Effect of single-walled carbon nanotube on the physical, rheological and mechanical properties of thermoplastic elastomer based on PP/EPDM

The effect of the incorporation of single-walled carbon nanotubes (SWNT) on the morphological, physical, rheological and mechanical properties of thermoplastic elastomer based polypropylene (PP)/ethylene propylene diene (EPDM) (80/20) is reported. The morphological study showed that the size of the...

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Main Authors: Narimani Amir, Hemmati Mahmood
Format: Article
Language:English
Published: De Gruyter 2014-01-01
Series:Science and Engineering of Composite Materials
Subjects:
Online Access:https://doi.org/10.1515/secm-2012-0145
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author Narimani Amir
Hemmati Mahmood
author_facet Narimani Amir
Hemmati Mahmood
author_sort Narimani Amir
collection DOAJ
description The effect of the incorporation of single-walled carbon nanotubes (SWNT) on the morphological, physical, rheological and mechanical properties of thermoplastic elastomer based polypropylene (PP)/ethylene propylene diene (EPDM) (80/20) is reported. The morphological study showed that the size of the dispersed phase decreased by the addition of SWNT, this effect being more appreciable with 0.5 wt.% of SWNT. The results of differential scanning calorimetry showed that the addition of SWNT increased the crystallinity of PP/EPDM/SWNT nanocomposites. This effect was not linearly dependent on SWNT content, particularly at high SWNT concentrations. The rheological results revealed that addition of SWNT increased the storage modulus and complex viscosity at low frequencies. The Izod impact strength and tensile strength improved when 0.5 wt.% of SWNT was used. Furthermore, the tensile modulus increased remarkably by increasing the SWNT content, but the elongation at break of the material decreased.
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spelling doaj.art-4662088976d94b4a83b99b954dfff5b22022-12-21T21:34:42ZengDe GruyterScience and Engineering of Composite Materials0792-12332191-03592014-01-01211152110.1515/secm-2012-0145Effect of single-walled carbon nanotube on the physical, rheological and mechanical properties of thermoplastic elastomer based on PP/EPDMNarimani Amir0Hemmati Mahmood1Department of Polymer Engineering, Islamic Azad University, South Branch, Tehran, IranResearch Institute of Petroleum Industry (RIPI), Tehran, IranThe effect of the incorporation of single-walled carbon nanotubes (SWNT) on the morphological, physical, rheological and mechanical properties of thermoplastic elastomer based polypropylene (PP)/ethylene propylene diene (EPDM) (80/20) is reported. The morphological study showed that the size of the dispersed phase decreased by the addition of SWNT, this effect being more appreciable with 0.5 wt.% of SWNT. The results of differential scanning calorimetry showed that the addition of SWNT increased the crystallinity of PP/EPDM/SWNT nanocomposites. This effect was not linearly dependent on SWNT content, particularly at high SWNT concentrations. The rheological results revealed that addition of SWNT increased the storage modulus and complex viscosity at low frequencies. The Izod impact strength and tensile strength improved when 0.5 wt.% of SWNT was used. Furthermore, the tensile modulus increased remarkably by increasing the SWNT content, but the elongation at break of the material decreased.https://doi.org/10.1515/secm-2012-0145mechanicalmorphological studiesphysical propertiesrheologicalswnt
spellingShingle Narimani Amir
Hemmati Mahmood
Effect of single-walled carbon nanotube on the physical, rheological and mechanical properties of thermoplastic elastomer based on PP/EPDM
Science and Engineering of Composite Materials
mechanical
morphological studies
physical properties
rheological
swnt
title Effect of single-walled carbon nanotube on the physical, rheological and mechanical properties of thermoplastic elastomer based on PP/EPDM
title_full Effect of single-walled carbon nanotube on the physical, rheological and mechanical properties of thermoplastic elastomer based on PP/EPDM
title_fullStr Effect of single-walled carbon nanotube on the physical, rheological and mechanical properties of thermoplastic elastomer based on PP/EPDM
title_full_unstemmed Effect of single-walled carbon nanotube on the physical, rheological and mechanical properties of thermoplastic elastomer based on PP/EPDM
title_short Effect of single-walled carbon nanotube on the physical, rheological and mechanical properties of thermoplastic elastomer based on PP/EPDM
title_sort effect of single walled carbon nanotube on the physical rheological and mechanical properties of thermoplastic elastomer based on pp epdm
topic mechanical
morphological studies
physical properties
rheological
swnt
url https://doi.org/10.1515/secm-2012-0145
work_keys_str_mv AT narimaniamir effectofsinglewalledcarbonnanotubeonthephysicalrheologicalandmechanicalpropertiesofthermoplasticelastomerbasedonppepdm
AT hemmatimahmood effectofsinglewalledcarbonnanotubeonthephysicalrheologicalandmechanicalpropertiesofthermoplasticelastomerbasedonppepdm