Functionalized silver nanoparticles as an effective medium towards trace determination of arsenic (III) in aqueous solution

Arsenic is well known for its toxicity and various health effects. In this work, we report a simple, environment friendly and cost effective colorimetric approach for selective detection of arsenic (III) in aqueous medium. PEG functionalized silver nanoparticles were synthesized by chemical reductio...

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Main Authors: Bijoy Sankar Boruah, Nikhil Kumar Daimari, Rajib Biswas
Format: Article
Language:English
Published: Elsevier 2019-03-01
Series:Results in Physics
Online Access:http://www.sciencedirect.com/science/article/pii/S2211379718335137
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author Bijoy Sankar Boruah
Nikhil Kumar Daimari
Rajib Biswas
author_facet Bijoy Sankar Boruah
Nikhil Kumar Daimari
Rajib Biswas
author_sort Bijoy Sankar Boruah
collection DOAJ
description Arsenic is well known for its toxicity and various health effects. In this work, we report a simple, environment friendly and cost effective colorimetric approach for selective detection of arsenic (III) in aqueous medium. PEG functionalized silver nanoparticles were synthesized by chemical reduction method and applied for detection of heavy metal ions like arsenic(III), cobalt (II), cadmium (II), copper (II), iron (III), lead (II), mercury (II), magnesium (II) and nickel (II). In case of arsenic samples, we have observed perceptible alteration of colors from yellow to bluish due to aggregation of PEG functionalized silver nanoparticles. Absorption spectra of the arsenic samples were measured through UV–Vis spectrometry to derive detectable range of arsenic (III) concentration. The results have showed that the detection limit of this sensing unit is 1 ppb with an excellent linearity of ∼0.99. Keywords: Silver nanoparticles, Polyethylene glycol, Colorimetric, Arsenic (III)
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spelling doaj.art-46a7fdfae5644919ae524487a96373732022-12-21T18:15:07ZengElsevierResults in Physics2211-37972019-03-011220612065Functionalized silver nanoparticles as an effective medium towards trace determination of arsenic (III) in aqueous solutionBijoy Sankar Boruah0Nikhil Kumar Daimari1Rajib Biswas2Applied Optics and Photonics Research Laboratory, Department of Physics, Tezpur University, Napaam 784028, Assam, IndiaApplied Optics and Photonics Research Laboratory, Department of Physics, Tezpur University, Napaam 784028, Assam, IndiaCorresponding author.; Applied Optics and Photonics Research Laboratory, Department of Physics, Tezpur University, Napaam 784028, Assam, IndiaArsenic is well known for its toxicity and various health effects. In this work, we report a simple, environment friendly and cost effective colorimetric approach for selective detection of arsenic (III) in aqueous medium. PEG functionalized silver nanoparticles were synthesized by chemical reduction method and applied for detection of heavy metal ions like arsenic(III), cobalt (II), cadmium (II), copper (II), iron (III), lead (II), mercury (II), magnesium (II) and nickel (II). In case of arsenic samples, we have observed perceptible alteration of colors from yellow to bluish due to aggregation of PEG functionalized silver nanoparticles. Absorption spectra of the arsenic samples were measured through UV–Vis spectrometry to derive detectable range of arsenic (III) concentration. The results have showed that the detection limit of this sensing unit is 1 ppb with an excellent linearity of ∼0.99. Keywords: Silver nanoparticles, Polyethylene glycol, Colorimetric, Arsenic (III)http://www.sciencedirect.com/science/article/pii/S2211379718335137
spellingShingle Bijoy Sankar Boruah
Nikhil Kumar Daimari
Rajib Biswas
Functionalized silver nanoparticles as an effective medium towards trace determination of arsenic (III) in aqueous solution
Results in Physics
title Functionalized silver nanoparticles as an effective medium towards trace determination of arsenic (III) in aqueous solution
title_full Functionalized silver nanoparticles as an effective medium towards trace determination of arsenic (III) in aqueous solution
title_fullStr Functionalized silver nanoparticles as an effective medium towards trace determination of arsenic (III) in aqueous solution
title_full_unstemmed Functionalized silver nanoparticles as an effective medium towards trace determination of arsenic (III) in aqueous solution
title_short Functionalized silver nanoparticles as an effective medium towards trace determination of arsenic (III) in aqueous solution
title_sort functionalized silver nanoparticles as an effective medium towards trace determination of arsenic iii in aqueous solution
url http://www.sciencedirect.com/science/article/pii/S2211379718335137
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AT nikhilkumardaimari functionalizedsilvernanoparticlesasaneffectivemediumtowardstracedeterminationofarseniciiiinaqueoussolution
AT rajibbiswas functionalizedsilvernanoparticlesasaneffectivemediumtowardstracedeterminationofarseniciiiinaqueoussolution