Experimental and Modeling Studies on the Correlation Between Auto-Ignition Delays and the Methane Number of Liquefied Natural Gas (LNG) and Liquefied Biogas (LBG)

Liquefied natural gas (LNG) and liquefied biogas (LBG) as transport fuels constitute one of the pillars of the European clean fuel strategy. LNG and LBG often contain higher hydrocarbons up to C5, which leads to more complex ignition properties when utilizing them in gas engines. Therefore, it is es...

Full description

Bibliographic Details
Main Authors: Bo Shu, Sonal K. Vallabhuni, Jiaxin Zheng, Sumit Agarwal, Ravi X. Fernandes
Format: Article
Language:English
Published: Frontiers Media S.A. 2020-07-01
Series:Frontiers in Mechanical Engineering
Subjects:
Online Access:https://www.frontiersin.org/article/10.3389/fmech.2020.00047/full
_version_ 1818510948005052416
author Bo Shu
Sonal K. Vallabhuni
Jiaxin Zheng
Jiaxin Zheng
Sumit Agarwal
Ravi X. Fernandes
Ravi X. Fernandes
author_facet Bo Shu
Sonal K. Vallabhuni
Jiaxin Zheng
Jiaxin Zheng
Sumit Agarwal
Ravi X. Fernandes
Ravi X. Fernandes
author_sort Bo Shu
collection DOAJ
description Liquefied natural gas (LNG) and liquefied biogas (LBG) as transport fuels constitute one of the pillars of the European clean fuel strategy. LNG and LBG often contain higher hydrocarbons up to C5, which leads to more complex ignition properties when utilizing them in gas engines. Therefore, it is essential to understand their combustion behavior and to quantify the abnormal combustion such as knocking propensity in correlation to the methane number (MN). Currently, there is no traceable standard to define the MN, and the literature algorithms give no consistent results for the same LNG/LBG mixtures. In this study, the correlation between the MN and ignition delays of several LNG/LGB mixtures containing C1-C5 alkanes and nitrogen was investigated at temperatures between 870 and 1,550 K, at 10, 20, and 40 bar, and with equivalence ratios of 0.4 and 1.2. Good correlations have been observed for mixtures with MN 50–90 at high temperatures. At intermediate temperatures, discrepancies were found between mixtures with same MN but different C1-C3 compositions. Moreover, the addition of butane and propane isomers at low vol.% showed no effect on the ignition delay times (IDTs) at intermediate temperatures.
first_indexed 2024-12-10T23:26:56Z
format Article
id doaj.art-46e353dd66d14d45b9e4a3b08cf84d9a
institution Directory Open Access Journal
issn 2297-3079
language English
last_indexed 2024-12-10T23:26:56Z
publishDate 2020-07-01
publisher Frontiers Media S.A.
record_format Article
series Frontiers in Mechanical Engineering
spelling doaj.art-46e353dd66d14d45b9e4a3b08cf84d9a2022-12-22T01:29:32ZengFrontiers Media S.A.Frontiers in Mechanical Engineering2297-30792020-07-01610.3389/fmech.2020.00047538170Experimental and Modeling Studies on the Correlation Between Auto-Ignition Delays and the Methane Number of Liquefied Natural Gas (LNG) and Liquefied Biogas (LBG)Bo Shu0Sonal K. Vallabhuni1Jiaxin Zheng2Jiaxin Zheng3Sumit Agarwal4Ravi X. Fernandes5Ravi X. Fernandes6Department of Physical Chemistry, Physikalisch-Technische Bundesanstalt, Braunschweig, GermanyDepartment of Physical Chemistry, Physikalisch-Technische Bundesanstalt, Braunschweig, GermanyDepartment of Physical Chemistry, Physikalisch-Technische Bundesanstalt, Braunschweig, GermanyInstitute of Internal Combustion Engines, Technical University of Braunschweig, Braunschweig, GermanyDepartment of Physical Chemistry, Physikalisch-Technische Bundesanstalt, Braunschweig, GermanyDepartment of Physical Chemistry, Physikalisch-Technische Bundesanstalt, Braunschweig, GermanyInstitute of Internal Combustion Engines, Technical University of Braunschweig, Braunschweig, GermanyLiquefied natural gas (LNG) and liquefied biogas (LBG) as transport fuels constitute one of the pillars of the European clean fuel strategy. LNG and LBG often contain higher hydrocarbons