μ-Propane-1,3-dithiolato-κ4S,S′:S,S′-bis[dicarbonyl(triphenylphosphane-κP)iron(II)](Fe—Fe)
The title compound, [Fe2(C3H6S2)(C18H15P)2(CO)4], which might serve as an active-site model of [FeFe]-hydrogenase, contains two fused Fe/S/C/C/C/S six-membered rings, one of which has a chair conformation and the other a boat conformation. Each Fe atom is coordinated by two carbonyl ligands, a triph...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811040621 |
| _version_ | 1818870240714424320 |
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| author | Bang-Shao Yin Tian-Bao Li Ming-Sheng Yang |
| author_facet | Bang-Shao Yin Tian-Bao Li Ming-Sheng Yang |
| author_sort | Bang-Shao Yin |
| collection | DOAJ |
| description | The title compound, [Fe2(C3H6S2)(C18H15P)2(CO)4], which might serve as an active-site model of [FeFe]-hydrogenase, contains two fused Fe/S/C/C/C/S six-membered rings, one of which has a chair conformation and the other a boat conformation. Each Fe atom is coordinated by two carbonyl ligands, a triphenylphosphane ligand and a bis-bidentate dithiolate ligand, and also forms an Fe—Fe bond [2.5167 (16) Å]. Together, the six bonded atoms form a very distorted octahedral arrangement. |
| first_indexed | 2024-12-19T12:03:53Z |
| format | Article |
| id | doaj.art-462008bac0fc4767ba7f6e8d61fda929 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T12:03:53Z |
| publishDate | 2011-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-462008bac0fc4767ba7f6e8d61fda9292022-12-21T20:22:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-11-016711m1502m150210.1107/S1600536811040621μ-Propane-1,3-dithiolato-κ4S,S′:S,S′-bis[dicarbonyl(triphenylphosphane-κP)iron(II)](Fe—Fe)Bang-Shao YinTian-Bao LiMing-Sheng YangThe title compound, [Fe2(C3H6S2)(C18H15P)2(CO)4], which might serve as an active-site model of [FeFe]-hydrogenase, contains two fused Fe/S/C/C/C/S six-membered rings, one of which has a chair conformation and the other a boat conformation. Each Fe atom is coordinated by two carbonyl ligands, a triphenylphosphane ligand and a bis-bidentate dithiolate ligand, and also forms an Fe—Fe bond [2.5167 (16) Å]. Together, the six bonded atoms form a very distorted octahedral arrangement.http://scripts.iucr.org/cgi-bin/paper?S1600536811040621 |
| spellingShingle | Bang-Shao Yin Tian-Bao Li Ming-Sheng Yang μ-Propane-1,3-dithiolato-κ4S,S′:S,S′-bis[dicarbonyl(triphenylphosphane-κP)iron(II)](Fe—Fe) Acta Crystallographica Section E |
| title | μ-Propane-1,3-dithiolato-κ4S,S′:S,S′-bis[dicarbonyl(triphenylphosphane-κP)iron(II)](Fe—Fe) |
| title_full | μ-Propane-1,3-dithiolato-κ4S,S′:S,S′-bis[dicarbonyl(triphenylphosphane-κP)iron(II)](Fe—Fe) |
| title_fullStr | μ-Propane-1,3-dithiolato-κ4S,S′:S,S′-bis[dicarbonyl(triphenylphosphane-κP)iron(II)](Fe—Fe) |
| title_full_unstemmed | μ-Propane-1,3-dithiolato-κ4S,S′:S,S′-bis[dicarbonyl(triphenylphosphane-κP)iron(II)](Fe—Fe) |
| title_short | μ-Propane-1,3-dithiolato-κ4S,S′:S,S′-bis[dicarbonyl(triphenylphosphane-κP)iron(II)](Fe—Fe) |
| title_sort | amp 956 propane 1 3 dithiolato amp 954 4s s amp 8242 s s amp 8242 bis dicarbonyl triphenylphosphane amp 954 p iron ii fe amp 8212 fe |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811040621 |
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