3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrophenyl)methyl]-5,5-dimethylcyclohex-2-en-1-one
Each of the cyclohexenone rings in the title compound, C23H27NO6, adopts a half-chair (envelope) conformation with the C atom carrying the methyl groups lying out of the plane defined by the five remaining C atoms; the O atoms lie to the same side of the molecule as the respective >C(CH3)...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810040079 |
| _version_ | 1818791673933594624 |
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| author | B. Palakshi Reddy V. Vijayakumar S. Sarveswari Seik Weng Ng Edward R. T. Tiekink |
| author_facet | B. Palakshi Reddy V. Vijayakumar S. Sarveswari Seik Weng Ng Edward R. T. Tiekink |
| author_sort | B. Palakshi Reddy |
| collection | DOAJ |
| description | Each of the cyclohexenone rings in the title compound, C23H27NO6, adopts a half-chair (envelope) conformation with the C atom carrying the methyl groups lying out of the plane defined by the five remaining C atoms; the O atoms lie to the same side of the molecule as the respective >C(CH3)2 atoms. The hydroxy and carbonyl O atoms face each other and are orientated to allow for the formation of two intramolecular O—H...O hydrogen bonds. In the crystal, the presence of C—H...O contacts leads to the formation of supramolecular chains along the b axis. These aggregate into layers that stack along c. |
| first_indexed | 2024-12-18T15:15:06Z |
| format | Article |
| id | doaj.art-46fbe3ec3ee6423091525604b7a6f9a9 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T15:15:06Z |
| publishDate | 2010-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-46fbe3ec3ee6423091525604b7a6f9a92022-12-21T21:03:33ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-11-016611o2806o280710.1107/S16005368100400793-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrophenyl)methyl]-5,5-dimethylcyclohex-2-en-1-oneB. Palakshi ReddyV. VijayakumarS. SarveswariSeik Weng NgEdward R. T. TiekinkEach of the cyclohexenone rings in the title compound, C23H27NO6, adopts a half-chair (envelope) conformation with the C atom carrying the methyl groups lying out of the plane defined by the five remaining C atoms; the O atoms lie to the same side of the molecule as the respective >C(CH3)2 atoms. The hydroxy and carbonyl O atoms face each other and are orientated to allow for the formation of two intramolecular O—H...O hydrogen bonds. In the crystal, the presence of C—H...O contacts leads to the formation of supramolecular chains along the b axis. These aggregate into layers that stack along c.http://scripts.iucr.org/cgi-bin/paper?S1600536810040079 |
| spellingShingle | B. Palakshi Reddy V. Vijayakumar S. Sarveswari Seik Weng Ng Edward R. T. Tiekink 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrophenyl)methyl]-5,5-dimethylcyclohex-2-en-1-one Acta Crystallographica Section E |
| title | 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrophenyl)methyl]-5,5-dimethylcyclohex-2-en-1-one |
| title_full | 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrophenyl)methyl]-5,5-dimethylcyclohex-2-en-1-one |
| title_fullStr | 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrophenyl)methyl]-5,5-dimethylcyclohex-2-en-1-one |
| title_full_unstemmed | 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrophenyl)methyl]-5,5-dimethylcyclohex-2-en-1-one |
| title_short | 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrophenyl)methyl]-5,5-dimethylcyclohex-2-en-1-one |
| title_sort | 3 hydroxy 2 2 hydroxy 4 4 dimethyl 6 oxocyclohex 1 en 1 yl 3 nitrophenyl methyl 5 5 dimethylcyclohex 2 en 1 one |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810040079 |
| work_keys_str_mv | AT bpalakshireddy 3hydroxy22hydroxy44dimethyl6oxocyclohex1en1yl3nitrophenylmethyl55dimethylcyclohex2en1one AT vvijayakumar 3hydroxy22hydroxy44dimethyl6oxocyclohex1en1yl3nitrophenylmethyl55dimethylcyclohex2en1one AT ssarveswari 3hydroxy22hydroxy44dimethyl6oxocyclohex1en1yl3nitrophenylmethyl55dimethylcyclohex2en1one AT seikwengng 3hydroxy22hydroxy44dimethyl6oxocyclohex1en1yl3nitrophenylmethyl55dimethylcyclohex2en1one AT edwardrttiekink 3hydroxy22hydroxy44dimethyl6oxocyclohex1en1yl3nitrophenylmethyl55dimethylcyclohex2en1one |