A PRELIMINARY INVESTIGATION OF POLYANILINE/CHITOSAN COMPOSITE’S PHYSICOCHEMICAL PROPERTIES AND POTENTIAL ELECTROCHEMICAL APPLICATION

A polyaniline/chitosan (PANI/CHT) modified SPCE based sensor was developed and validated by electrochemical detection of PFOA. The PANI/CHT composite was synthesized by chemical oxidative polymerization technique. The synthesized material was characterized by scanning electron microscope (SEM)-Energ...

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Main Authors: NUR FARAHIN SUHAIMI, Siti Nor Atika Baharin, Nurul' Ain Jamion, Kavirajaa Pandian Sambasevam
Format: Article
Language:English
Published: Universiti Teknologi MARA, Negeri Sembilan 2022-10-01
Series:Journal of Academia
Subjects:
Online Access:https://myjms.mohe.gov.my/index.php/joa/article/view/19146
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author NUR FARAHIN SUHAIMI
Siti Nor Atika Baharin
Nurul' Ain Jamion
Kavirajaa Pandian Sambasevam
author_facet NUR FARAHIN SUHAIMI
Siti Nor Atika Baharin
Nurul' Ain Jamion
Kavirajaa Pandian Sambasevam
author_sort NUR FARAHIN SUHAIMI
collection DOAJ
description A polyaniline/chitosan (PANI/CHT) modified SPCE based sensor was developed and validated by electrochemical detection of PFOA. The PANI/CHT composite was synthesized by chemical oxidative polymerization technique. The synthesized material was characterized by scanning electron microscope (SEM)-Energy dispersive X-ray spectroscopy (EDX), Thermal gravimetric analysis (TGA) and Ultraviolet visible Spectroscopy (UV-Vis) techniques. The redox properties of the modified SPCE were examined by cyclic voltammetry studies. The investigation showed that PANI/CHT SPCE exhibit high electroactive surface area compared to unmodified SPCE. The PANI/CHT SPCE recorded lowest detection limit (LOD) of 1.60 ppb with LOQ of 4.82 ppb, in the linear range of 25-50 ppb.
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spelling doaj.art-463fd69dace246518b3ede031bd6efb22024-04-17T16:36:03ZengUniversiti Teknologi MARA, Negeri SembilanJournal of Academia2289-63682022-10-01102175186A PRELIMINARY INVESTIGATION OF POLYANILINE/CHITOSAN COMPOSITE’S PHYSICOCHEMICAL PROPERTIES AND POTENTIAL ELECTROCHEMICAL APPLICATIONNUR FARAHIN SUHAIMI 0Siti Nor Atika Baharin 1Nurul' Ain Jamion 2Kavirajaa Pandian Sambasevam 3UNIVERSITI TEKNOLOGI MARA (UiTM ), kampus kuala pilah,72000 kuala pilah, negeri sembilanUITM CAWANGAN NEGERI SEMBILAN, KAMPUS KUALA PILAHUITM CAWANGAN NEGERI SEMBILAN, KAMPUS KUALA PILAHUITM CAWANGAN NEGERI SEMBILAN, KAMPUS KUALA PILAHA polyaniline/chitosan (PANI/CHT) modified SPCE based sensor was developed and validated by electrochemical detection of PFOA. The PANI/CHT composite was synthesized by chemical oxidative polymerization technique. The synthesized material was characterized by scanning electron microscope (SEM)-Energy dispersive X-ray spectroscopy (EDX), Thermal gravimetric analysis (TGA) and Ultraviolet visible Spectroscopy (UV-Vis) techniques. The redox properties of the modified SPCE were examined by cyclic voltammetry studies. The investigation showed that PANI/CHT SPCE exhibit high electroactive surface area compared to unmodified SPCE. The PANI/CHT SPCE recorded lowest detection limit (LOD) of 1.60 ppb with LOQ of 4.82 ppb, in the linear range of 25-50 ppb.https://myjms.mohe.gov.my/index.php/joa/article/view/19146polyanilinechitosanperfluorooctanoic acidscreen-printed carbon electrodeelectrochemical sensor.
spellingShingle NUR FARAHIN SUHAIMI
Siti Nor Atika Baharin
Nurul' Ain Jamion
Kavirajaa Pandian Sambasevam
A PRELIMINARY INVESTIGATION OF POLYANILINE/CHITOSAN COMPOSITE’S PHYSICOCHEMICAL PROPERTIES AND POTENTIAL ELECTROCHEMICAL APPLICATION
Journal of Academia
polyaniline
chitosan
perfluorooctanoic acid
screen-printed carbon electrode
electrochemical sensor.
title A PRELIMINARY INVESTIGATION OF POLYANILINE/CHITOSAN COMPOSITE’S PHYSICOCHEMICAL PROPERTIES AND POTENTIAL ELECTROCHEMICAL APPLICATION
title_full A PRELIMINARY INVESTIGATION OF POLYANILINE/CHITOSAN COMPOSITE’S PHYSICOCHEMICAL PROPERTIES AND POTENTIAL ELECTROCHEMICAL APPLICATION
title_fullStr A PRELIMINARY INVESTIGATION OF POLYANILINE/CHITOSAN COMPOSITE’S PHYSICOCHEMICAL PROPERTIES AND POTENTIAL ELECTROCHEMICAL APPLICATION
title_full_unstemmed A PRELIMINARY INVESTIGATION OF POLYANILINE/CHITOSAN COMPOSITE’S PHYSICOCHEMICAL PROPERTIES AND POTENTIAL ELECTROCHEMICAL APPLICATION
title_short A PRELIMINARY INVESTIGATION OF POLYANILINE/CHITOSAN COMPOSITE’S PHYSICOCHEMICAL PROPERTIES AND POTENTIAL ELECTROCHEMICAL APPLICATION
title_sort preliminary investigation of polyaniline chitosan composite s physicochemical properties and potential electrochemical application
topic polyaniline
chitosan
perfluorooctanoic acid
screen-printed carbon electrode
electrochemical sensor.
url https://myjms.mohe.gov.my/index.php/joa/article/view/19146
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