up to C5, which leads to more complex ignition properties when utilizing them in gas engines. Therefore, it is essential to understand their combustion behavior and to quantify the abnormal combustion such as knocking propensity in correlation to the methane number (MN). Currently, there is no traceable standard to define the MN, and the literature algorithms give no consistent results for the same LNG/LBG mixtures. In this study, the correlation between the MN and ignition delays of several LNG/LGB mixtures containing C1-C5 alkanes and nitrogen was investigated at temperatures between 870 and 1,550 K, at 10, 20, and 40 bar, and with equivalence ratios of 0.4 and 1.2. Good correlations have been observed for mixtures with MN 50–90 at high temperatures. At intermediate temperatures, discrepancies were found between mixtures with same MN but different C1-C3 compositions. Moreover, the addition of butane and propane isomers at low vol.% showed no effect on the ignition delay times (IDTs) at intermediate temperatures.https://www.frontiersin.org/article/10.3389/fmech.2020.00047/fullliquefied natural gasliquefied biogasrapid compression machineauto-ignition delayschemical kineticsmodeling
spellingShingle Bo Shu
Sonal K. Vallabhuni
Jiaxin Zheng
Jiaxin Zheng
Sumit Agarwal
Ravi X. Fernandes
Ravi X. Fernandes
Experimental and Modeling Studies on the Correlation Between Auto-Ignition Delays and the Methane Number of Liquefied Natural Gas (LNG) and Liquefied Biogas (LBG)
Frontiers in Mechanical Engineering
liquefied natural gas
liquefied biogas
rapid compression machine
auto-ignition delays
chemical kinetics
modeling
title Experimental and Modeling Studies on the Correlation Between Auto-Ignition Delays and the Methane Number of Liquefied Natural Gas (LNG) and Liquefied Biogas (LBG)
title_full Experimental and Modeling Studies on the Correlation Between Auto-Ignition Delays and the Methane Number of Liquefied Natural Gas (LNG) and Liquefied Biogas (LBG)
title_fullStr Experimental and Modeling Studies on the Correlation Between Auto-Ignition Delays and the Methane Number of Liquefied Natural Gas (LNG) and Liquefied Biogas (LBG)
title_full_unstemmed Experimental and Modeling Studies on the Correlation Between Auto-Ignition Delays and the Methane Number of Liquefied Natural Gas (LNG) and Liquefied Biogas (LBG)
title_short Experimental and Modeling Studies on the Correlation Between Auto-Ignition Delays and the Methane Number of Liquefied Natural Gas (LNG) and Liquefied Biogas (LBG)
title_sort experimental and modeling studies on the correlation between auto ignition delays and the methane number of liquefied natural gas lng and liquefied biogas lbg
topic liquefied natural gas
liquefied biogas
rapid compression machine
auto-ignition delays
chemical kinetics
modeling
url https://www.frontiersin.org/article/10.3389/fmech.2020.00047/full
work_keys_str_mv AT boshu experimentalandmodelingstudiesonthecorrelationbetweenautoignitiondelaysandthemethanenumberofliquefiednaturalgaslngandliquefiedbiogaslbg
AT sonalkvallabhuni experimentalandmodelingstudiesonthecorrelationbetweenautoignitiondelaysandthemethanenumberofliquefiednaturalgaslngandliquefiedbiogaslbg
AT jiaxinzheng experimentalandmodelingstudiesonthecorrelationbetweenautoignitiondelaysandthemethanenumberofliquefiednaturalgaslngandliquefiedbiogaslbg
AT jiaxinzheng experimentalandmodelingstudiesonthecorrelationbetweenautoignitiondelaysandthemethanenumberofliquefiednaturalgaslngandliquefiedbiogaslbg
AT sumitagarwal experimentalandmodelingstudiesonthecorrelationbetweenautoignitiondelaysandthemethanenumberofliquefiednaturalgaslngandliquefiedbiogaslbg
AT ravixfernandes experimentalandmodelingstudiesonthecorrelationbetweenautoignitiondelaysandthemethanenumberofliquefiednaturalgaslngandliquefiedbiogaslbg
AT ravixfernandes experimentalandmodelingstudiesonthecorrelationbetweenautoignitiondelaysandthemethanenumberofliquefiednaturalgaslngandliquefiedbiogaslbg