Electrochemical Properties of Chlorine Dioxide Using Aminated Glassy Carbon Electrodes Fabricated by Electrolysis
Voltammetric properties of chlorine dioxide (ClO2) obtained by using a glassy carbon (GC) electrode fabricated by electrolyzing in ammonium carbamate aqueous solution were first reported. GC electrode surface was covalently modified with nitrogen atoms containing functional groups, which were introd...
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Language: | English |
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The Electrochemical Society of Japan
2020-09-01
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Series: | Electrochemistry |
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Online Access: | https://www.jstage.jst.go.jp/article/electrochemistry/88/5/88_20-64053/_pdf/-char/en |
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author | Motoyasu JINNAI Chihiro SHIMAMURA Satrio KUNTOLAKSONO Yutaro TOKOYO Susumu SATO Hiroaki MATSUURA |
author_facet | Motoyasu JINNAI Chihiro SHIMAMURA Satrio KUNTOLAKSONO Yutaro TOKOYO Susumu SATO Hiroaki MATSUURA |
author_sort | Motoyasu JINNAI |
collection | DOAJ |
description | Voltammetric properties of chlorine dioxide (ClO2) obtained by using a glassy carbon (GC) electrode fabricated by electrolyzing in ammonium carbamate aqueous solution were first reported. GC electrode surface was covalently modified with nitrogen atoms containing functional groups, which were introduced onto GC surfaces by electrochemical oxidation process in ammonium carbamate aqueous solution. The introduction of nitrogen into the GC surface structure enhanced the electrocatalytic activities of GC electrode towards the electro-oxidation of ClO2 in an acidic medium more than a bare GC electrode does. A favorable linearity for the peak current signals in cyclic voltammograms was exhibited in the concentration range from 2.0 to 100 ppm. |
first_indexed | 2024-04-11T02:19:13Z |
format | Article |
id | doaj.art-45a55be474484f859fe6aaf1e5116e8b |
institution | Directory Open Access Journal |
issn | 2186-2451 |
language | English |
last_indexed | 2024-04-11T02:19:13Z |
publishDate | 2020-09-01 |
publisher | The Electrochemical Society of Japan |
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series | Electrochemistry |
spelling | doaj.art-45a55be474484f859fe6aaf1e5116e8b2023-01-03T00:20:45ZengThe Electrochemical Society of JapanElectrochemistry2186-24512020-09-0188534734910.5796/electrochemistry.20-64053electrochemistryElectrochemical Properties of Chlorine Dioxide Using Aminated Glassy Carbon Electrodes Fabricated by ElectrolysisMotoyasu JINNAI0Chihiro SHIMAMURA1Satrio KUNTOLAKSONO2Yutaro TOKOYO3Susumu SATO4Hiroaki MATSUURA5Department of Information Systems, Graduate School of Engineering, Saitama Institute of TechnologyDepartment of Life Science & Green Chemistry, Graduate School of Engineering, Saitama Institute of TechnologyDepartment of Life Science & Green Chemistry, Graduate School of Engineering, Saitama Institute of TechnologyDepartment of Life Science & Green Chemistry, Faculty of Engineering, Saitama Institute of TechnologyDepartment of Information Systems, Graduate School of Engineering, Saitama Institute of TechnologyDepartment of Life Science & Green Chemistry, Graduate School of Engineering, Saitama Institute of TechnologyVoltammetric properties of chlorine dioxide (ClO2) obtained by using a glassy carbon (GC) electrode fabricated by electrolyzing in ammonium carbamate aqueous solution were first reported. GC electrode surface was covalently modified with nitrogen atoms containing functional groups, which were introduced onto GC surfaces by electrochemical oxidation process in ammonium carbamate aqueous solution. The introduction of nitrogen into the GC surface structure enhanced the electrocatalytic activities of GC electrode towards the electro-oxidation of ClO2 in an acidic medium more than a bare GC electrode does. A favorable linearity for the peak current signals in cyclic voltammograms was exhibited in the concentration range from 2.0 to 100 ppm.https://www.jstage.jst.go.jp/article/electrochemistry/88/5/88_20-64053/_pdf/-char/ennitrogen atoms containing functional groupselectrochemical modificationchlorine dioxideelectrocatalytic activity |
spellingShingle | Motoyasu JINNAI Chihiro SHIMAMURA Satrio KUNTOLAKSONO Yutaro TOKOYO Susumu SATO Hiroaki MATSUURA Electrochemical Properties of Chlorine Dioxide Using Aminated Glassy Carbon Electrodes Fabricated by Electrolysis Electrochemistry nitrogen atoms containing functional groups electrochemical modification chlorine dioxide electrocatalytic activity |
title | Electrochemical Properties of Chlorine Dioxide Using Aminated Glassy Carbon Electrodes Fabricated by Electrolysis |
title_full | Electrochemical Properties of Chlorine Dioxide Using Aminated Glassy Carbon Electrodes Fabricated by Electrolysis |
title_fullStr | Electrochemical Properties of Chlorine Dioxide Using Aminated Glassy Carbon Electrodes Fabricated by Electrolysis |
title_full_unstemmed | Electrochemical Properties of Chlorine Dioxide Using Aminated Glassy Carbon Electrodes Fabricated by Electrolysis |
title_short | Electrochemical Properties of Chlorine Dioxide Using Aminated Glassy Carbon Electrodes Fabricated by Electrolysis |
title_sort | electrochemical properties of chlorine dioxide using aminated glassy carbon electrodes fabricated by electrolysis |
topic | nitrogen atoms containing functional groups electrochemical modification chlorine dioxide electrocatalytic activity |
url | https://www.jstage.jst.go.jp/article/electrochemistry/88/5/88_20-64053/_pdf/-char/en |
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