Alternative green solvents in sample preparation
Sample treatment is one of the most contaminant steps in the analytical process, mainly due to the high consumption of energy and petrol-based organic solvents, which involve a high environmental impact. One of the most promising strategies to reduce the side effects of the analytical methodology co...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
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Elsevier
2022-04-01
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Series: | Green Analytical Chemistry |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2772577422000076 |
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author | Sergio Armenta Francesc A. Esteve-Turrillas Salvador Garrigues Miguel de la Guardia |
author_facet | Sergio Armenta Francesc A. Esteve-Turrillas Salvador Garrigues Miguel de la Guardia |
author_sort | Sergio Armenta |
collection | DOAJ |
description | Sample treatment is one of the most contaminant steps in the analytical process, mainly due to the high consumption of energy and petrol-based organic solvents, which involve a high environmental impact. One of the most promising strategies to reduce the side effects of the analytical methodology consists of the substitution of organic solvents by a greener alternative. Current green solvents such as subcritical water, supercritical fluids, bio-based solvents, such as methanol, ethanol, d-limonene, and cyrene, surfactant-based solutions including supramolecular solvents and hydrotopes, deep eutectic solvents with special emphasis in natural deep eutectic solvents, and ionic liquids have been evaluated as alternatives to conventional solvents and their advantages and drawbacks have been critically highlighted. Moreover, the different ways employed for evaluate their green character has been discussed including life cycle assessment, CO2 emission or CHEM21 selection guide. |
first_indexed | 2024-03-08T11:41:14Z |
format | Article |
id | doaj.art-46ded7c2fd8a452aa8e79c7ab7a6955a |
institution | Directory Open Access Journal |
issn | 2772-5774 |
language | English |
last_indexed | 2024-03-08T11:41:14Z |
publishDate | 2022-04-01 |
publisher | Elsevier |
record_format | Article |
series | Green Analytical Chemistry |
spelling | doaj.art-46ded7c2fd8a452aa8e79c7ab7a6955a2024-01-25T05:24:09ZengElsevierGreen Analytical Chemistry2772-57742022-04-011100007Alternative green solvents in sample preparationSergio Armenta0Francesc A. Esteve-Turrillas1Salvador Garrigues2Miguel de la Guardia3Corresponding author.; Department of Analytical Chemistry, University of Valencia, Jerónimo Muñoz Building, 50th Dr. Moliner St., 46100 Burjassot, SpainDepartment of Analytical Chemistry, University of Valencia, Jerónimo Muñoz Building, 50th Dr. Moliner St., 46100 Burjassot, SpainDepartment of Analytical Chemistry, University of Valencia, Jerónimo Muñoz Building, 50th Dr. Moliner St., 46100 Burjassot, SpainDepartment of Analytical Chemistry, University of Valencia, Jerónimo Muñoz Building, 50th Dr. Moliner St., 46100 Burjassot, SpainSample treatment is one of the most contaminant steps in the analytical process, mainly due to the high consumption of energy and petrol-based organic solvents, which involve a high environmental impact. One of the most promising strategies to reduce the side effects of the analytical methodology consists of the substitution of organic solvents by a greener alternative. Current green solvents such as subcritical water, supercritical fluids, bio-based solvents, such as methanol, ethanol, d-limonene, and cyrene, surfactant-based solutions including supramolecular solvents and hydrotopes, deep eutectic solvents with special emphasis in natural deep eutectic solvents, and ionic liquids have been evaluated as alternatives to conventional solvents and their advantages and drawbacks have been critically highlighted. Moreover, the different ways employed for evaluate their green character has been discussed including life cycle assessment, CO2 emission or CHEM21 selection guide.http://www.sciencedirect.com/science/article/pii/S2772577422000076Green analytical chemistrySample preparationSubcritical waterBio-based solventsIonic liquidsDeep eutectic solvents |
spellingShingle | Sergio Armenta Francesc A. Esteve-Turrillas Salvador Garrigues Miguel de la Guardia Alternative green solvents in sample preparation Green Analytical Chemistry Green analytical chemistry Sample preparation Subcritical water Bio-based solvents Ionic liquids Deep eutectic solvents |
title | Alternative green solvents in sample preparation |
title_full | Alternative green solvents in sample preparation |
title_fullStr | Alternative green solvents in sample preparation |
title_full_unstemmed | Alternative green solvents in sample preparation |
title_short | Alternative green solvents in sample preparation |
title_sort | alternative green solvents in sample preparation |
topic | Green analytical chemistry Sample preparation Subcritical water Bio-based solvents Ionic liquids Deep eutectic solvents |
url | http://www.sciencedirect.com/science/article/pii/S2772577422000076 |
work_keys_str_mv | AT sergioarmenta alternativegreensolventsinsamplepreparation AT francescaesteveturrillas alternativegreensolventsinsamplepreparation AT salvadorgarrigues alternativegreensolventsinsamplepreparation AT migueldelaguardia alternativegreensolventsinsamplepreparation |