Reduction and Elimination of Humic Acid Fouling in Air Sparged Membrane Distillation Using Nanocarbon Immobilized Membrane

In this paper, we present the treatment of humic acid solution via carbon nanotube immobilized membrane (CNIM) distillation assisted by air sparging (AS). Carbon nanotubes offer excellent hydrophobicity to the modified membrane surface and actively transport water vapor molecules through the membran...

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Main Authors: Mitun Chandra Bhoumick, Sagar Roy, Somenath Mitra
Format: Article
Language:English
Published: MDPI AG 2022-05-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/27/9/2896
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author Mitun Chandra Bhoumick
Sagar Roy
Somenath Mitra
author_facet Mitun Chandra Bhoumick
Sagar Roy
Somenath Mitra
author_sort Mitun Chandra Bhoumick
collection DOAJ
description In this paper, we present the treatment of humic acid solution via carbon nanotube immobilized membrane (CNIM) distillation assisted by air sparging (AS). Carbon nanotubes offer excellent hydrophobicity to the modified membrane surface and actively transport water vapor molecules through the membrane to generate higher vapor flux and better rejection of humic acid. The introduction of air sparging in the membrane distillation (MD) system has changed the humic substance fouling by changing the colloidal behavior of the deposits. This modified MD system can sustain a higher run time of separation and has enhanced the evaporation efficiency by 20% more than the regular membrane distillation. The air sparging has reduced the deposition by 30% in weight and offered lesser fouling of membrane surface even after a longer operating cycle. The water vapor flux increased with temperature and decreased as the volumetric concentrating factor (VCF) increased. The mass transfer coefficient was found to be the highest for the air sparged—carbon nanotube immobilized membrane (AS-CNIM) integrated membrane distillation. While the highest change in mass transfer coefficient (MTC) was found for polytetrafluoroethylene (PTFE) membrane with air sparging at 70 °C.
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spelling doaj.art-4557e22f8db5439db60023c4d596c96e2023-11-23T08:51:16ZengMDPI AGMolecules1420-30492022-05-01279289610.3390/molecules27092896Reduction and Elimination of Humic Acid Fouling in Air Sparged Membrane Distillation Using Nanocarbon Immobilized MembraneMitun Chandra Bhoumick0Sagar Roy1Somenath Mitra2Department of Chemistry and Environmental Science, New Jersey Institute of Technology, Newark College of Engineering, University Heights, Newark, NJ 07102, USADepartment of Chemistry and Environmental Science, New Jersey Institute of Technology, Newark College of Engineering, University Heights, Newark, NJ 07102, USADepartment of Chemistry and Environmental Science, New Jersey Institute of Technology, Newark College of Engineering, University Heights, Newark, NJ 07102, USAIn this paper, we present the treatment of humic acid solution via carbon nanotube immobilized membrane (CNIM) distillation assisted by air sparging (AS). Carbon nanotubes offer excellent hydrophobicity to the modified membrane surface and actively transport water vapor molecules through the membrane to generate higher vapor flux and better rejection of humic acid. The introduction of air sparging in the membrane distillation (MD) system has changed the humic substance fouling by changing the colloidal behavior of the deposits. This modified MD system can sustain a higher run time of separation and has enhanced the evaporation efficiency by 20% more than the regular membrane distillation. The air sparging has reduced the deposition by 30% in weight and offered lesser fouling of membrane surface even after a longer operating cycle. The water vapor flux increased with temperature and decreased as the volumetric concentrating factor (VCF) increased. The mass transfer coefficient was found to be the highest for the air sparged—carbon nanotube immobilized membrane (AS-CNIM) integrated membrane distillation. While the highest change in mass transfer coefficient (MTC) was found for polytetrafluoroethylene (PTFE) membrane with air sparging at 70 °C.https://www.mdpi.com/1420-3049/27/9/2896air spargingmembrane foulingcarbon nanotubeshydrophobic membrane and evaporation efficiency
spellingShingle Mitun Chandra Bhoumick
Sagar Roy
Somenath Mitra
Reduction and Elimination of Humic Acid Fouling in Air Sparged Membrane Distillation Using Nanocarbon Immobilized Membrane
Molecules
air sparging
membrane fouling
carbon nanotubes
hydrophobic membrane and evaporation efficiency
title Reduction and Elimination of Humic Acid Fouling in Air Sparged Membrane Distillation Using Nanocarbon Immobilized Membrane
title_full Reduction and Elimination of Humic Acid Fouling in Air Sparged Membrane Distillation Using Nanocarbon Immobilized Membrane
title_fullStr Reduction and Elimination of Humic Acid Fouling in Air Sparged Membrane Distillation Using Nanocarbon Immobilized Membrane
title_full_unstemmed Reduction and Elimination of Humic Acid Fouling in Air Sparged Membrane Distillation Using Nanocarbon Immobilized Membrane
title_short Reduction and Elimination of Humic Acid Fouling in Air Sparged Membrane Distillation Using Nanocarbon Immobilized Membrane
title_sort reduction and elimination of humic acid fouling in air sparged membrane distillation using nanocarbon immobilized membrane
topic air sparging
membrane fouling
carbon nanotubes
hydrophobic membrane and evaporation efficiency
url https://www.mdpi.com/1420-3049/27/9/2896
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AT somenathmitra reductionandeliminationofhumicacidfoulinginairspargedmembranedistillationusingnanocarbonimmobilizedmembrane