Uptake of Hg2+ from aqueous solutions by microporous titano- and zircono-silicates

Being mercury one of the most toxic heavy metals present in the environment, it is of major concern to develop cleanup technologies to remove it from wastewater and recover mercury polluted ecosystems. In this context, we study the potential of some microporous titanosilicates and zirconosilicates f...

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Main Authors: Cláudia B. Lopes, Joana Coimbra, Marta Otero, Eduarda Pereira, Armando C. Duarte, Zhi Lin, João Rocha
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2008-01-01
Series:Química Nova
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000200025
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author Cláudia B. Lopes
Joana Coimbra
Marta Otero
Eduarda Pereira
Armando C. Duarte
Zhi Lin
João Rocha
author_facet Cláudia B. Lopes
Joana Coimbra
Marta Otero
Eduarda Pereira
Armando C. Duarte
Zhi Lin
João Rocha
author_sort Cláudia B. Lopes
collection DOAJ
description Being mercury one of the most toxic heavy metals present in the environment, it is of major concern to develop cleanup technologies to remove it from wastewater and recover mercury polluted ecosystems. In this context, we study the potential of some microporous titanosilicates and zirconosilicates for taking up Hg2+ from aqueous solutions. These materials have unique chemical and physical properties, and here we are able to confirm that they readily remove Hg2+ from aqueous solutions. Moreover, the presence of the competitive Mg2+ and Na+, which are some of the dominant cations in natural waters, does not reduce the uptake capacity of some of these materials. Thus, several inorganic materials reported here may have important environmental applications, efficiently removing Hg2+ from aqueous solutions.
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spelling doaj.art-46defc8328444cdeb564b193546bb6a62022-12-22T02:06:21ZengSociedade Brasileira de QuímicaQuímica Nova0100-40421678-70642008-01-0131232132510.1590/S0100-40422008000200025Uptake of Hg2+ from aqueous solutions by microporous titano- and zircono-silicatesCláudia B. LopesJoana CoimbraMarta OteroEduarda PereiraArmando C. DuarteZhi LinJoão RochaBeing mercury one of the most toxic heavy metals present in the environment, it is of major concern to develop cleanup technologies to remove it from wastewater and recover mercury polluted ecosystems. In this context, we study the potential of some microporous titanosilicates and zirconosilicates for taking up Hg2+ from aqueous solutions. These materials have unique chemical and physical properties, and here we are able to confirm that they readily remove Hg2+ from aqueous solutions. Moreover, the presence of the competitive Mg2+ and Na+, which are some of the dominant cations in natural waters, does not reduce the uptake capacity of some of these materials. Thus, several inorganic materials reported here may have important environmental applications, efficiently removing Hg2+ from aqueous solutions.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000200025mercurytitanosilicateszirconosilicates
spellingShingle Cláudia B. Lopes
Joana Coimbra
Marta Otero
Eduarda Pereira
Armando C. Duarte
Zhi Lin
João Rocha
Uptake of Hg2+ from aqueous solutions by microporous titano- and zircono-silicates
Química Nova
mercury
titanosilicates
zirconosilicates
title Uptake of Hg2+ from aqueous solutions by microporous titano- and zircono-silicates
title_full Uptake of Hg2+ from aqueous solutions by microporous titano- and zircono-silicates
title_fullStr Uptake of Hg2+ from aqueous solutions by microporous titano- and zircono-silicates
title_full_unstemmed Uptake of Hg2+ from aqueous solutions by microporous titano- and zircono-silicates
title_short Uptake of Hg2+ from aqueous solutions by microporous titano- and zircono-silicates
title_sort uptake of hg2 from aqueous solutions by microporous titano and zircono silicates
topic mercury
titanosilicates
zirconosilicates
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000200025
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