Synthesis and properties of chlorine and phosphorus containing rubber seed oil as a second plasticizer for flame retardant polyvinyl chloride materials

The synthesis of multifunctional plasticizer using rubber seed oil can increase its added value and expand the application field of plasticized products. Recent studies on bio-based plasticizers focus on bio-based raw materials but products lack functionality. In this study, flame retardant phosphat...

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Main Authors: Li Huabei, Wang Xiaolin, Yao Xinding, Chu Hongying
Format: Article
Language:English
Published: Sciendo 2023-06-01
Series:Polish Journal of Chemical Technology
Subjects:
Online Access:https://doi.org/10.2478/pjct-2023-0015
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author Li Huabei
Wang Xiaolin
Yao Xinding
Chu Hongying
author_facet Li Huabei
Wang Xiaolin
Yao Xinding
Chu Hongying
author_sort Li Huabei
collection DOAJ
description The synthesis of multifunctional plasticizer using rubber seed oil can increase its added value and expand the application field of plasticized products. Recent studies on bio-based plasticizers focus on bio-based raw materials but products lack functionality. In this study, flame retardant phosphate and chlorine were introduced into the chemical structure of rubber seed oil to synthesis a nitrogen and phosphorus synergistic flame retardant plasticizer based on rubber seed oil(NPFP) and apply it to plasticize polyvinyl chloride (PVC). Thermal stability, limiting oxygen index, plasticizing property, solvent extraction resistance, and microstructure of plasticized PVC materials were characterized. The results showed that NPFP with excellent solvent extraction resistance can significantly enhance the limiting oxygen index and thermal stability of plasticized PVC materials, and can partially replace dioctyl phthalate(DOP) as multifunctional auxiliary plasticizer.
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spelling doaj.art-46742f19f8054237b31e1a96ea210dd72023-07-03T10:21:46ZengSciendoPolish Journal of Chemical Technology1899-47412023-06-01252364210.2478/pjct-2023-0015Synthesis and properties of chlorine and phosphorus containing rubber seed oil as a second plasticizer for flame retardant polyvinyl chloride materialsLi Huabei0Wang Xiaolin1Yao Xinding2Chu Hongying31Yellow River Conservancy Technical Institute, Kaifeng475004, China3Henan Technical Institute, Kaifeng475000, China1Yellow River Conservancy Technical Institute, Kaifeng475004, China1Yellow River Conservancy Technical Institute, Kaifeng475004, ChinaThe synthesis of multifunctional plasticizer using rubber seed oil can increase its added value and expand the application field of plasticized products. Recent studies on bio-based plasticizers focus on bio-based raw materials but products lack functionality. In this study, flame retardant phosphate and chlorine were introduced into the chemical structure of rubber seed oil to synthesis a nitrogen and phosphorus synergistic flame retardant plasticizer based on rubber seed oil(NPFP) and apply it to plasticize polyvinyl chloride (PVC). Thermal stability, limiting oxygen index, plasticizing property, solvent extraction resistance, and microstructure of plasticized PVC materials were characterized. The results showed that NPFP with excellent solvent extraction resistance can significantly enhance the limiting oxygen index and thermal stability of plasticized PVC materials, and can partially replace dioctyl phthalate(DOP) as multifunctional auxiliary plasticizer.https://doi.org/10.2478/pjct-2023-0015flame retardant plasticizerrubber seed oilpolyvinyl chlorideflame retardant performance
spellingShingle Li Huabei
Wang Xiaolin
Yao Xinding
Chu Hongying
Synthesis and properties of chlorine and phosphorus containing rubber seed oil as a second plasticizer for flame retardant polyvinyl chloride materials
Polish Journal of Chemical Technology
flame retardant plasticizer
rubber seed oil
polyvinyl chloride
flame retardant performance
title Synthesis and properties of chlorine and phosphorus containing rubber seed oil as a second plasticizer for flame retardant polyvinyl chloride materials
title_full Synthesis and properties of chlorine and phosphorus containing rubber seed oil as a second plasticizer for flame retardant polyvinyl chloride materials
title_fullStr Synthesis and properties of chlorine and phosphorus containing rubber seed oil as a second plasticizer for flame retardant polyvinyl chloride materials
title_full_unstemmed Synthesis and properties of chlorine and phosphorus containing rubber seed oil as a second plasticizer for flame retardant polyvinyl chloride materials
title_short Synthesis and properties of chlorine and phosphorus containing rubber seed oil as a second plasticizer for flame retardant polyvinyl chloride materials
title_sort synthesis and properties of chlorine and phosphorus containing rubber seed oil as a second plasticizer for flame retardant polyvinyl chloride materials
topic flame retardant plasticizer
rubber seed oil
polyvinyl chloride
flame retardant performance
url https://doi.org/10.2478/pjct-2023-0015
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AT wangxiaolin synthesisandpropertiesofchlorineandphosphoruscontainingrubberseedoilasasecondplasticizerforflameretardantpolyvinylchloridematerials
AT yaoxinding synthesisandpropertiesofchlorineandphosphoruscontainingrubberseedoilasasecondplasticizerforflameretardantpolyvinylchloridematerials
AT chuhongying synthesisandpropertiesofchlorineandphosphoruscontainingrubberseedoilasasecondplasticizerforflameretardantpolyvinylchloridematerials