ADSORPTION OF METHYLENE BLUE FROM AQUEOUS SOLUTION USING FREE AND IMMOBILIZED ALGAE CELLS

This study was aimed to investigate the potential adsorptive behavior of mixed algae for decolorization of methylene blue dye from aqueous solution in the form of free and immobilized. Effects of initial pH value (3-9), biosorbent dosage (0.02-0.5)g/L, and initial concentration (10-50) mg/L for dif...

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Main Authors: Raghad N. M, Abeer I. A
Format: Article
Language:English
Published: Baghdad University 2023-10-01
Series:The Iraqi Journal of Agricultural science
Subjects:
Online Access:https://jcoagri.uobaghdad.edu.iq/index.php/intro/article/view/1839
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author Raghad N. M
Abeer I. A
author_facet Raghad N. M
Abeer I. A
author_sort Raghad N. M
collection DOAJ
description This study was aimed to investigate the potential adsorptive behavior of mixed algae for decolorization of methylene blue dye from aqueous solution in the form of free and immobilized. Effects of initial pH value (3-9), biosorbent dosage (0.02-0.5)g/L, and initial concentration (10-50) mg/L for different contact time (0-180) min at 200 rpm shaking speed were investigated. In addition, experimental data were analyzed using adsorption (Langmuir and Freundlich) isotherms as well as kinetic models. The results demonstrated that the maximum decolorization percentage was 93% and 91% by free and immobilized algae, respectively for pH 6, 10 initial concentration, 0.3g/100mL algae dosage, and 90 min contact time. The results revealed that the Langmuir isotherm model was adequate for describing the dye removal process (R2= 0.99) for both forms. Results of pseudo-second order kinetic model revealed best fitting with the sorption data indicating that chemisorption process is the dominant mechanism controlling the dye removal. Furthermore, the characterization study performed using FT-IR and scanning electron micrograph techniques, revealed that the used algal biomass has good biosorption capabilities associated to active groups and surface structure and confirming that the immobilization was successful.
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spelling doaj.art-45c71b22c2f44d56a78b17b2c4b8ab8e2023-10-29T14:23:03ZengBaghdad UniversityThe Iraqi Journal of Agricultural science0075-05302410-08622023-10-0154510.36103/ijas.v54i5.1839ADSORPTION OF METHYLENE BLUE FROM AQUEOUS SOLUTION USING FREE AND IMMOBILIZED ALGAE CELLSRaghad N. MAbeer I. A This study was aimed to investigate the potential adsorptive behavior of mixed algae for decolorization of methylene blue dye from aqueous solution in the form of free and immobilized. Effects of initial pH value (3-9), biosorbent dosage (0.02-0.5)g/L, and initial concentration (10-50) mg/L for different contact time (0-180) min at 200 rpm shaking speed were investigated. In addition, experimental data were analyzed using adsorption (Langmuir and Freundlich) isotherms as well as kinetic models. The results demonstrated that the maximum decolorization percentage was 93% and 91% by free and immobilized algae, respectively for pH 6, 10 initial concentration, 0.3g/100mL algae dosage, and 90 min contact time. The results revealed that the Langmuir isotherm model was adequate for describing the dye removal process (R2= 0.99) for both forms. Results of pseudo-second order kinetic model revealed best fitting with the sorption data indicating that chemisorption process is the dominant mechanism controlling the dye removal. Furthermore, the characterization study performed using FT-IR and scanning electron micrograph techniques, revealed that the used algal biomass has good biosorption capabilities associated to active groups and surface structure and confirming that the immobilization was successful. https://jcoagri.uobaghdad.edu.iq/index.php/intro/article/view/1839methylene blue; mixed algae; adsorption; isotherm; kinetic; algae characteristics
spellingShingle Raghad N. M
Abeer I. A
ADSORPTION OF METHYLENE BLUE FROM AQUEOUS SOLUTION USING FREE AND IMMOBILIZED ALGAE CELLS
The Iraqi Journal of Agricultural science
methylene blue; mixed algae; adsorption; isotherm; kinetic; algae characteristics
title ADSORPTION OF METHYLENE BLUE FROM AQUEOUS SOLUTION USING FREE AND IMMOBILIZED ALGAE CELLS
title_full ADSORPTION OF METHYLENE BLUE FROM AQUEOUS SOLUTION USING FREE AND IMMOBILIZED ALGAE CELLS
title_fullStr ADSORPTION OF METHYLENE BLUE FROM AQUEOUS SOLUTION USING FREE AND IMMOBILIZED ALGAE CELLS
title_full_unstemmed ADSORPTION OF METHYLENE BLUE FROM AQUEOUS SOLUTION USING FREE AND IMMOBILIZED ALGAE CELLS
title_short ADSORPTION OF METHYLENE BLUE FROM AQUEOUS SOLUTION USING FREE AND IMMOBILIZED ALGAE CELLS
title_sort adsorption of methylene blue from aqueous solution using free and immobilized algae cells
topic methylene blue; mixed algae; adsorption; isotherm; kinetic; algae characteristics
url https://jcoagri.uobaghdad.edu.iq/index.php/intro/article/view/1839
work_keys_str_mv AT raghadnm adsorptionofmethylenebluefromaqueoussolutionusingfreeandimmobilizedalgaecells
AT abeeria adsorptionofmethylenebluefromaqueoussolutionusingfreeandimmobilizedalgaecells