catena-Poly[[(5,5′-dimethyl- 2,2′-bipyridine-κ2N,N′)cadmium(II)]-di-μ-chlorido]
The asymmetric unit of the title compound, [CdCl2(C12H12N2)]n, contains one half-molecule; a twofold rotation axis passes through the Cd atom. The CdII atom is six-coordinated in a distorted octahedral configuration by two N atoms from 2,2′-bipyridine-5,5′-dimethyl and four bridg...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808027657 |
| _version_ | 1818998417679974400 |
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| author | Hamid Reza Khavasi Vahid Amani Khadijeh Kalateh Aida Khalighi Roya Ahmadi |
| author_facet | Hamid Reza Khavasi Vahid Amani Khadijeh Kalateh Aida Khalighi Roya Ahmadi |
| author_sort | Hamid Reza Khavasi |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [CdCl2(C12H12N2)]n, contains one half-molecule; a twofold rotation axis passes through the Cd atom. The CdII atom is six-coordinated in a distorted octahedral configuration by two N atoms from 2,2′-bipyridine-5,5′-dimethyl and four bridging Cl atoms. The bridging function of the chloro atoms leads to a one-dimensional chain structure. There is a π–π contact between the pyridine rings [centroid–centroid distance = 3.9807 (9) Å]. |
| first_indexed | 2024-12-20T22:01:12Z |
| format | Article |
| id | doaj.art-462be86ed87246449b00fe74e4e839c8 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T22:01:12Z |
| publishDate | 2008-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-462be86ed87246449b00fe74e4e839c82022-12-21T19:25:21ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-10-016410m1233m123310.1107/S1600536808027657catena-Poly[[(5,5′-dimethyl- 2,2′-bipyridine-κ2N,N′)cadmium(II)]-di-μ-chlorido]Hamid Reza KhavasiVahid AmaniKhadijeh KalatehAida KhalighiRoya AhmadiThe asymmetric unit of the title compound, [CdCl2(C12H12N2)]n, contains one half-molecule; a twofold rotation axis passes through the Cd atom. The CdII atom is six-coordinated in a distorted octahedral configuration by two N atoms from 2,2′-bipyridine-5,5′-dimethyl and four bridging Cl atoms. The bridging function of the chloro atoms leads to a one-dimensional chain structure. There is a π–π contact between the pyridine rings [centroid–centroid distance = 3.9807 (9) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536808027657 |
| spellingShingle | Hamid Reza Khavasi Vahid Amani Khadijeh Kalateh Aida Khalighi Roya Ahmadi catena-Poly[[(5,5′-dimethyl- 2,2′-bipyridine-κ2N,N′)cadmium(II)]-di-μ-chlorido] Acta Crystallographica Section E |
| title | catena-Poly[[(5,5′-dimethyl- 2,2′-bipyridine-κ2N,N′)cadmium(II)]-di-μ-chlorido] |
| title_full | catena-Poly[[(5,5′-dimethyl- 2,2′-bipyridine-κ2N,N′)cadmium(II)]-di-μ-chlorido] |
| title_fullStr | catena-Poly[[(5,5′-dimethyl- 2,2′-bipyridine-κ2N,N′)cadmium(II)]-di-μ-chlorido] |
| title_full_unstemmed | catena-Poly[[(5,5′-dimethyl- 2,2′-bipyridine-κ2N,N′)cadmium(II)]-di-μ-chlorido] |
| title_short | catena-Poly[[(5,5′-dimethyl- 2,2′-bipyridine-κ2N,N′)cadmium(II)]-di-μ-chlorido] |
| title_sort | catena poly 5 5 8242 dimethyl 2 2 8242 bipyridine 954 2n n 8242 cadmium ii di 956 chlorido |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808027657 |
| work_keys_str_mv | AT hamidrezakhavasi catenapoly558242dimethyl228242bipyridine9542nn8242cadmiumiidi956chlorido AT vahidamani catenapoly558242dimethyl228242bipyridine9542nn8242cadmiumiidi956chlorido AT khadijehkalateh catenapoly558242dimethyl228242bipyridine9542nn8242cadmiumiidi956chlorido AT aidakhalighi catenapoly558242dimethyl228242bipyridine9542nn8242cadmiumiidi956chlorido AT royaahmadi catenapoly558242dimethyl228242bipyridine9542nn8242cadmiumiidi956chlorido |