Synthesis of pyridone derivatives using 2D rod like bifunctional Fe based MOF and CuO nanocomposites as a novel heterogeneous catalyst
Abstract In this study, a new and efficient Rod-like bifunctional Fe-based MOF@CuO nanocomposites (RL BF Fe-based MOF@CuO NC) were synthesized as new and efficient heterogeneous catalyst through a simple method from easily available 1,3,5-benzenetricarbocylic acid linker, nitrate ferric as a source...
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| Format: | Article |
| Language: | English |
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Nature Portfolio
2023-09-01
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| Series: | Scientific Reports |
| Online Access: | https://doi.org/10.1038/s41598-023-43045-6 |
| _version_ | 1797452774247497728 |
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| author | Negar Hoot Enayatollah Sheikhhosseini Sayed Ali Ahmadi Mahdieh Ghazizadeh Moslem Malekshahi Mahdieh Yahyazadehfar |
| author_facet | Negar Hoot Enayatollah Sheikhhosseini Sayed Ali Ahmadi Mahdieh Ghazizadeh Moslem Malekshahi Mahdieh Yahyazadehfar |
| author_sort | Negar Hoot |
| collection | DOAJ |
| description | Abstract In this study, a new and efficient Rod-like bifunctional Fe-based MOF@CuO nanocomposites (RL BF Fe-based MOF@CuO NC) were synthesized as new and efficient heterogeneous catalyst through a simple method from easily available 1,3,5-benzenetricarbocylic acid linker, nitrate ferric as a source of iron and copper oxide (CuO) nanoparticles under microwave irradiation. The synthesized nanocatalysts were characterized with different techniques such as Brunauer–Emmett–Teller (BET), energy dispersive spectroscopy (EDS), field emission scanning electron microscopy (FE-SEM), mapping, transmission electron microscopy (TEM), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), thermogravimetric analysis (TGA) and Fourier transform infrared spectroscopy (FT-IR). The RL BF Fe-based MOF@CuO NC had relatively high specific surface area (203 m2 g−1) while exhibiting superparamagnetic properties. The catalytic activity of RL BF Fe-based MOF@CuO NC was explored in a facile and green methodology to prepare diverse N‑amino-2-pyridones by one-pot four component reactions comprising aromatic aldehyde, malononitrile, methyl cyanoacetate and hydrazine hydrate within mild and solvent-free conditions. This protocol enjoys features like providing the final products during low reaction times in excellent yields under solvent-free conditions. The use of easily available and inexpensive reactants for the synthesis of the catalyst, environmental compatibility, low catalyst loading, fast and clean work-up and reusability of catalyst for several cycles with consistent activity are counted as the outstanding features of this procedure. |
| first_indexed | 2024-03-09T15:12:36Z |
| format | Article |
| id | doaj.art-4682781d5b374af2891f456294b78ed4 |
| institution | Directory Open Access Journal |
| issn | 2045-2322 |
| language | English |
| last_indexed | 2024-03-09T15:12:36Z |
| publishDate | 2023-09-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Scientific Reports |
| spelling | doaj.art-4682781d5b374af2891f456294b78ed42023-11-26T13:14:59ZengNature PortfolioScientific Reports2045-23222023-09-0113111410.1038/s41598-023-43045-6Synthesis of pyridone derivatives using 2D rod like bifunctional Fe based MOF and CuO nanocomposites as a novel heterogeneous catalystNegar Hoot0Enayatollah Sheikhhosseini1Sayed Ali Ahmadi2Mahdieh Ghazizadeh3Moslem Malekshahi4Mahdieh Yahyazadehfar5Department of Chemistry, Kerman Branch, Islamic Azad UniversityDepartment of Chemistry, Kerman Branch, Islamic Azad UniversityDepartment of Chemistry, Kerman Branch, Islamic Azad UniversityDepartment of Chemistry, Kerman Branch, Islamic Azad UniversityDepartment of Chemistry, Kerman Branch, Islamic Azad UniversityDepartment of Chemistry, Kerman Branch, Islamic Azad UniversityAbstract In this study, a new and efficient Rod-like bifunctional Fe-based MOF@CuO nanocomposites (RL BF Fe-based MOF@CuO NC) were synthesized as new and efficient heterogeneous catalyst through a simple method from easily available 1,3,5-benzenetricarbocylic acid linker, nitrate ferric as a source of iron and copper oxide (CuO) nanoparticles under microwave irradiation. The synthesized nanocatalysts were characterized with different techniques such as Brunauer–Emmett–Teller (BET), energy dispersive spectroscopy (EDS), field emission scanning electron microscopy (FE-SEM), mapping, transmission electron microscopy (TEM), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), thermogravimetric analysis (TGA) and Fourier transform infrared spectroscopy (FT-IR). The RL BF Fe-based MOF@CuO NC had relatively high specific surface area (203 m2 g−1) while exhibiting superparamagnetic properties. The catalytic activity of RL BF Fe-based MOF@CuO NC was explored in a facile and green methodology to prepare diverse N‑amino-2-pyridones by one-pot four component reactions comprising aromatic aldehyde, malononitrile, methyl cyanoacetate and hydrazine hydrate within mild and solvent-free conditions. This protocol enjoys features like providing the final products during low reaction times in excellent yields under solvent-free conditions. The use of easily available and inexpensive reactants for the synthesis of the catalyst, environmental compatibility, low catalyst loading, fast and clean work-up and reusability of catalyst for several cycles with consistent activity are counted as the outstanding features of this procedure.https://doi.org/10.1038/s41598-023-43045-6 |
| spellingShingle | Negar Hoot Enayatollah Sheikhhosseini Sayed Ali Ahmadi Mahdieh Ghazizadeh Moslem Malekshahi Mahdieh Yahyazadehfar Synthesis of pyridone derivatives using 2D rod like bifunctional Fe based MOF and CuO nanocomposites as a novel heterogeneous catalyst Scientific Reports |
| title | Synthesis of pyridone derivatives using 2D rod like bifunctional Fe based MOF and CuO nanocomposites as a novel heterogeneous catalyst |
| title_full | Synthesis of pyridone derivatives using 2D rod like bifunctional Fe based MOF and CuO nanocomposites as a novel heterogeneous catalyst |
| title_fullStr | Synthesis of pyridone derivatives using 2D rod like bifunctional Fe based MOF and CuO nanocomposites as a novel heterogeneous catalyst |
| title_full_unstemmed | Synthesis of pyridone derivatives using 2D rod like bifunctional Fe based MOF and CuO nanocomposites as a novel heterogeneous catalyst |
| title_short | Synthesis of pyridone derivatives using 2D rod like bifunctional Fe based MOF and CuO nanocomposites as a novel heterogeneous catalyst |
| title_sort | synthesis of pyridone derivatives using 2d rod like bifunctional fe based mof and cuo nanocomposites as a novel heterogeneous catalyst |
| url | https://doi.org/10.1038/s41598-023-43045-6 |
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