Phase equilibrium diagram of Y-Cu-Sb system at 870 K

The interaction of the components in the Y-Cu-Sb ternary system was investigated using the methods of X-ray phase analysis, microstructure, and energy-dispersive X-ray spectroscopy in the whole concentration range at 870 K. At the temperature of investigation Y-Cu-Sb system is characterized by the f...

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Main Authors: L. Romaka, Yu. Stadnyk, V.V. Romaka, A. Zelinskiy, P. Klyzub, A. Horyn
Format: Article
Language:English
Published: Vasyl Stefanyk Precarpathian National University 2023-11-01
Series:Фізика і хімія твердого тіла
Subjects:
Online Access:https://journals.pnu.edu.ua/index.php/pcss/article/view/6888
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author L. Romaka
Yu. Stadnyk
V.V. Romaka
A. Zelinskiy
P. Klyzub
A. Horyn
author_facet L. Romaka
Yu. Stadnyk
V.V. Romaka
A. Zelinskiy
P. Klyzub
A. Horyn
author_sort L. Romaka
collection DOAJ
description The interaction of the components in the Y-Cu-Sb ternary system was investigated using the methods of X-ray phase analysis, microstructure, and energy-dispersive X-ray spectroscopy in the whole concentration range at 870 K. At the temperature of investigation Y-Cu-Sb system is characterized by the formation of three ternary compounds: Y3Cu22Sb9 (Dy3Cu20+xSb11-x structure type, space group F-43m, a=1.6614(3) nm), Y3Cu3Sb4 (Y3Au3Sb4 structure type, space group I-43d, а=0.95357(5) nm), YCuSb2 (HfCuSi2 structure type, space group P4/nmm, a=0.42580(1), c=0.98932(3) nm). The solubility of copper in the binary compound YSb (NaCl structure type) extends up to 8 at. %.
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spelling doaj.art-45f510908acd42e2a93958b16d9c7e002024-03-29T22:27:38ZengVasyl Stefanyk Precarpathian National UniversityФізика і хімія твердого тіла1729-44282309-85892023-11-0124461061510.15330/pcss.24.4.610-6155994Phase equilibrium diagram of Y-Cu-Sb system at 870 KL. RomakaYu. StadnykV.V. RomakaA. ZelinskiyP. KlyzubA. HorynThe interaction of the components in the Y-Cu-Sb ternary system was investigated using the methods of X-ray phase analysis, microstructure, and energy-dispersive X-ray spectroscopy in the whole concentration range at 870 K. At the temperature of investigation Y-Cu-Sb system is characterized by the formation of three ternary compounds: Y3Cu22Sb9 (Dy3Cu20+xSb11-x structure type, space group F-43m, a=1.6614(3) nm), Y3Cu3Sb4 (Y3Au3Sb4 structure type, space group I-43d, а=0.95357(5) nm), YCuSb2 (HfCuSi2 structure type, space group P4/nmm, a=0.42580(1), c=0.98932(3) nm). The solubility of copper in the binary compound YSb (NaCl structure type) extends up to 8 at. %.https://journals.pnu.edu.ua/index.php/pcss/article/view/6888intermetallicsternary systemphase equilibriacrystal structure
spellingShingle L. Romaka
Yu. Stadnyk
V.V. Romaka
A. Zelinskiy
P. Klyzub
A. Horyn
Phase equilibrium diagram of Y-Cu-Sb system at 870 K
Фізика і хімія твердого тіла
intermetallics
ternary system
phase equilibria
crystal structure
title Phase equilibrium diagram of Y-Cu-Sb system at 870 K
title_full Phase equilibrium diagram of Y-Cu-Sb system at 870 K
title_fullStr Phase equilibrium diagram of Y-Cu-Sb system at 870 K
title_full_unstemmed Phase equilibrium diagram of Y-Cu-Sb system at 870 K
title_short Phase equilibrium diagram of Y-Cu-Sb system at 870 K
title_sort phase equilibrium diagram of y cu sb system at 870 k
topic intermetallics
ternary system
phase equilibria
crystal structure
url https://journals.pnu.edu.ua/index.php/pcss/article/view/6888
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AT yustadnyk phaseequilibriumdiagramofycusbsystemat870k
AT vvromaka phaseequilibriumdiagramofycusbsystemat870k
AT azelinskiy phaseequilibriumdiagramofycusbsystemat870k
AT pklyzub phaseequilibriumdiagramofycusbsystemat870k
AT ahoryn phaseequilibriumdiagramofycusbsystemat870k