Tetra-μ-acetato-κ8O:O′-bis[(pyridine-2-carbonitrile-κN1)copper(II)]
The title binuclear compound, [Cu2(CH3COO)4(C6H4N2)2], lies about an inversion center, with the CuII cation bridged by four acetate anions and coordinated by a pyridine N atom in a distorted square-pyramidal geometry. The Cu...Cu distance is 2.5997 (15) Å. In the crystal, molecules are linked by wea...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813034120 |
| _version_ | 1818998730303471616 |
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| author | Mei Luo Lei Wang Jing-Cheng Zhang |
| author_facet | Mei Luo Lei Wang Jing-Cheng Zhang |
| author_sort | Mei Luo |
| collection | DOAJ |
| description | The title binuclear compound, [Cu2(CH3COO)4(C6H4N2)2], lies about an inversion center, with the CuII cation bridged by four acetate anions and coordinated by a pyridine N atom in a distorted square-pyramidal geometry. The Cu...Cu distance is 2.5997 (15) Å. In the crystal, molecules are linked by weak C—H...O and C—H...N hydrogen bonds into a three-dimensional supramolecular architecture. The crystal studied was a non-merohedral twin with a minor twin component of 4.1 (1)%. |
| first_indexed | 2024-12-20T22:06:10Z |
| format | Article |
| id | doaj.art-4639a5c58bed4054bdf94a812e13d1c5 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T22:06:10Z |
| publishDate | 2014-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-4639a5c58bed4054bdf94a812e13d1c52022-12-21T19:25:16ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-01-01701m27m2710.1107/S1600536813034120xu5755Tetra-μ-acetato-κ8O:O′-bis[(pyridine-2-carbonitrile-κN1)copper(II)]Mei Luo0Lei Wang1Jing-Cheng Zhang2Hefei University of Technology, Hefei, People's Republic of ChinaHefei University of Technology, Hefei, People's Republic of ChinaHefei University of Technology, Hefei, People's Republic of ChinaThe title binuclear compound, [Cu2(CH3COO)4(C6H4N2)2], lies about an inversion center, with the CuII cation bridged by four acetate anions and coordinated by a pyridine N atom in a distorted square-pyramidal geometry. The Cu...Cu distance is 2.5997 (15) Å. In the crystal, molecules are linked by weak C—H...O and C—H...N hydrogen bonds into a three-dimensional supramolecular architecture. The crystal studied was a non-merohedral twin with a minor twin component of 4.1 (1)%.http://scripts.iucr.org/cgi-bin/paper?S1600536813034120 |
| spellingShingle | Mei Luo Lei Wang Jing-Cheng Zhang Tetra-μ-acetato-κ8O:O′-bis[(pyridine-2-carbonitrile-κN1)copper(II)] Acta Crystallographica Section E |
| title | Tetra-μ-acetato-κ8O:O′-bis[(pyridine-2-carbonitrile-κN1)copper(II)] |
| title_full | Tetra-μ-acetato-κ8O:O′-bis[(pyridine-2-carbonitrile-κN1)copper(II)] |
| title_fullStr | Tetra-μ-acetato-κ8O:O′-bis[(pyridine-2-carbonitrile-κN1)copper(II)] |
| title_full_unstemmed | Tetra-μ-acetato-κ8O:O′-bis[(pyridine-2-carbonitrile-κN1)copper(II)] |
| title_short | Tetra-μ-acetato-κ8O:O′-bis[(pyridine-2-carbonitrile-κN1)copper(II)] |
| title_sort | tetra μ acetato κ8o o bis pyridine 2 carbonitrile κn1 copper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813034120 |
| work_keys_str_mv | AT meiluo tetramacetatok8oobispyridine2carbonitrilekn1copperii AT leiwang tetramacetatok8oobispyridine2carbonitrilekn1copperii AT jingchengzhang tetramacetatok8oobispyridine2carbonitrilekn1copperii |