{1-[4-(pyridin-4-yl)phenyl]ethanone-κN}mercury(II) |
| title_fullStr | Dibromidobis{1-[4-(pyridin-4-yl)phenyl]ethanone-κN}mercury(II) |
| title_full_unstemmed | Dibromidobis{1-[4-(pyridin-4-yl)phenyl]ethanone-κN}mercury(II) |
| title_short | Dibromidobis{1-[4-(pyridin-4-yl)phenyl]ethanone-κN}mercury(II) |
| title_sort | dibromidobis 1 4 pyridin 4 yl phenyl ethanone amp 954 n mercury ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811049993 |
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