Copper Surface Treatment in Metal-Polymer Direct Molding Technology

The preparation technology of micro-nano structure on copper surface is studied and optimized. Aqueous solution containing sodium carbonate and sodium molybdate is used as electrolyte, and the copper sample is anodized at a constant voltage to form a layer of oxidation on the copper surface. Then, t...

Full description

Bibliographic Details
Main Authors: GUO Rongsheng, HU Guanghong, RONG Jian, WANG Yuanlong
Format: Article
Language:zho
Published: Editorial Office of Journal of Shanghai Jiao Tong University 2021-01-01
Series:Shanghai Jiaotong Daxue xuebao
Subjects:
Online Access:http://xuebao.sjtu.edu.cn/CN/10.16183/j.cnki.jsjtu.2019.185
_version_ 1818978585413681152
author GUO Rongsheng
HU Guanghong
RONG Jian
WANG Yuanlong
author_facet GUO Rongsheng
HU Guanghong
RONG Jian
WANG Yuanlong
author_sort GUO Rongsheng
collection DOAJ
description The preparation technology of micro-nano structure on copper surface is studied and optimized. Aqueous solution containing sodium carbonate and sodium molybdate is used as electrolyte, and the copper sample is anodized at a constant voltage to form a layer of oxidation on the copper surface. Then, the copper surface is treated with aqueous solution containing phosphate and sodium dihydrogen phosphate as corrosion solution to obtain a micro-nano structure on the copper. The surface is observed by using a scanning electron microscope. Finally, the analysis software is used to analyze the scanning electron microscope image to calculate the micro-nano structure pores on the copper surface. The results show that when the anodizing voltage is 15 V, the anodizing time is 20 min, the phosphoric acid mass fraction is 20%, and the corrosion time is 30 min, the copper surface is relatively smooth, and the porosity reaches 25.77%. Orthogonal experiments demonstrate that the type, concentration of the corrosive solution, and etching time have a great effect, while the anodizing electrolyte, voltage and electrolysis have no significant effect on the porosity. Using a combination of anodic oxidation and chemical corrosion, micro and nano junctions with uniform and high porosity can be prepared on the copper surface.
first_indexed 2024-12-20T16:45:58Z
format Article
id doaj.art-46ddab8adea24df78147d8b740fffe01
institution Directory Open Access Journal
issn 1006-2467
language zho
last_indexed 2024-12-20T16:45:58Z
publishDate 2021-01-01
publisher Editorial Office of Journal of Shanghai Jiao Tong University
record_format Article
series Shanghai Jiaotong Daxue xuebao
spelling doaj.art-46ddab8adea24df78147d8b740fffe012022-12-21T19:32:55ZzhoEditorial Office of Journal of Shanghai Jiao Tong UniversityShanghai Jiaotong Daxue xuebao1006-24672021-01-0155019610210.16183/j.cnki.jsjtu.2019.1851006-2467(2021)01-0096-07Copper Surface Treatment in Metal-Polymer Direct Molding TechnologyGUO RongshengHU GuanghongRONG JianWANG YuanlongThe preparation technology of micro-nano structure on copper surface is studied and optimized. Aqueous solution containing sodium carbonate and sodium molybdate is used as electrolyte, and the copper sample is anodized at a constant voltage to form a layer of oxidation on the copper surface. Then, the copper surface is treated with aqueous solution containing phosphate and sodium dihydrogen phosphate as corrosion solution to obtain a micro-nano structure on the copper. The surface is observed by using a scanning electron microscope. Finally, the analysis software is used to analyze the scanning electron microscope image to calculate the micro-nano structure pores on the copper surface. The results show that when the anodizing voltage is 15 V, the anodizing time is 20 min, the phosphoric acid mass fraction is 20%, and the corrosion time is 30 min, the copper surface is relatively smooth, and the porosity reaches 25.77%. Orthogonal experiments demonstrate that the type, concentration of the corrosive solution, and etching time have a great effect, while the anodizing electrolyte, voltage and electrolysis have no significant effect on the porosity. Using a combination of anodic oxidation and chemical corrosion, micro and nano junctions with uniform and high porosity can be prepared on the copper surface.http://xuebao.sjtu.edu.cn/CN/10.16183/j.cnki.jsjtu.2019.185coppersurface treatmentnano injection moldinganodic oxidationmicro-nano structure
spellingShingle GUO Rongsheng
HU Guanghong
RONG Jian
WANG Yuanlong
Copper Surface Treatment in Metal-Polymer Direct Molding Technology
Shanghai Jiaotong Daxue xuebao
copper
surface treatment
nano injection molding
anodic oxidation
micro-nano structure
title Copper Surface Treatment in Metal-Polymer Direct Molding Technology
title_full Copper Surface Treatment in Metal-Polymer Direct Molding Technology
title_fullStr Copper Surface Treatment in Metal-Polymer Direct Molding Technology
title_full_unstemmed Copper Surface Treatment in Metal-Polymer Direct Molding Technology
title_short Copper Surface Treatment in Metal-Polymer Direct Molding Technology
title_sort copper surface treatment in metal polymer direct molding technology
topic copper
surface treatment
nano injection molding
anodic oxidation
micro-nano structure
url http://xuebao.sjtu.edu.cn/CN/10.16183/j.cnki.jsjtu.2019.185
work_keys_str_mv AT guorongsheng coppersurfacetreatmentinmetalpolymerdirectmoldingtechnology
AT huguanghong coppersurfacetreatmentinmetalpolymerdirectmoldingtechnology
AT rongjian coppersurfacetreatmentinmetalpolymerdirectmoldingtechnology
AT wangyuanlong coppersurfacetreatmentinmetalpolymerdirectmoldingtechnology