Binary Adsorption of Vapours in Active Carbons Described by the Combined Theories of Myers—Prausnitz and Dubinin (II)
The new MPD method, described recently, has been applied to the adsorption of benzene +1,2-dichloroethane vapours by a typical active carbon at 293 K. A total of 102 experiments have been carried out for adsorbed mole fractions between 0.06 and 0.94. Good agreement was found between the experimental...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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SAGE Publications
1997-10-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1177/026361749701500904 |
| _version_ | 1797283592052670464 |
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| author | F. Stoeckli D. Wintgens A. Lavanchy M. Stöckli |
| author_facet | F. Stoeckli D. Wintgens A. Lavanchy M. Stöckli |
| author_sort | F. Stoeckli |
| collection | DOAJ |
| description | The new MPD method, described recently, has been applied to the adsorption of benzene +1,2-dichloroethane vapours by a typical active carbon at 293 K. A total of 102 experiments have been carried out for adsorbed mole fractions between 0.06 and 0.94. Good agreement was found between the experimental and calculated values of the selectivity of the carbon for benzene, which decreased as the mole fraction of benzene increased. This variation reflects the heterogeneity of the carbon, which is taken into account by the DR equation. Although the liquid mixture is ideal, deviations from Raoult's law are observed in the adsorbed state, indicating a clear preference for benzene. The values of the activity coefficients obtained from the liquid/solid equilibrium improve the fit of the MPD method. |
| first_indexed | 2024-03-07T17:33:59Z |
| format | Article |
| id | doaj.art-462f61b0cc6f4672963ff2cc5f486807 |
| institution | Directory Open Access Journal |
| issn | 0263-6174 2048-4038 |
| language | English |
| last_indexed | 2024-03-07T17:33:59Z |
| publishDate | 1997-10-01 |
| publisher | SAGE Publications |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj.art-462f61b0cc6f4672963ff2cc5f4868072024-03-02T17:14:35ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40381997-10-011510.1177/026361749701500904Binary Adsorption of Vapours in Active Carbons Described by the Combined Theories of Myers—Prausnitz and Dubinin (II)F. Stoeckli0D. Wintgens1A. Lavanchy2M. Stöckli3 Chemistry Department of the University, CH-2000 Neuchâtel, Switzerland Chemistry Department of the University, CH-2000 Neuchâtel, Switzerland NC-Laboratory, CH-3700 Spiez, Switzerland NC-Laboratory, CH-3700 Spiez, SwitzerlandThe new MPD method, described recently, has been applied to the adsorption of benzene +1,2-dichloroethane vapours by a typical active carbon at 293 K. A total of 102 experiments have been carried out for adsorbed mole fractions between 0.06 and 0.94. Good agreement was found between the experimental and calculated values of the selectivity of the carbon for benzene, which decreased as the mole fraction of benzene increased. This variation reflects the heterogeneity of the carbon, which is taken into account by the DR equation. Although the liquid mixture is ideal, deviations from Raoult's law are observed in the adsorbed state, indicating a clear preference for benzene. The values of the activity coefficients obtained from the liquid/solid equilibrium improve the fit of the MPD method.https://doi.org/10.1177/026361749701500904 |
| spellingShingle | F. Stoeckli D. Wintgens A. Lavanchy M. Stöckli Binary Adsorption of Vapours in Active Carbons Described by the Combined Theories of Myers—Prausnitz and Dubinin (II) Adsorption Science & Technology |
| title | Binary Adsorption of Vapours in Active Carbons Described by the Combined Theories of Myers—Prausnitz and Dubinin (II) |
| title_full | Binary Adsorption of Vapours in Active Carbons Described by the Combined Theories of Myers—Prausnitz and Dubinin (II) |
| title_fullStr | Binary Adsorption of Vapours in Active Carbons Described by the Combined Theories of Myers—Prausnitz and Dubinin (II) |
| title_full_unstemmed | Binary Adsorption of Vapours in Active Carbons Described by the Combined Theories of Myers—Prausnitz and Dubinin (II) |
| title_short | Binary Adsorption of Vapours in Active Carbons Described by the Combined Theories of Myers—Prausnitz and Dubinin (II) |
| title_sort | binary adsorption of vapours in active carbons described by the combined theories of myers prausnitz and dubinin ii |
| url | https://doi.org/10.1177/026361749701500904 |
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