Recent advances in electrochemical carboxylation reactions using carbon dioxide
From the viewpoint of abundance, economy, non-toxicity, and renewability, CO2 is the ideal C1 synthon in organic synthetic chemistry. Utilizing CO2 for chemical conversion to synthesize highly value-added fine chemicals is of great significance. Organic electrochemical synthesis that employs electro...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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KeAi Communications Co. Ltd.
2022-06-01
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| Series: | Green Chemical Engineering |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2666952821000911 |
| _version_ | 1797976365929070592 |
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| author | Xiao-Fei Liu Ke Zhang Li Tao Xiao-Bing Lu Wen-Zhen Zhang |
| author_facet | Xiao-Fei Liu Ke Zhang Li Tao Xiao-Bing Lu Wen-Zhen Zhang |
| author_sort | Xiao-Fei Liu |
| collection | DOAJ |
| description | From the viewpoint of abundance, economy, non-toxicity, and renewability, CO2 is the ideal C1 synthon in organic synthetic chemistry. Utilizing CO2 for chemical conversion to synthesize highly value-added fine chemicals is of great significance. Organic electrochemical synthesis that employs electrons as redox reagents to achieve selective oxidation or reduction has attracted much attention in the past decades. In this review, recent advances in the electrochemical carboxylations using CO2 from the perspective of organic synthesis will be summarized. We give an overview about the research progress of electrocarboxylation reactions according to the classification of substrates, such as alkenes, organic (pseudo)halides, aldehydes, ketones, and imines. The carbanions produced by cathodic reduction are important intermediates in the electrocarboxylation reactions using CO2. |
| first_indexed | 2024-04-11T04:49:47Z |
| format | Article |
| id | doaj.art-469291cfd8ce4590bec8249d816d981b |
| institution | Directory Open Access Journal |
| issn | 2666-9528 |
| language | English |
| last_indexed | 2024-04-11T04:49:47Z |
| publishDate | 2022-06-01 |
| publisher | KeAi Communications Co. Ltd. |
| record_format | Article |
| series | Green Chemical Engineering |
| spelling | doaj.art-469291cfd8ce4590bec8249d816d981b2022-12-27T04:40:11ZengKeAi Communications Co. Ltd.Green Chemical Engineering2666-95282022-06-0132125137Recent advances in electrochemical carboxylation reactions using carbon dioxideXiao-Fei Liu0Ke Zhang1Li Tao2Xiao-Bing Lu3Wen-Zhen Zhang4State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, ChinaState Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, ChinaState Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, ChinaState Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, ChinaCorresponding author.; State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, ChinaFrom the viewpoint of abundance, economy, non-toxicity, and renewability, CO2 is the ideal C1 synthon in organic synthetic chemistry. Utilizing CO2 for chemical conversion to synthesize highly value-added fine chemicals is of great significance. Organic electrochemical synthesis that employs electrons as redox reagents to achieve selective oxidation or reduction has attracted much attention in the past decades. In this review, recent advances in the electrochemical carboxylations using CO2 from the perspective of organic synthesis will be summarized. We give an overview about the research progress of electrocarboxylation reactions according to the classification of substrates, such as alkenes, organic (pseudo)halides, aldehydes, ketones, and imines. The carbanions produced by cathodic reduction are important intermediates in the electrocarboxylation reactions using CO2.http://www.sciencedirect.com/science/article/pii/S2666952821000911Carbon dioxideOrganic electrochemical synthesisCarboxylationGreen chemistryCarboxylic acid |
| spellingShingle | Xiao-Fei Liu Ke Zhang Li Tao Xiao-Bing Lu Wen-Zhen Zhang Recent advances in electrochemical carboxylation reactions using carbon dioxide Green Chemical Engineering Carbon dioxide Organic electrochemical synthesis Carboxylation Green chemistry Carboxylic acid |
| title | Recent advances in electrochemical carboxylation reactions using carbon dioxide |
| title_full | Recent advances in electrochemical carboxylation reactions using carbon dioxide |
| title_fullStr | Recent advances in electrochemical carboxylation reactions using carbon dioxide |
| title_full_unstemmed | Recent advances in electrochemical carboxylation reactions using carbon dioxide |
| title_short | Recent advances in electrochemical carboxylation reactions using carbon dioxide |
| title_sort | recent advances in electrochemical carboxylation reactions using carbon dioxide |
| topic | Carbon dioxide Organic electrochemical synthesis Carboxylation Green chemistry Carboxylic acid |
| url | http://www.sciencedirect.com/science/article/pii/S2666952821000911 |
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