Analysis of the Corrosion Resistance of Bronze to Aluminium (ASTM B 824) in a Corrosive Environment Controlled with an Artificial Seawater Solution

Abstract This paper presents the analysis of corrosion resistance of bronzes to aluminum in a controlled corrosive environment. Three alloys were studied CuAl4.5; CuAl7,1 and CuAl10,1 (ASTM B824), whose chemical composition was evaluated by spectrometry (OES). To determine its metal phases, chemical...

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Bibliographic Details
Main Authors: C. V. Cargua-López, D. C. Vásconez-Núñez, F. M. Tello-Oquendo
Format: Article
Language:Spanish
Published: Knowledge E 2021-08-01
Series:ESPOCH Congresses
Subjects:
Online Access:https://doi.org/10.18502/espoch.v1i1.9555
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Summary:Abstract This paper presents the analysis of corrosion resistance of bronzes to aluminum in a controlled corrosive environment. Three alloys were studied CuAl4.5; CuAl7,1 and CuAl10,1 (ASTM B824), whose chemical composition was evaluated by spectrometry (OES). To determine its metal phases, chemical attacks were carried out with FeCl3, HCl in 95% Ethanol and FeCl3, HCl, CrO3 in distilled water. The microstructures obtained were characterized by metallography using two microscopes, an optical and a scanning electron (SEM) and the phases obtained were compared. Subsequently, electrochemical corrosion tests were performed on each alloy. The electrolyte used in the tests was artificial seawater (ASTM D1141) with a pH of 10 ± 0.3. Then, the corrosion products were characterized by EDS and SEM. Once the identification phase was over, the products were removed with a 50% HCl solution. Corrosive attack damage in each microstructural matrix was identified and corrosion rates for each alloy were evaluated. Finally, the corrosion rate data were correlated with the Al and Sn percentages of the alloy. The results show that the higher the increase in aluminum, the lower the corrosion rate, for a maximum limit of Al = 10.11%; Sn = 0.13%; CR = 5,170 mpy; In addition, it was shown that these alloys are effective for marine environments with high salinity. The correlation can be used to estimate the corrosion rate for different pH of the electrolytic medium of any type of ferrous or non-ferrous alloy whose variables are dependent on its chemical composition.
ISSN:2789-5009