Challenges in Sustainable Degradability of Bio-Based and Oxo-Degradable Packaging Materials during Anaerobic Thermophilic Treatment

Although the manufacturers labelled commercially available bio-based products as biodegradable, there are discrepancies concerning the time frame for their sustainable biodegradation and methane production. Starch-based, polylactic acid-based and oxo-degradable foils were anaerobically treated in th...

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Main Authors: Magdalena Zaborowska, Katarzyna Bernat, Bartosz Pszczółkowski, Irena Wojnowska-Baryła, Dorota Kulikowska
Format: Article
Language:English
Published: MDPI AG 2021-08-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/14/16/4775
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author Magdalena Zaborowska
Katarzyna Bernat
Bartosz Pszczółkowski
Irena Wojnowska-Baryła
Dorota Kulikowska
author_facet Magdalena Zaborowska
Katarzyna Bernat
Bartosz Pszczółkowski
Irena Wojnowska-Baryła
Dorota Kulikowska
author_sort Magdalena Zaborowska
collection DOAJ
description Although the manufacturers labelled commercially available bio-based products as biodegradable, there are discrepancies concerning the time frame for their sustainable biodegradation and methane production. Starch-based, polylactic acid-based and oxo-degradable foils were anaerobically treated in thermophilic condition (55 °C, 100 days). The effect of alkaline pretreatment on foils degradation was also investigated. To examine changes in their mechanical and physical properties, static tensile tests and microscopic analyses, FTIR and surface roughness analyses were conducted. Despite the thermophilic condition, and the longer retention time compared to that needed for biowaste, a small amount of methane was produced with bio-based foils, even after pretreatment (ca. 30 vs. 50 L/kg VS) and foils only lost functional and mechanical properties. The pieces of bio-based materials had only disintegrated, which means that digestate may become contaminated with fragments of these materials. Thus, providing guidelines for bio-based foil treatment remains a challenge in waste management.
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spelling doaj.art-46c2d8e97db9419085424d644073ef392023-11-22T07:27:13ZengMDPI AGEnergies1996-10732021-08-011416477510.3390/en14164775Challenges in Sustainable Degradability of Bio-Based and Oxo-Degradable Packaging Materials during Anaerobic Thermophilic TreatmentMagdalena Zaborowska0Katarzyna Bernat1Bartosz Pszczółkowski2Irena Wojnowska-Baryła3Dorota Kulikowska4Department of Environmental Biotechnology, Faculty of Geoengineering, University of Warmia and Mazury in Olsztyn, 10-719 Olsztyn, PolandDepartment of Environmental Biotechnology, Faculty of Geoengineering, University of Warmia and Mazury in Olsztyn, 10-719 Olsztyn, PolandDepartment of Materials and Machines Technology, University of Warmia and Mazury in Olsztyn, ul. Oczapowskiego 11, 10-719 Olsztyn, PolandDepartment of Environmental Biotechnology, Faculty of Geoengineering, University of Warmia and Mazury in Olsztyn, 10-719 Olsztyn, PolandDepartment of Environmental Biotechnology, Faculty of Geoengineering, University of Warmia and Mazury in Olsztyn, 10-719 Olsztyn, PolandAlthough the manufacturers labelled commercially available bio-based products as biodegradable, there are discrepancies concerning the time frame for their sustainable biodegradation and methane production. Starch-based, polylactic acid-based and oxo-degradable foils were anaerobically treated in thermophilic condition (55 °C, 100 days). The effect of alkaline pretreatment on foils degradation was also investigated. To examine changes in their mechanical and physical properties, static tensile tests and microscopic analyses, FTIR and surface roughness analyses were conducted. Despite the thermophilic condition, and the longer retention time compared to that needed for biowaste, a small amount of methane was produced with bio-based foils, even after pretreatment (ca. 30 vs. 50 L/kg VS) and foils only lost functional and mechanical properties. The pieces of bio-based materials had only disintegrated, which means that digestate may become contaminated with fragments of these materials. Thus, providing guidelines for bio-based foil treatment remains a challenge in waste management.https://www.mdpi.com/1996-1073/14/16/4775biopolymersstarch- and polylactic acid-based materialmethane productionsurface roughnesstensile strengthFTIR and microscopic analyses
spellingShingle Magdalena Zaborowska
Katarzyna Bernat
Bartosz Pszczółkowski
Irena Wojnowska-Baryła
Dorota Kulikowska
Challenges in Sustainable Degradability of Bio-Based and Oxo-Degradable Packaging Materials during Anaerobic Thermophilic Treatment
Energies
biopolymers
starch- and polylactic acid-based material
methane production
surface roughness
tensile strength
FTIR and microscopic analyses
title Challenges in Sustainable Degradability of Bio-Based and Oxo-Degradable Packaging Materials during Anaerobic Thermophilic Treatment
title_full Challenges in Sustainable Degradability of Bio-Based and Oxo-Degradable Packaging Materials during Anaerobic Thermophilic Treatment
title_fullStr Challenges in Sustainable Degradability of Bio-Based and Oxo-Degradable Packaging Materials during Anaerobic Thermophilic Treatment
title_full_unstemmed Challenges in Sustainable Degradability of Bio-Based and Oxo-Degradable Packaging Materials during Anaerobic Thermophilic Treatment
title_short Challenges in Sustainable Degradability of Bio-Based and Oxo-Degradable Packaging Materials during Anaerobic Thermophilic Treatment
title_sort challenges in sustainable degradability of bio based and oxo degradable packaging materials during anaerobic thermophilic treatment
topic biopolymers
starch- and polylactic acid-based material
methane production
surface roughness
tensile strength
FTIR and microscopic analyses
url https://www.mdpi.com/1996-1073/14/16/4775
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AT bartoszpszczołkowski challengesinsustainabledegradabilityofbiobasedandoxodegradablepackagingmaterialsduringanaerobicthermophilictreatment
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