Palladium-coated thiourea core-shell nanocomposite as a new, efficient, and magnetic responsive nanocatalyst for the Suzuki-Miyaura coupling reactions
In this research, according to the important aspects of palladium components in conducting Suzuki-Miyaura coupling reactions and formation of biphenyl compounds, magnetic responsive palladium/thiourea nanocomposite as a new magnetic nanocatalyst was designed, synthesized, and characterized using FT-...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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IOP Publishing
2021-01-01
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| Series: | Materials Research Express |
| Subjects: | |
| Online Access: | https://doi.org/10.1088/2053-1591/abe320 |
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| author | Reza Eivazzadeh-Keihan Negar Bahrami Fateme Radinekiyan Ali Maleki Mohammad Mahdavi |
| author_facet | Reza Eivazzadeh-Keihan Negar Bahrami Fateme Radinekiyan Ali Maleki Mohammad Mahdavi |
| author_sort | Reza Eivazzadeh-Keihan |
| collection | DOAJ |
| description | In this research, according to the important aspects of palladium components in conducting Suzuki-Miyaura coupling reactions and formation of biphenyl compounds, magnetic responsive palladium/thiourea nanocomposite as a new magnetic nanocatalyst was designed, synthesized, and characterized using FT-IR, EDX, FE-SEM, and VSM analyses. The catalytic performance of this new nanocomposite with magnetic susceptibility was evaluated in the Suzuki-Miyaura coupling reaction. Based on the functionalized surface of Fe _3 O _4 magnetic cores with SiO _2 , CPTMS, thiourea shells, and especially Palladium ions shell, the formation of biphenyl derivatives in a green and eco-friendly reaction condition was highlighted. |
| first_indexed | 2024-03-12T15:41:02Z |
| format | Article |
| id | doaj.art-45676eaf881945b4a33b047fa074562f |
| institution | Directory Open Access Journal |
| issn | 2053-1591 |
| language | English |
| last_indexed | 2024-03-12T15:41:02Z |
| publishDate | 2021-01-01 |
| publisher | IOP Publishing |
| record_format | Article |
| series | Materials Research Express |
| spelling | doaj.art-45676eaf881945b4a33b047fa074562f2023-08-09T15:58:29ZengIOP PublishingMaterials Research Express2053-15912021-01-018202610210.1088/2053-1591/abe320Palladium-coated thiourea core-shell nanocomposite as a new, efficient, and magnetic responsive nanocatalyst for the Suzuki-Miyaura coupling reactionsReza Eivazzadeh-Keihan0Negar Bahrami1Fateme Radinekiyan2Ali Maleki3https://orcid.org/0000-0001-5490-3350Mohammad Mahdavi4Catalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and Technology , Tehran 16846-13114, IranCatalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and Technology , Tehran 16846-13114, IranCatalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and Technology , Tehran 16846-13114, IranCatalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and Technology , Tehran 16846-13114, IranEndocrinology and Metabolism Research Center, Endocrinology and Metabolism Clinical Sciences Institute, Tehran University of Medical Sciences , Tehran, IranIn this research, according to the important aspects of palladium components in conducting Suzuki-Miyaura coupling reactions and formation of biphenyl compounds, magnetic responsive palladium/thiourea nanocomposite as a new magnetic nanocatalyst was designed, synthesized, and characterized using FT-IR, EDX, FE-SEM, and VSM analyses. The catalytic performance of this new nanocomposite with magnetic susceptibility was evaluated in the Suzuki-Miyaura coupling reaction. Based on the functionalized surface of Fe _3 O _4 magnetic cores with SiO _2 , CPTMS, thiourea shells, and especially Palladium ions shell, the formation of biphenyl derivatives in a green and eco-friendly reaction condition was highlighted.https://doi.org/10.1088/2053-1591/abe320Suzuki-Miyaura coupling reactionFunctionalized Fe3O4 magnetic nanoparticlesthioureapalladiummagnetic responsive catalyst |
| spellingShingle | Reza Eivazzadeh-Keihan Negar Bahrami Fateme Radinekiyan Ali Maleki Mohammad Mahdavi Palladium-coated thiourea core-shell nanocomposite as a new, efficient, and magnetic responsive nanocatalyst for the Suzuki-Miyaura coupling reactions Materials Research Express Suzuki-Miyaura coupling reaction Functionalized Fe3O4 magnetic nanoparticles thiourea palladium magnetic responsive catalyst |
| title | Palladium-coated thiourea core-shell nanocomposite as a new, efficient, and magnetic responsive nanocatalyst for the Suzuki-Miyaura coupling reactions |
| title_full | Palladium-coated thiourea core-shell nanocomposite as a new, efficient, and magnetic responsive nanocatalyst for the Suzuki-Miyaura coupling reactions |
| title_fullStr | Palladium-coated thiourea core-shell nanocomposite as a new, efficient, and magnetic responsive nanocatalyst for the Suzuki-Miyaura coupling reactions |
| title_full_unstemmed | Palladium-coated thiourea core-shell nanocomposite as a new, efficient, and magnetic responsive nanocatalyst for the Suzuki-Miyaura coupling reactions |
| title_short | Palladium-coated thiourea core-shell nanocomposite as a new, efficient, and magnetic responsive nanocatalyst for the Suzuki-Miyaura coupling reactions |
| title_sort | palladium coated thiourea core shell nanocomposite as a new efficient and magnetic responsive nanocatalyst for the suzuki miyaura coupling reactions |
| topic | Suzuki-Miyaura coupling reaction Functionalized Fe3O4 magnetic nanoparticles thiourea palladium magnetic responsive catalyst |
| url | https://doi.org/10.1088/2053-1591/abe320 |
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