Electrochemical Properties of Chlorine Dioxide Using Aminated Glassy Carbon Electrodes Fabricated by Electrolysis

Voltammetric properties of chlorine dioxide (ClO2) obtained by using a glassy carbon (GC) electrode fabricated by electrolyzing in ammonium carbamate aqueous solution were first reported. GC electrode surface was covalently modified with nitrogen atoms containing functional groups, which were introd...

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Main Authors: Motoyasu JINNAI, Chihiro SHIMAMURA, Satrio KUNTOLAKSONO, Yutaro TOKOYO, Susumu SATO, Hiroaki MATSUURA
Format: Article
Language:English
Published: The Electrochemical Society of Japan 2020-09-01
Series:Electrochemistry
Subjects:
Online Access:https://www.jstage.jst.go.jp/article/electrochemistry/88/5/88_20-64053/_pdf/-char/en
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author Motoyasu JINNAI
Chihiro SHIMAMURA
Satrio KUNTOLAKSONO
Yutaro TOKOYO
Susumu SATO
Hiroaki MATSUURA
author_facet Motoyasu JINNAI
Chihiro SHIMAMURA
Satrio KUNTOLAKSONO
Yutaro TOKOYO
Susumu SATO
Hiroaki MATSUURA
author_sort Motoyasu JINNAI
collection DOAJ
description Voltammetric properties of chlorine dioxide (ClO2) obtained by using a glassy carbon (GC) electrode fabricated by electrolyzing in ammonium carbamate aqueous solution were first reported. GC electrode surface was covalently modified with nitrogen atoms containing functional groups, which were introduced onto GC surfaces by electrochemical oxidation process in ammonium carbamate aqueous solution. The introduction of nitrogen into the GC surface structure enhanced the electrocatalytic activities of GC electrode towards the electro-oxidation of ClO2 in an acidic medium more than a bare GC electrode does. A favorable linearity for the peak current signals in cyclic voltammograms was exhibited in the concentration range from 2.0 to 100 ppm.
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language English
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publisher The Electrochemical Society of Japan
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spelling doaj.art-45a55be474484f859fe6aaf1e5116e8b2023-01-03T00:20:45ZengThe Electrochemical Society of JapanElectrochemistry2186-24512020-09-0188534734910.5796/electrochemistry.20-64053electrochemistryElectrochemical Properties of Chlorine Dioxide Using Aminated Glassy Carbon Electrodes Fabricated by ElectrolysisMotoyasu JINNAI0Chihiro SHIMAMURA1Satrio KUNTOLAKSONO2Yutaro TOKOYO3Susumu SATO4Hiroaki MATSUURA5Department of Information Systems, Graduate School of Engineering, Saitama Institute of TechnologyDepartment of Life Science & Green Chemistry, Graduate School of Engineering, Saitama Institute of TechnologyDepartment of Life Science & Green Chemistry, Graduate School of Engineering, Saitama Institute of TechnologyDepartment of Life Science & Green Chemistry, Faculty of Engineering, Saitama Institute of TechnologyDepartment of Information Systems, Graduate School of Engineering, Saitama Institute of TechnologyDepartment of Life Science & Green Chemistry, Graduate School of Engineering, Saitama Institute of TechnologyVoltammetric properties of chlorine dioxide (ClO2) obtained by using a glassy carbon (GC) electrode fabricated by electrolyzing in ammonium carbamate aqueous solution were first reported. GC electrode surface was covalently modified with nitrogen atoms containing functional groups, which were introduced onto GC surfaces by electrochemical oxidation process in ammonium carbamate aqueous solution. The introduction of nitrogen into the GC surface structure enhanced the electrocatalytic activities of GC electrode towards the electro-oxidation of ClO2 in an acidic medium more than a bare GC electrode does. A favorable linearity for the peak current signals in cyclic voltammograms was exhibited in the concentration range from 2.0 to 100 ppm.https://www.jstage.jst.go.jp/article/electrochemistry/88/5/88_20-64053/_pdf/-char/ennitrogen atoms containing functional groupselectrochemical modificationchlorine dioxideelectrocatalytic activity
spellingShingle Motoyasu JINNAI
Chihiro SHIMAMURA
Satrio KUNTOLAKSONO
Yutaro TOKOYO
Susumu SATO
Hiroaki MATSUURA
Electrochemical Properties of Chlorine Dioxide Using Aminated Glassy Carbon Electrodes Fabricated by Electrolysis
Electrochemistry
nitrogen atoms containing functional groups
electrochemical modification
chlorine dioxide
electrocatalytic activity
title Electrochemical Properties of Chlorine Dioxide Using Aminated Glassy Carbon Electrodes Fabricated by Electrolysis
title_full Electrochemical Properties of Chlorine Dioxide Using Aminated Glassy Carbon Electrodes Fabricated by Electrolysis
title_fullStr Electrochemical Properties of Chlorine Dioxide Using Aminated Glassy Carbon Electrodes Fabricated by Electrolysis
title_full_unstemmed Electrochemical Properties of Chlorine Dioxide Using Aminated Glassy Carbon Electrodes Fabricated by Electrolysis
title_short Electrochemical Properties of Chlorine Dioxide Using Aminated Glassy Carbon Electrodes Fabricated by Electrolysis
title_sort electrochemical properties of chlorine dioxide using aminated glassy carbon electrodes fabricated by electrolysis
topic nitrogen atoms containing functional groups
electrochemical modification
chlorine dioxide
electrocatalytic activity
url https://www.jstage.jst.go.jp/article/electrochemistry/88/5/88_20-64053/_pdf/-char/en
work_keys_str_mv AT motoyasujinnai electrochemicalpropertiesofchlorinedioxideusingaminatedglassycarbonelectrodesfabricatedbyelectrolysis
AT chihiroshimamura electrochemicalpropertiesofchlorinedioxideusingaminatedglassycarbonelectrodesfabricatedbyelectrolysis
AT satriokuntolaksono electrochemicalpropertiesofchlorinedioxideusingaminatedglassycarbonelectrodesfabricatedbyelectrolysis
AT yutarotokoyo electrochemicalpropertiesofchlorinedioxideusingaminatedglassycarbonelectrodesfabricatedbyelectrolysis
AT susumusato electrochemicalpropertiesofchlorinedioxideusingaminatedglassycarbonelectrodesfabricatedbyelectrolysis
AT hiroakimatsuura electrochemicalpropertiesofchlorinedioxideusingaminatedglassycarbonelectrodesfabricatedbyelectrolysis