Synthesis and Crystal Structure of Chlorido-Bridged Binuclear Copper(I) Complexes with Carbodithioate-Type Ligands
The CuCl binuclear complexes were synthesized with phenyl-1<i>H</i>-pyrazole-1-carbodithioate (<b>L<sup>1</sup></b>) and phenyl-3-methyl-1<i>H</i>-pyrazole-1-carbodithioate (<b>L<sup>2</sup></b>) ligands. The complexes were isol...
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MDPI AG
2023-02-01
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| Series: | Crystals |
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| Online Access: | https://www.mdpi.com/2073-4352/13/2/322 |
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| author | Sher Ali Khan Ezzat Khan Sadaf Qayyum Awal Noor |
| author_facet | Sher Ali Khan Ezzat Khan Sadaf Qayyum Awal Noor |
| author_sort | Sher Ali Khan |
| collection | DOAJ |
| description | The CuCl binuclear complexes were synthesized with phenyl-1<i>H</i>-pyrazole-1-carbodithioate (<b>L<sup>1</sup></b>) and phenyl-3-methyl-1<i>H</i>-pyrazole-1-carbodithioate (<b>L<sup>2</sup></b>) ligands. The complexes were isolated as crystalline material in a reasonable quantity. The complexes were crystallized in acetonitrile (MeCN) and characterized for their single crystal, using X-ray diffraction. The two units with the general formula LCuCl are bridged together via chlorido ligands, affording (LCuCl)<sub>2-</sub>type complexes. The complexes, [Cu<sub>2</sub>(μ-Cl)<sub>2</sub>(L<sup>1</sup>)<sub>2</sub>] <b>1</b> and [Cu<sub>2</sub>(μ-Cl)<sub>2</sub>(L<sup>2</sup>)<sub>2</sub>] <b>2</b> are monoclinic and triclinic with space group <i>P</i>2<sub>1</sub><i>/n</i> and <i>Pi</i>, respectively. The crystal packing is stabilized by C1(p)⋯C(p) and S⋯C(p) interactions extended in 2D fashion in complex <b>1,</b> while complex <b>2</b> is stabilized by C(p)⋯S interactions extended in a 1D fashion. Structural features and secondary interactions present in both complexes discussed in this article. |
| first_indexed | 2024-03-11T08:57:47Z |
| format | Article |
| id | doaj.art-457d3f366392438aaff47376fdbbdb0c |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-03-11T08:57:47Z |
| publishDate | 2023-02-01 |
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| record_format | Article |
| series | Crystals |
| spelling | doaj.art-457d3f366392438aaff47376fdbbdb0c2023-11-16T19:56:37ZengMDPI AGCrystals2073-43522023-02-0113232210.3390/cryst13020322Synthesis and Crystal Structure of Chlorido-Bridged Binuclear Copper(I) Complexes with Carbodithioate-Type LigandsSher Ali Khan0Ezzat Khan1Sadaf Qayyum2Awal Noor3Department of Chemistry, Government Postgraduate Jahanazeb College, Saidu Sharif 19130, PakistanDepartment of Chemistry, University of Malakand, Chakdara 18800, PakistanDepartment of Basic Sciences, Preparatory Year Deanship, King Faisal University, Al-Hassa 31982, Saudi ArabiaDepartment of Basic Sciences, Preparatory Year Deanship, King Faisal University, Al-Hassa 31982, Saudi ArabiaThe CuCl binuclear complexes were synthesized with phenyl-1<i>H</i>-pyrazole-1-carbodithioate (<b>L<sup>1</sup></b>) and phenyl-3-methyl-1<i>H</i>-pyrazole-1-carbodithioate (<b>L<sup>2</sup></b>) ligands. The complexes were isolated as crystalline material in a reasonable quantity. The complexes were crystallized in acetonitrile (MeCN) and characterized for their single crystal, using X-ray diffraction. The two units with the general formula LCuCl are bridged together via chlorido ligands, affording (LCuCl)<sub>2-</sub>type complexes. The complexes, [Cu<sub>2</sub>(μ-Cl)<sub>2</sub>(L<sup>1</sup>)<sub>2</sub>] <b>1</b> and [Cu<sub>2</sub>(μ-Cl)<sub>2</sub>(L<sup>2</sup>)<sub>2</sub>] <b>2</b> are monoclinic and triclinic with space group <i>P</i>2<sub>1</sub><i>/n</i> and <i>Pi</i>, respectively. The crystal packing is stabilized by C1(p)⋯C(p) and S⋯C(p) interactions extended in 2D fashion in complex <b>1,</b> while complex <b>2</b> is stabilized by C(p)⋯S interactions extended in a 1D fashion. Structural features and secondary interactions present in both complexes discussed in this article.https://www.mdpi.com/2073-4352/13/2/322phenyl-1<i>H</i>-pyrazole-1-carbodithioate3-methyl-1<i>H</i>-pyrazole-1-carbodithioateCuchloride-bridgedcrystal structure2D extension |
| spellingShingle | Sher Ali Khan Ezzat Khan Sadaf Qayyum Awal Noor Synthesis and Crystal Structure of Chlorido-Bridged Binuclear Copper(I) Complexes with Carbodithioate-Type Ligands Crystals phenyl-1<i>H</i>-pyrazole-1-carbodithioate 3-methyl-1<i>H</i>-pyrazole-1-carbodithioate Cu chloride-bridged crystal structure 2D extension |
| title | Synthesis and Crystal Structure of Chlorido-Bridged Binuclear Copper(I) Complexes with Carbodithioate-Type Ligands |
| title_full | Synthesis and Crystal Structure of Chlorido-Bridged Binuclear Copper(I) Complexes with Carbodithioate-Type Ligands |
| title_fullStr | Synthesis and Crystal Structure of Chlorido-Bridged Binuclear Copper(I) Complexes with Carbodithioate-Type Ligands |
| title_full_unstemmed | Synthesis and Crystal Structure of Chlorido-Bridged Binuclear Copper(I) Complexes with Carbodithioate-Type Ligands |
| title_short | Synthesis and Crystal Structure of Chlorido-Bridged Binuclear Copper(I) Complexes with Carbodithioate-Type Ligands |
| title_sort | synthesis and crystal structure of chlorido bridged binuclear copper i complexes with carbodithioate type ligands |
| topic | phenyl-1<i>H</i>-pyrazole-1-carbodithioate 3-methyl-1<i>H</i>-pyrazole-1-carbodithioate Cu chloride-bridged crystal structure 2D extension |
| url | https://www.mdpi.com/2073-4352/13/2/322 |
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