Mild and Efficient Strontium Chloride Hexahydrate-Catalyzed Conversion of Ketones and Aldehydes into Corresponding gem- Dihydroperoxides by Aqueous H2O2
SrCl2·6H2O has been shown to act as an efficient catalyst for the conversion of aldehydes or ketones into the corresponding gem-dihydroperoxides (DHPs) by treatment with aqueous H2O2 (30%) in acetonitrile. The reactions proceed under mild and neutral conditions at room temperature to afford good to...
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MDPI AG
2010-03-01
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Series: | Molecules |
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Online Access: | http://www.mdpi.com/1420-3049/15/3/1433/ |
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author | Fatemeh Soleimanei Kaveh Khosravi Davood Azarifar |
author_facet | Fatemeh Soleimanei Kaveh Khosravi Davood Azarifar |
author_sort | Fatemeh Soleimanei |
collection | DOAJ |
description | SrCl2·6H2O has been shown to act as an efficient catalyst for the conversion of aldehydes or ketones into the corresponding gem-dihydroperoxides (DHPs) by treatment with aqueous H2O2 (30%) in acetonitrile. The reactions proceed under mild and neutral conditions at room temperature to afford good to excellent yields of product. |
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format | Article |
id | doaj.art-45d4d936be5d42d79530162914f5701e |
institution | Directory Open Access Journal |
issn | 1420-3049 |
language | English |
last_indexed | 2024-12-11T03:51:46Z |
publishDate | 2010-03-01 |
publisher | MDPI AG |
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series | Molecules |
spelling | doaj.art-45d4d936be5d42d79530162914f5701e2022-12-22T01:21:53ZengMDPI AGMolecules1420-30492010-03-011531433144110.3390/molecules15031433Mild and Efficient Strontium Chloride Hexahydrate-Catalyzed Conversion of Ketones and Aldehydes into Corresponding gem- Dihydroperoxides by Aqueous H2O2Fatemeh SoleimaneiKaveh KhosraviDavood AzarifarSrCl2·6H2O has been shown to act as an efficient catalyst for the conversion of aldehydes or ketones into the corresponding gem-dihydroperoxides (DHPs) by treatment with aqueous H2O2 (30%) in acetonitrile. The reactions proceed under mild and neutral conditions at room temperature to afford good to excellent yields of product.http://www.mdpi.com/1420-3049/15/3/1433/gem-dihydroperoxidestrontium chloride hexahydrateketonealdehydehydrogen peroxide |
spellingShingle | Fatemeh Soleimanei Kaveh Khosravi Davood Azarifar Mild and Efficient Strontium Chloride Hexahydrate-Catalyzed Conversion of Ketones and Aldehydes into Corresponding gem- Dihydroperoxides by Aqueous H2O2 Molecules gem-dihydroperoxide strontium chloride hexahydrate ketone aldehyde hydrogen peroxide |
title | Mild and Efficient Strontium Chloride Hexahydrate-Catalyzed Conversion of Ketones and Aldehydes into Corresponding gem- Dihydroperoxides by Aqueous H2O2 |
title_full | Mild and Efficient Strontium Chloride Hexahydrate-Catalyzed Conversion of Ketones and Aldehydes into Corresponding gem- Dihydroperoxides by Aqueous H2O2 |
title_fullStr | Mild and Efficient Strontium Chloride Hexahydrate-Catalyzed Conversion of Ketones and Aldehydes into Corresponding gem- Dihydroperoxides by Aqueous H2O2 |
title_full_unstemmed | Mild and Efficient Strontium Chloride Hexahydrate-Catalyzed Conversion of Ketones and Aldehydes into Corresponding gem- Dihydroperoxides by Aqueous H2O2 |
title_short | Mild and Efficient Strontium Chloride Hexahydrate-Catalyzed Conversion of Ketones and Aldehydes into Corresponding gem- Dihydroperoxides by Aqueous H2O2 |
title_sort | mild and efficient strontium chloride hexahydrate catalyzed conversion of ketones and aldehydes into corresponding gem dihydroperoxides by aqueous h2o2 |
topic | gem-dihydroperoxide strontium chloride hexahydrate ketone aldehyde hydrogen peroxide |
url | http://www.mdpi.com/1420-3049/15/3/1433/ |
work_keys_str_mv | AT fatemehsoleimanei mildandefficientstrontiumchloridehexahydratecatalyzedconversionofketonesandaldehydesintocorrespondinggemdihydroperoxidesbyaqueoush2o2 AT kavehkhosravi mildandefficientstrontiumchloridehexahydratecatalyzedconversionofketonesandaldehydesintocorrespondinggemdihydroperoxidesbyaqueoush2o2 AT davoodazarifar mildandefficientstrontiumchloridehexahydratecatalyzedconversionofketonesandaldehydesintocorrespondinggemdihydroperoxidesbyaqueoush2o2 |