Synchronous treatment of heavy metal ions and nitrate by nanoscale zero-valent iron (Fe0)(纳米级Fe0同步处理重金属离子与硝酸根的研究)
纳米级零价铁(Fe0)同步处理Cu2+、Ni2+、Cr(VI)等重金属离子和硝酸根的实验中发现,硝酸盐对重金属离子的去除基本无影响,而不同重金属离子则对硝酸盐的去除有不同的影响.同步去除Cu2+和NO3-、Ni2+和NO3-时,与单独去除NO3-相比,Cu2+、Ni2+可以明显地提高硝酸盐的去除率和反应速度,并且Cu2+、Ni2+的初始浓度越高,NO3-的去除效果越好,反应速率常数kobs也越大.纳米级Fe0同步去除Cr(VI)和NO3-时,Cr(VI)阻碍了Fe0还原脱除硝酸盐反应的发生,当Cu2+、Ni2+或Cr(VI)的初始浓度为20 mg • L-1时,纳米级Fe0去除NO3-的反应速...
Main Authors: | , , , , , , |
---|---|
Format: | Article |
Language: | zho |
Published: |
Zhejiang University Press
2008-11-01
|
Series: | Zhejiang Daxue xuebao. Lixue ban |
Subjects: | |
Online Access: | https://doi.org/10.3785/j.issn.1008-9497.2008.06.014 |
_version_ | 1797236129411366912 |
---|---|
author | ZHANGZhen(张珍) HAOZhi-wei(郝志伟) WOJing-jing(沃静静) QIANHui-jing(钱慧静) TONGXin(童新) WUYan-jun(吴燕君) XUXin-hua(徐新华) |
author_facet | ZHANGZhen(张珍) HAOZhi-wei(郝志伟) WOJing-jing(沃静静) QIANHui-jing(钱慧静) TONGXin(童新) WUYan-jun(吴燕君) XUXin-hua(徐新华) |
author_sort | ZHANGZhen(张珍) |
collection | DOAJ |
description | 纳米级零价铁(Fe0)同步处理Cu2+、Ni2+、Cr(VI)等重金属离子和硝酸根的实验中发现,硝酸盐对重金属离子的去除基本无影响,而不同重金属离子则对硝酸盐的去除有不同的影响.同步去除Cu2+和NO3-、Ni2+和NO3-时,与单独去除NO3-相比,Cu2+、Ni2+可以明显地提高硝酸盐的去除率和反应速度,并且Cu2+、Ni2+的初始浓度越高,NO3-的去除效果越好,反应速率常数kobs也越大.纳米级Fe0同步去除Cr(VI)和NO3-时,Cr(VI)阻碍了Fe0还原脱除硝酸盐反应的发生,当Cu2+、Ni2+或Cr(VI)的初始浓度为20 mg • L-1时,纳米级Fe0去除NO3-的反应速率常数kobs分别为0.311 1、0.243 3 min-1和0.036 5 min-1. |
first_indexed | 2024-04-24T16:58:57Z |
format | Article |
id | doaj.art-4702c453611c4181b2e0c4bb98f73c66 |
institution | Directory Open Access Journal |
issn | 1008-9497 |
language | zho |
last_indexed | 2024-04-24T16:58:57Z |
publishDate | 2008-11-01 |
publisher | Zhejiang University Press |
record_format | Article |
series | Zhejiang Daxue xuebao. Lixue ban |
spelling | doaj.art-4702c453611c4181b2e0c4bb98f73c662024-03-29T01:58:26ZzhoZhejiang University PressZhejiang Daxue xuebao. Lixue ban1008-94972008-11-0135664865210.3785/j.issn.1008-9497.2008.06.014Synchronous treatment of heavy metal ions and nitrate by nanoscale zero-valent iron (Fe0)(纳米级Fe0同步处理重金属离子与硝酸根的研究)ZHANGZhen(张珍)0HAOZhi-wei(郝志伟)1WOJing-jing(沃静静)2QIANHui-jing(钱慧静)3TONGXin(童新)4WUYan-jun(吴燕君)5XUXin-hua(徐新华)6 1.Department of Environmental Engineering, Zhejiang University, Hangzhou 310027, China( 1.浙江大学环境工程系,浙江 杭州 310027) 1.Department of Environmental Engineering, Zhejiang University, Hangzhou 310027, China( 1.浙江大学环境工程系,浙江 杭州 310027) 1.Department of Environmental Engineering, Zhejiang University, Hangzhou 310027, China( 1.浙江大学环境工程系,浙江 杭州 310027) 1.Department of Environmental Engineering, Zhejiang University, Hangzhou 310027, China( 1.浙江大学环境工程系,浙江 杭州 310027) 1.Department of Environmental Engineering, Zhejiang University, Hangzhou 310027, China( 1.