EFFECT OF AMMONIA-ETHANOL MOLE RATIO ON THE SILICA NANOPARTICLES SYNTHESIZED FOR RHODAMINE B DYES ADSORPTION

Various ammonia-ethanol mole ratios were successfully used for the synthesis of silica nanoparticles for rhodamine B adsorption. This study aims to determine the characteristics of the adsorbent at different ammonia-ethanol mole ratios, maximum adsorption at pH, and contact time. Several steps, incl...

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Main Authors: Yayuk Puji Lestari, Amaria Amaria
Format: Article
Language:English
Published: Universitas Airlangga 2023-06-01
Series:Jurnal Kimia Riset
Subjects:
Online Access:https://e-journal.unair.ac.id/JKR/article/view/44400
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author Yayuk Puji Lestari
Amaria Amaria
author_facet Yayuk Puji Lestari
Amaria Amaria
author_sort Yayuk Puji Lestari
collection DOAJ
description Various ammonia-ethanol mole ratios were successfully used for the synthesis of silica nanoparticles for rhodamine B adsorption. This study aims to determine the characteristics of the adsorbent at different ammonia-ethanol mole ratios, maximum adsorption at pH, and contact time. Several steps, including extraction of Na2SiO3 from rice husk ash, synthesis of adsorbents with ammonia-ethanol mole ratios (14:1, 21:1, 28:1, and 42:1), and their characterization. The parameters studied in the adsorbent include the functional groups, particle size, maximum pH, and rate constant adsorption. The FTIR results showed that all adsorbents had functional groups, indicating the presence of silica. The results suggest that the optimum mole ratio of NS 14:1 particles has a size of 39.82 nm. The optimum adsorption of rhodamine B by NS 14:1 occurred at a pH 3 of 0.00419 mmol.g-1 and a contact time of 40 min. The rate constant of adsorption by NS 14:1 was 102.42 g.mmol-1.min-1 followed a pseudo-second order kinetic model.
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spelling doaj.art-455d824717844a8c8cb43e47b7c682302023-07-04T02:26:30ZengUniversitas AirlanggaJurnal Kimia Riset2528-04142528-04222023-06-01819210410.20473/jkr.v8i1.4440042482EFFECT OF AMMONIA-ETHANOL MOLE RATIO ON THE SILICA NANOPARTICLES SYNTHESIZED FOR RHODAMINE B DYES ADSORPTIONYayuk Puji Lestari0Amaria Amaria1Universitas Negeri SurabayaUniversitas Negeri SurabayaVarious ammonia-ethanol mole ratios were successfully used for the synthesis of silica nanoparticles for rhodamine B adsorption. This study aims to determine the characteristics of the adsorbent at different ammonia-ethanol mole ratios, maximum adsorption at pH, and contact time. Several steps, including extraction of Na2SiO3 from rice husk ash, synthesis of adsorbents with ammonia-ethanol mole ratios (14:1, 21:1, 28:1, and 42:1), and their characterization. The parameters studied in the adsorbent include the functional groups, particle size, maximum pH, and rate constant adsorption. The FTIR results showed that all adsorbents had functional groups, indicating the presence of silica. The results suggest that the optimum mole ratio of NS 14:1 particles has a size of 39.82 nm. The optimum adsorption of rhodamine B by NS 14:1 occurred at a pH 3 of 0.00419 mmol.g-1 and a contact time of 40 min. The rate constant of adsorption by NS 14:1 was 102.42 g.mmol-1.min-1 followed a pseudo-second order kinetic model.https://e-journal.unair.ac.id/JKR/article/view/44400adsorptionrhodamine bsilica nanoparticles
spellingShingle Yayuk Puji Lestari
Amaria Amaria
EFFECT OF AMMONIA-ETHANOL MOLE RATIO ON THE SILICA NANOPARTICLES SYNTHESIZED FOR RHODAMINE B DYES ADSORPTION
Jurnal Kimia Riset
adsorption
rhodamine b
silica nanoparticles
title EFFECT OF AMMONIA-ETHANOL MOLE RATIO ON THE SILICA NANOPARTICLES SYNTHESIZED FOR RHODAMINE B DYES ADSORPTION
title_full EFFECT OF AMMONIA-ETHANOL MOLE RATIO ON THE SILICA NANOPARTICLES SYNTHESIZED FOR RHODAMINE B DYES ADSORPTION
title_fullStr EFFECT OF AMMONIA-ETHANOL MOLE RATIO ON THE SILICA NANOPARTICLES SYNTHESIZED FOR RHODAMINE B DYES ADSORPTION
title_full_unstemmed EFFECT OF AMMONIA-ETHANOL MOLE RATIO ON THE SILICA NANOPARTICLES SYNTHESIZED FOR RHODAMINE B DYES ADSORPTION
title_short EFFECT OF AMMONIA-ETHANOL MOLE RATIO ON THE SILICA NANOPARTICLES SYNTHESIZED FOR RHODAMINE B DYES ADSORPTION
title_sort effect of ammonia ethanol mole ratio on the silica nanoparticles synthesized for rhodamine b dyes adsorption
topic adsorption
rhodamine b
silica nanoparticles
url https://e-journal.unair.ac.id/JKR/article/view/44400
work_keys_str_mv AT yayukpujilestari effectofammoniaethanolmoleratioonthesilicananoparticlessynthesizedforrhodaminebdyesadsorption
AT amariaamaria effectofammoniaethanolmoleratioonthesilicananoparticlessynthesizedforrhodaminebdyesadsorption