Mild and Efficient Strontium Chloride Hexahydrate-Catalyzed Conversion of Ketones and Aldehydes into Corresponding gem- Dihydroperoxides by Aqueous H2O2

SrCl2·6H2O has been shown to act as an efficient catalyst for the conversion of aldehydes or ketones into the corresponding gem-dihydroperoxides (DHPs) by treatment with aqueous H2O2 (30%) in acetonitrile. The reactions proceed under mild and neutral conditions at room temperature to afford good to...

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Main Authors: Fatemeh Soleimanei, Kaveh Khosravi, Davood Azarifar
Format: Article
Language:English
Published: MDPI AG 2010-03-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/15/3/1433/
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author Fatemeh Soleimanei
Kaveh Khosravi
Davood Azarifar
author_facet Fatemeh Soleimanei
Kaveh Khosravi
Davood Azarifar
author_sort Fatemeh Soleimanei
collection DOAJ
description SrCl2·6H2O has been shown to act as an efficient catalyst for the conversion of aldehydes or ketones into the corresponding gem-dihydroperoxides (DHPs) by treatment with aqueous H2O2 (30%) in acetonitrile. The reactions proceed under mild and neutral conditions at room temperature to afford good to excellent yields of product.
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spelling doaj.art-45d4d936be5d42d79530162914f5701e2022-12-22T01:21:53ZengMDPI AGMolecules1420-30492010-03-011531433144110.3390/molecules15031433Mild and Efficient Strontium Chloride Hexahydrate-Catalyzed Conversion of Ketones and Aldehydes into Corresponding gem- Dihydroperoxides by Aqueous H2O2Fatemeh SoleimaneiKaveh KhosraviDavood AzarifarSrCl2·6H2O has been shown to act as an efficient catalyst for the conversion of aldehydes or ketones into the corresponding gem-dihydroperoxides (DHPs) by treatment with aqueous H2O2 (30%) in acetonitrile. The reactions proceed under mild and neutral conditions at room temperature to afford good to excellent yields of product.http://www.mdpi.com/1420-3049/15/3/1433/gem-dihydroperoxidestrontium chloride hexahydrateketonealdehydehydrogen peroxide
spellingShingle Fatemeh Soleimanei
Kaveh Khosravi
Davood Azarifar
Mild and Efficient Strontium Chloride Hexahydrate-Catalyzed Conversion of Ketones and Aldehydes into Corresponding gem- Dihydroperoxides by Aqueous H2O2
Molecules
gem-dihydroperoxide
strontium chloride hexahydrate
ketone
aldehyde
hydrogen peroxide
title Mild and Efficient Strontium Chloride Hexahydrate-Catalyzed Conversion of Ketones and Aldehydes into Corresponding gem- Dihydroperoxides by Aqueous H2O2
title_full Mild and Efficient Strontium Chloride Hexahydrate-Catalyzed Conversion of Ketones and Aldehydes into Corresponding gem- Dihydroperoxides by Aqueous H2O2
title_fullStr Mild and Efficient Strontium Chloride Hexahydrate-Catalyzed Conversion of Ketones and Aldehydes into Corresponding gem- Dihydroperoxides by Aqueous H2O2
title_full_unstemmed Mild and Efficient Strontium Chloride Hexahydrate-Catalyzed Conversion of Ketones and Aldehydes into Corresponding gem- Dihydroperoxides by Aqueous H2O2
title_short Mild and Efficient Strontium Chloride Hexahydrate-Catalyzed Conversion of Ketones and Aldehydes into Corresponding gem- Dihydroperoxides by Aqueous H2O2
title_sort mild and efficient strontium chloride hexahydrate catalyzed conversion of ketones and aldehydes into corresponding gem dihydroperoxides by aqueous h2o2
topic gem-dihydroperoxide
strontium chloride hexahydrate
ketone
aldehyde
hydrogen peroxide
url http://www.mdpi.com/1420-3049/15/3/1433/
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AT kavehkhosravi mildandefficientstrontiumchloridehexahydratecatalyzedconversionofketonesandaldehydesintocorrespondinggemdihydroperoxidesbyaqueoush2o2
AT davoodazarifar mildandefficientstrontiumchloridehexahydratecatalyzedconversionofketonesandaldehydesintocorrespondinggemdihydroperoxidesbyaqueoush2o2