Fast Gating for Raman Spectroscopy

Fast gating in Raman spectroscopy is used to reject the fluorescence contribution from the sample and/or the substrate. Several techniques have been set up in the last few decades aiming either to enhance the Raman signal (CARS, SERS or Resonant Raman scattering) or to cancel out the fluorescence co...

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Main Authors: Andrea Chiuri, Federico Angelini
Format: Article
Language:English
Published: MDPI AG 2021-04-01
Series:Sensors
Subjects:
Online Access:https://www.mdpi.com/1424-8220/21/8/2579
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author Andrea Chiuri
Federico Angelini
author_facet Andrea Chiuri
Federico Angelini
author_sort Andrea Chiuri
collection DOAJ
description Fast gating in Raman spectroscopy is used to reject the fluorescence contribution from the sample and/or the substrate. Several techniques have been set up in the last few decades aiming either to enhance the Raman signal (CARS, SERS or Resonant Raman scattering) or to cancel out the fluorescence contribution (SERDS), and a number of reviews have already been published on these sub-topics. However, for many reasons it is sometimes necessary to reject fluorescence in traditional Raman spectroscopy, and in the last few decades a variety of papers dealt with this issue, which is still challenging due to the time scales at stake (down to picoseconds). Fast gating (<1 ns) in the time domain allows one to cut off part of the fluorescence signal and retrieve the best Raman signal, depending on the fluorescence lifetime of the sample and laser pulse duration. In particular, three different techniques have been developed to accomplish this task: optical Kerr cells, intensified Charge Coupling Devices and systems based on Single Photon Avalanche Photodiodes. The utility of time domain fast gating will be discussed, and In this work, the utility of time domain fast gating is discussed, as well as the performances of the mentioned techniques as reported in literature.
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spelling doaj.art-46a85e8bc9d84f30b4ac07c84e0e71772023-11-21T14:28:53ZengMDPI AGSensors1424-82202021-04-01218257910.3390/s21082579Fast Gating for Raman SpectroscopyAndrea Chiuri0Federico Angelini1Diagnostic and Metrology Laboratory, FSN-TECFIS-DIM Nuclear Fusion and Safety Technologies Department, ENEA Via Enrico Fermi 45, 00044 Frascati, ItalyDiagnostic and Metrology Laboratory, FSN-TECFIS-DIM Nuclear Fusion and Safety Technologies Department, ENEA Via Enrico Fermi 45, 00044 Frascati, ItalyFast gating in Raman spectroscopy is used to reject the fluorescence contribution from the sample and/or the substrate. Several techniques have been set up in the last few decades aiming either to enhance the Raman signal (CARS, SERS or Resonant Raman scattering) or to cancel out the fluorescence contribution (SERDS), and a number of reviews have already been published on these sub-topics. However, for many reasons it is sometimes necessary to reject fluorescence in traditional Raman spectroscopy, and in the last few decades a variety of papers dealt with this issue, which is still challenging due to the time scales at stake (down to picoseconds). Fast gating (<1 ns) in the time domain allows one to cut off part of the fluorescence signal and retrieve the best Raman signal, depending on the fluorescence lifetime of the sample and laser pulse duration. In particular, three different techniques have been developed to accomplish this task: optical Kerr cells, intensified Charge Coupling Devices and systems based on Single Photon Avalanche Photodiodes. The utility of time domain fast gating will be discussed, and In this work, the utility of time domain fast gating is discussed, as well as the performances of the mentioned techniques as reported in literature.https://www.mdpi.com/1424-8220/21/8/2579time-gatingRamanICCDKerrSPAD
spellingShingle Andrea Chiuri
Federico Angelini
Fast Gating for Raman Spectroscopy
Sensors
time-gating
Raman
ICCD
Kerr
SPAD
title Fast Gating for Raman Spectroscopy
title_full Fast Gating for Raman Spectroscopy
title_fullStr Fast Gating for Raman Spectroscopy
title_full_unstemmed Fast Gating for Raman Spectroscopy
title_short Fast Gating for Raman Spectroscopy
title_sort fast gating for raman spectroscopy
topic time-gating
Raman
ICCD
Kerr
SPAD
url https://www.mdpi.com/1424-8220/21/8/2579
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