A New Thiourea Compound as Potential Ionophore for Metal Ion Sensor
A new thiourea compound, 2,2-oxybis(ethyl)-4-(1-naphthyl)-3-thiourea 3 has been synthesized and characterized by using FTIR, 1H-NMR, 13C-NMR, and MS spectroscopy. The binding properties of with various cations were also carried out using ‘naked eye’, UV-vis and 1H-NMR titration experiments. This com...
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| Format: | Article |
| Language: | English |
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Department of Chemistry, Universitas Gadjah Mada
2018-02-01
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| Series: | Indonesian Journal of Chemistry |
| Subjects: | |
| Online Access: | https://jurnal.ugm.ac.id/ijc/article/view/27078 |
| _version_ | 1818925115537096704 |
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| author | Fatimatul Akma Awang Ngah Emma Izzati Zakariah Imran Fakhar Nurul Izzaty Hassan Lee Yook Heng Bohari Yamin Siti Aishah Hasbullah |
| author_facet | Fatimatul Akma Awang Ngah Emma Izzati Zakariah Imran Fakhar Nurul Izzaty Hassan Lee Yook Heng Bohari Yamin Siti Aishah Hasbullah |
| author_sort | Fatimatul Akma Awang Ngah |
| collection | DOAJ |
| description | A new thiourea compound, 2,2-oxybis(ethyl)-4-(1-naphthyl)-3-thiourea 3 has been synthesized and characterized by using FTIR, 1H-NMR, 13C-NMR, and MS spectroscopy. The binding properties of with various cations were also carried out using ‘naked eye’, UV-vis and 1H-NMR titration experiments. This compound exhibited effective binding for Hg2+ in the presence of other cations, such as Ag+, Ni2+, Sn2+, Zn2+, Fe2+, Cu2+, and Pb2+. Continuous variation titration experiments were conducted in order to determine the binding behavior for Hg2+. Stoichiometry of the host and guest binding interactions were also determined using continuous variation titration experiments and plotting molar-ratio curves. Pearson Product moment method was employed to calculate the correlation coefficient, and non-linear regression equation was used to calculate dissociation constant Kd. Molar-ratio and binding constant data substantiated the presence of binding sites for the compound 3. |
| first_indexed | 2024-12-20T02:36:06Z |
| format | Article |
| id | doaj.art-467232a7e05b4f3a8c2e8ec4b6c7e20c |
| institution | Directory Open Access Journal |
| issn | 1411-9420 2460-1578 |
| language | English |
| last_indexed | 2024-12-20T02:36:06Z |
| publishDate | 2018-02-01 |
| publisher | Department of Chemistry, Universitas Gadjah Mada |
| record_format | Article |
| series | Indonesian Journal of Chemistry |
| spelling | doaj.art-467232a7e05b4f3a8c2e8ec4b6c7e20c2022-12-21T19:56:27ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782018-02-0118111612010.22146/ijc.2707820099A New Thiourea Compound as Potential Ionophore for Metal Ion SensorFatimatul Akma Awang Ngah0Emma Izzati Zakariah1Imran Fakhar2Nurul Izzaty Hassan3Lee Yook Heng4Bohari Yamin5Siti Aishah Hasbullah6School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 46000 Bangi, Selangor, MalaysiaSchool of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 46000 Bangi, Selangor, MalaysiaSchool of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 46000 Bangi, Selangor, MalaysiaSchool of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 46000 Bangi, Selangor, MalaysiaSchool of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 46000 Bangi, Selangor, MalaysiaSchool of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 46000 Bangi, Selangor, MalaysiaSchool of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 46000 Bangi, Selangor, MalaysiaA new thiourea compound, 2,2-oxybis(ethyl)-4-(1-naphthyl)-3-thiourea 3 has been synthesized and characterized by using FTIR, 1H-NMR, 13C-NMR, and MS spectroscopy. The binding properties of with various cations were also carried out using ‘naked eye’, UV-vis and 1H-NMR titration experiments. This compound exhibited effective binding for Hg2+ in the presence of other cations, such as Ag+, Ni2+, Sn2+, Zn2+, Fe2+, Cu2+, and Pb2+. Continuous variation titration experiments were conducted in order to determine the binding behavior for Hg2+. Stoichiometry of the host and guest binding interactions were also determined using continuous variation titration experiments and plotting molar-ratio curves. Pearson Product moment method was employed to calculate the correlation coefficient, and non-linear regression equation was used to calculate dissociation constant Kd. Molar-ratio and binding constant data substantiated the presence of binding sites for the compound 3.https://jurnal.ugm.ac.id/ijc/article/view/27078thioureaionophoresensormercury |
| spellingShingle | Fatimatul Akma Awang Ngah Emma Izzati Zakariah Imran Fakhar Nurul Izzaty Hassan Lee Yook Heng Bohari Yamin Siti Aishah Hasbullah A New Thiourea Compound as Potential Ionophore for Metal Ion Sensor Indonesian Journal of Chemistry thiourea ionophore sensor mercury |
| title | A New Thiourea Compound as Potential Ionophore for Metal Ion Sensor |
| title_full | A New Thiourea Compound as Potential Ionophore for Metal Ion Sensor |
| title_fullStr | A New Thiourea Compound as Potential Ionophore for Metal Ion Sensor |
| title_full_unstemmed | A New Thiourea Compound as Potential Ionophore for Metal Ion Sensor |
| title_short | A New Thiourea Compound as Potential Ionophore for Metal Ion Sensor |
| title_sort | new thiourea compound as potential ionophore for metal ion sensor |
| topic | thiourea ionophore sensor mercury |
| url | https://jurnal.ugm.ac.id/ijc/article/view/27078 |
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