Chiral Liquid Crystal Lenses Confined in Microchannels

It is known that the liquid crystalline smectic-A phase has geometric defects, called focal conic domains, which can be used as gradient-index microlenses. Cholesteric (chiral nematic) phases also have topological defects with a central symmetry and a singularity at their center. We explore a weakly...

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Main Authors: Sean M. Hare, Beatrice Lunsford-Poe, MinSu Kim, Francesca Serra
Format: Article
Language:English
Published: MDPI AG 2020-08-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/13/17/3761
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author Sean M. Hare
Beatrice Lunsford-Poe
MinSu Kim
Francesca Serra
author_facet Sean M. Hare
Beatrice Lunsford-Poe
MinSu Kim
Francesca Serra
author_sort Sean M. Hare
collection DOAJ
description It is known that the liquid crystalline smectic-A phase has geometric defects, called focal conic domains, which can be used as gradient-index microlenses. Cholesteric (chiral nematic) phases also have topological defects with a central symmetry and a singularity at their center. We explore a weakly chiral system in which both types of defects can be present in the same material at different temperatures, and with this strategy we create lenses whose focal length is tunable with temperature. We measure the focal length of the tunable lenses, and we investigate the behavior of the defects near the phase transition. We identify the experimental conditions that make the simultaneous presence of the smectic focal conic domains and the circular cholesteric domains possible, such as the concentration of chiral dopant and the rate of heating and cooling. The transformation of focal conic domains into circular cholesteric domains is a new example of memory at the phase transition between smectic-A and nematic liquid crystals.
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spelling doaj.art-461ce0dc8c7e4ad3a609676f0a4d547b2023-11-20T11:21:44ZengMDPI AGMaterials1996-19442020-08-011317376110.3390/ma13173761Chiral Liquid Crystal Lenses Confined in MicrochannelsSean M. Hare0Beatrice Lunsford-Poe1MinSu Kim2Francesca Serra3Department of Physics and Astronomy, Johns Hopkins University, Baltimore, MD 21218, USADepartment of Physics and Astronomy, Johns Hopkins University, Baltimore, MD 21218, USADepartment of Physics and Astronomy, Johns Hopkins University, Baltimore, MD 21218, USADepartment of Physics and Astronomy, Johns Hopkins University, Baltimore, MD 21218, USAIt is known that the liquid crystalline smectic-A phase has geometric defects, called focal conic domains, which can be used as gradient-index microlenses. Cholesteric (chiral nematic) phases also have topological defects with a central symmetry and a singularity at their center. We explore a weakly chiral system in which both types of defects can be present in the same material at different temperatures, and with this strategy we create lenses whose focal length is tunable with temperature. We measure the focal length of the tunable lenses, and we investigate the behavior of the defects near the phase transition. We identify the experimental conditions that make the simultaneous presence of the smectic focal conic domains and the circular cholesteric domains possible, such as the concentration of chiral dopant and the rate of heating and cooling. The transformation of focal conic domains into circular cholesteric domains is a new example of memory at the phase transition between smectic-A and nematic liquid crystals.https://www.mdpi.com/1996-1944/13/17/3761liquid crystalsmicro-lensesphase transition
spellingShingle Sean M. Hare
Beatrice Lunsford-Poe
MinSu Kim
Francesca Serra
Chiral Liquid Crystal Lenses Confined in Microchannels
Materials
liquid crystals
micro-lenses
phase transition
title Chiral Liquid Crystal Lenses Confined in Microchannels
title_full Chiral Liquid Crystal Lenses Confined in Microchannels
title_fullStr Chiral Liquid Crystal Lenses Confined in Microchannels
title_full_unstemmed Chiral Liquid Crystal Lenses Confined in Microchannels
title_short Chiral Liquid Crystal Lenses Confined in Microchannels
title_sort chiral liquid crystal lenses confined in microchannels
topic liquid crystals
micro-lenses
phase transition
url https://www.mdpi.com/1996-1944/13/17/3761
work_keys_str_mv AT seanmhare chiralliquidcrystallensesconfinedinmicrochannels
AT beatricelunsfordpoe chiralliquidcrystallensesconfinedinmicrochannels
AT minsukim chiralliquidcrystallensesconfinedinmicrochannels
AT francescaserra chiralliquidcrystallensesconfinedinmicrochannels