Development of Thermoelectric Half-Heusler Alloys over the Past 25 Years

Half-Heusler alloys are among the most promising thermoelectric materials. In the present review, thermoelectric properties (at 300 K and 800 K) of more than 1100 compositions from more than 220 publications between 1998 and 2023 were collected and evaluated. The dependence of the peak figure of mer...

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Main Authors: Gerda Rogl, Peter Franz Rogl
Format: Article
Language:English
Published: MDPI AG 2023-07-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/13/7/1152
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author Gerda Rogl
Peter Franz Rogl
author_facet Gerda Rogl
Peter Franz Rogl
author_sort Gerda Rogl
collection DOAJ
description Half-Heusler alloys are among the most promising thermoelectric materials. In the present review, thermoelectric properties (at 300 K and 800 K) of more than 1100 compositions from more than 220 publications between 1998 and 2023 were collected and evaluated. The dependence of the peak figure of merit, <i>ZT</i><sub>max</sub>, of p- and n-type half-Heusler alloys on the publishing year and the peak temperature is displayed in several figures. Furthermore, plots of <i>ZT</i> vs. the electrical resistivity, the Seebeck coefficient and the thermal conductivity at 300 K and 800 K are shown and discussed. Especially thermal conductivity vs. power factor leads to a good overview of <i>ZT</i>. For both p- and n-type individually separated into systems, <i>ZT</i>s and peak <i>ZT</i>s in dependence on the composition are displayed and discussed. This overview can help to find the ideal half-Heusler alloy for practical use.
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spelling doaj.art-4612a93df53c4f6db1b84ae86351b3282023-11-18T18:55:15ZengMDPI AGCrystals2073-43522023-07-01137115210.3390/cryst13071152Development of Thermoelectric Half-Heusler Alloys over the Past 25 YearsGerda Rogl0Peter Franz Rogl1Institute of Materials Chemistry, University of Vienna, Währingerstraße 42, A-1090 Wien, AustriaInstitute of Materials Chemistry, University of Vienna, Währingerstraße 42, A-1090 Wien, AustriaHalf-Heusler alloys are among the most promising thermoelectric materials. In the present review, thermoelectric properties (at 300 K and 800 K) of more than 1100 compositions from more than 220 publications between 1998 and 2023 were collected and evaluated. The dependence of the peak figure of merit, <i>ZT</i><sub>max</sub>, of p- and n-type half-Heusler alloys on the publishing year and the peak temperature is displayed in several figures. Furthermore, plots of <i>ZT</i> vs. the electrical resistivity, the Seebeck coefficient and the thermal conductivity at 300 K and 800 K are shown and discussed. Especially thermal conductivity vs. power factor leads to a good overview of <i>ZT</i>. For both p- and n-type individually separated into systems, <i>ZT</i>s and peak <i>ZT</i>s in dependence on the composition are displayed and discussed. This overview can help to find the ideal half-Heusler alloy for practical use.https://www.mdpi.com/2073-4352/13/7/1152half-Heusler alloysphysical propertiesfigure of merit (<i>ZT</i>)
spellingShingle Gerda Rogl
Peter Franz Rogl
Development of Thermoelectric Half-Heusler Alloys over the Past 25 Years
Crystals
half-Heusler alloys
physical properties
figure of merit (<i>ZT</i>)
title Development of Thermoelectric Half-Heusler Alloys over the Past 25 Years
title_full Development of Thermoelectric Half-Heusler Alloys over the Past 25 Years
title_fullStr Development of Thermoelectric Half-Heusler Alloys over the Past 25 Years
title_full_unstemmed Development of Thermoelectric Half-Heusler Alloys over the Past 25 Years
title_short Development of Thermoelectric Half-Heusler Alloys over the Past 25 Years
title_sort development of thermoelectric half heusler alloys over the past 25 years
topic half-Heusler alloys
physical properties
figure of merit (<i>ZT</i>)
url https://www.mdpi.com/2073-4352/13/7/1152
work_keys_str_mv AT gerdarogl developmentofthermoelectrichalfheusleralloysoverthepast25years
AT peterfranzrogl developmentofthermoelectrichalfheusleralloysoverthepast25years