A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole
The title complex, tetraaqua{1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole-κN4}(sulfato-κO)copper(II) sesquihydrate, [Cu(SO4)(C9H8N6)(H2O)4]·1.5H2O, is composed of one copper atom, one 1-[(2H-benzotriazol-1-yl)methyl]-1-H-1,2,4-triazole (bmt) ligand, one s...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811013511 |
| _version_ | 1819291470363885568 |
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| author | Huai-xia Yang Jun Zhang Dong Zhao |
| author_facet | Huai-xia Yang Jun Zhang Dong Zhao |
| author_sort | Huai-xia Yang |
| collection | DOAJ |
| description | The title complex, tetraaqua{1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole-κN4}(sulfato-κO)copper(II) sesquihydrate, [Cu(SO4)(C9H8N6)(H2O)4]·1.5H2O, is composed of one copper atom, one 1-[(2H-benzotriazol-1-yl)methyl]-1-H-1,2,4-triazole (bmt) ligand, one sulfate ligand, four coordinated water molecules and one and a half uncoordinated water molecules. The CuII atom is six-coordinated by one N atom from a bmt ligand and five O atoms from the monodentate sulfate ligand and four water molecules in a distorted octahedral geometry. In the crystal, adjacent molecules are linked through O—H...O and O—H...N hydrogen bonds involving the sulfate anion and the coordinated and uncoordinated water molecules into a three-dimensional network. |
| first_indexed | 2024-12-24T03:39:09Z |
| format | Article |
| id | doaj.art-4616cd27d2774e1b8258cb30531b566b |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:39:09Z |
| publishDate | 2011-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-4616cd27d2774e1b8258cb30531b566b2022-12-21T17:16:58ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-05-01675m602m60210.1107/S1600536811013511A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazoleHuai-xia YangJun ZhangDong ZhaoThe title complex, tetraaqua{1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole-κN4}(sulfato-κO)copper(II) sesquihydrate, [Cu(SO4)(C9H8N6)(H2O)4]·1.5H2O, is composed of one copper atom, one 1-[(2H-benzotriazol-1-yl)methyl]-1-H-1,2,4-triazole (bmt) ligand, one sulfate ligand, four coordinated water molecules and one and a half uncoordinated water molecules. The CuII atom is six-coordinated by one N atom from a bmt ligand and five O atoms from the monodentate sulfate ligand and four water molecules in a distorted octahedral geometry. In the crystal, adjacent molecules are linked through O—H...O and O—H...N hydrogen bonds involving the sulfate anion and the coordinated and uncoordinated water molecules into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536811013511 |
| spellingShingle | Huai-xia Yang Jun Zhang Dong Zhao A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole Acta Crystallographica Section E |
| title | A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole |
| title_full | A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole |
| title_fullStr | A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole |
| title_full_unstemmed | A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole |
| title_short | A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole |
| title_sort | new copper ii complex based on 1 1h benzotriazol 1 yl methyl 1h 1 2 4 triazole |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811013511 |
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