Thermodynamics and dynamical properties of the KH<sub>2</sub>PO<sub>4</sub> type ferroelectric compounds. A unified model

Within the framework of the proposed unified proton ordering model for the ferroelectric compounds of the KH<sub>2</sub>PO<sub>4</sub> family, in the four-particle cluster approximation for the short-range interactions and mean field approximation for the long-range interacti...

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Main Authors: R.R. Levitskii, I.R. Zachek, A.S. Vdovych, S.I. Sorokov
Format: Article
Language:English
Published: Institute for Condensed Matter Physics 2009-01-01
Series:Condensed Matter Physics
Subjects:
Online Access:http://dx.doi.org/10.5488/CMP.12.1.75
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author R.R. Levitskii
I.R. Zachek
A.S. Vdovych
S.I. Sorokov
author_facet R.R. Levitskii
I.R. Zachek
A.S. Vdovych
S.I. Sorokov
author_sort R.R. Levitskii
collection DOAJ
description Within the framework of the proposed unified proton ordering model for the ferroelectric compounds of the KH<sub>2</sub>PO<sub>4</sub> family, in the four-particle cluster approximation for the short-range interactions and mean field approximation for the long-range interactions, we calculate thermodynamic and longitudinal dynamic characteristics of the KD<sub>2</sub>PO<sub>4</sub> type ferroelectrics and ND<sub>4</sub>D<sub>2</sub>PO<sub>4</sub> type antiferroelectrics. Calculations for partially deuterated K(H<sub>1-x</sub>D<sub>x</sub>)<sub>2</sub>PO<sub>4</sub> type ferroelectrics and N(H<sub>1-x</sub>D<sub>x</sub>)<sub>4</sub>(H<sub>1-x</sub>D<sub>x</sub>)<sub>2</sub>PO<sub>4</sub> type antiferroelectrics are performed within the mean crystal approximation. It is shown that at the proper choice of the theory parameters, a good quantitative description of experimental data for the KH<sub>2</sub>PO<sub>4</sub> family crystals is obtained.
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spelling doaj.art-464810a7796545d09f41fbe9a70b80af2022-12-22T03:18:21ZengInstitute for Condensed Matter PhysicsCondensed Matter Physics1607-324X2009-01-0112175119Thermodynamics and dynamical properties of the KH<sub>2</sub>PO<sub>4</sub> type ferroelectric compounds. A unified modelR.R. LevitskiiI.R. ZachekA.S. VdovychS.I. SorokovWithin the framework of the proposed unified proton ordering model for the ferroelectric compounds of the KH<sub>2</sub>PO<sub>4</sub> family, in the four-particle cluster approximation for the short-range interactions and mean field approximation for the long-range interactions, we calculate thermodynamic and longitudinal dynamic characteristics of the KD<sub>2</sub>PO<sub>4</sub> type ferroelectrics and ND<sub>4</sub>D<sub>2</sub>PO<sub>4</sub> type antiferroelectrics. Calculations for partially deuterated K(H<sub>1-x</sub>D<sub>x</sub>)<sub>2</sub>PO<sub>4</sub> type ferroelectrics and N(H<sub>1-x</sub>D<sub>x</sub>)<sub>4</sub>(H<sub>1-x</sub>D<sub>x</sub>)<sub>2</sub>PO<sub>4</sub> type antiferroelectrics are performed within the mean crystal approximation. It is shown that at the proper choice of the theory parameters, a good quantitative description of experimental data for the KH<sub>2</sub>PO<sub>4</sub> family crystals is obtained.http://dx.doi.org/10.5488/CMP.12.1.75ferroelectricscluster approximation
spellingShingle R.R. Levitskii
I.R. Zachek
A.S. Vdovych
S.I. Sorokov
Thermodynamics and dynamical properties of the KH<sub>2</sub>PO<sub>4</sub> type ferroelectric compounds. A unified model
Condensed Matter Physics
ferroelectrics
cluster approximation
title Thermodynamics and dynamical properties of the KH<sub>2</sub>PO<sub>4</sub> type ferroelectric compounds. A unified model
title_full Thermodynamics and dynamical properties of the KH<sub>2</sub>PO<sub>4</sub> type ferroelectric compounds. A unified model
title_fullStr Thermodynamics and dynamical properties of the KH<sub>2</sub>PO<sub>4</sub> type ferroelectric compounds. A unified model
title_full_unstemmed Thermodynamics and dynamical properties of the KH<sub>2</sub>PO<sub>4</sub> type ferroelectric compounds. A unified model
title_short Thermodynamics and dynamical properties of the KH<sub>2</sub>PO<sub>4</sub> type ferroelectric compounds. A unified model
title_sort thermodynamics and dynamical properties of the kh sub 2 sub po sub 4 sub type ferroelectric compounds a unified model
topic ferroelectrics
cluster approximation
url http://dx.doi.org/10.5488/CMP.12.1.75
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AT asvdovych thermodynamicsanddynamicalpropertiesofthekhsub2subposub4subtypeferroelectriccompoundsaunifiedmodel
AT sisorokov thermodynamicsanddynamicalpropertiesofthekhsub2subposub4subtypeferroelectriccompoundsaunifiedmodel