浙江大学环境工程系,浙江 杭州 310027) 1.Department of Environmental Engineering, Zhejiang University, Hangzhou 310027, China( 1.浙江大学环境工程系,浙江 杭州 310027) 1.Department of Environmental Engineering, Zhejiang University, Hangzhou 310027, China( 1.浙江大学环境工程系,浙江 杭州 310027)纳米级零价铁(Fe0)同步处理Cu2+、Ni2+、Cr(VI)等重金属离子和硝酸根的实验中发现,硝酸盐对重金属离子的去除基本无影响,而不同重金属离子则对硝酸盐的去除有不同的影响.同步去除Cu2+和NO3-、Ni2+和NO3-时,与单独去除NO3-相比,Cu2+、Ni2+可以明显地提高硝酸盐的去除率和反应速度,并且Cu2+、Ni2+的初始浓度越高,NO3-的去除效果越好,反应速率常数kobs也越大.纳米级Fe0同步去除Cr(VI)和NO3-时,Cr(VI)阻碍了Fe0还原脱除硝酸盐反应的发生,当Cu2+、Ni2+或Cr(VI)的初始浓度为20 mg • L-1时,纳米级Fe0去除NO3-的反应速率常数kobs分别为0.311 1、0.243 3 min-1和0.036 5 min-1.https://doi.org/10.3785/j.issn.1008-9497.2008.06.014cu2+ni2+cr(vi)no3-纳米级fe0同步处理 |
spellingShingle | ZHANGZhen(张珍) HAOZhi-wei(郝志伟) WOJing-jing(沃静静) QIANHui-jing(钱慧静) TONGXin(童新) WUYan-jun(吴燕君) XUXin-hua(徐新华) Synchronous treatment of heavy metal ions and nitrate by nanoscale zero-valent iron (Fe0)(纳米级Fe0同步处理重金属离子与硝酸根的研究) Zhejiang Daxue xuebao. Lixue ban cu2+ ni2+ cr(vi) no3- 纳米级fe0 同步处理 |
title | Synchronous treatment of heavy metal ions and nitrate by nanoscale zero-valent iron (Fe0)(纳米级Fe0同步处理重金属离子与硝酸根的研究) |
title_full | Synchronous treatment of heavy metal ions and nitrate by nanoscale zero-valent iron (Fe0)(纳米级Fe0同步处理重金属离子与硝酸根的研究) |
title_fullStr | Synchronous treatment of heavy metal ions and nitrate by nanoscale zero-valent iron (Fe0)(纳米级Fe0同步处理重金属离子与硝酸根的研究) |
title_full_unstemmed | Synchronous treatment of heavy metal ions and nitrate by nanoscale zero-valent iron (Fe0)(纳米级Fe0同步处理重金属离子与硝酸根的研究) |
title_short | Synchronous treatment of heavy metal ions and nitrate by nanoscale zero-valent iron (Fe0)(纳米级Fe0同步处理重金属离子与硝酸根的研究) |
title_sort | synchronous treatment of heavy metal ions and nitrate by nanoscale zero valent iron fe0 纳米级fe0同步处理重金属离子与硝酸根的研究 |
topic | cu2+ ni2+ cr(vi) no3- 纳米级fe0 同步处理 |
url | https://doi.org/10.3785/j.issn.1008-9497.2008.06.014 |
work_keys_str_mv | AT zhangzhenzhāngzhēn synchronoustreatmentofheavymetalionsandnitratebynanoscalezerovalentironfe0nàmǐjífe0tóngbùchùlǐzhòngjīnshǔlíziyǔxiāosuāngēndeyánjiū AT haozhiweihǎozhìwěi synchronoustreatmentofheavymetalionsandnitratebynanoscalezerovalentironfe0nàmǐjífe0tóngbùchùlǐzhòngjīnshǔlíziyǔxiāosuāngēndeyánjiū AT wojingjingwòjìngjìng synchronoustreatmentofheavymetalionsandnitratebynanoscalezerovalentironfe0nàmǐjífe0tóngbùchùlǐzhòngjīnshǔlíziyǔxiāosuāngēndeyánjiū AT qianhuijingqiánhuìjìng synchronoustreatmentofheavymetalionsandnitratebynanoscalezerovalentironfe0nàmǐjífe0tóngbùchùlǐzhòngjīnshǔlíziyǔxiāosuāngēndeyánjiū AT tongxintóngxīn synchronoustreatmentofheavymetalionsandnitratebynanoscalezerovalentironfe0nàmǐjífe0tóngbùchùlǐzhòngjīnshǔlíziyǔxiāosuāngēndeyánjiū AT wuyanjunwúyànjūn synchronoustreatmentofheavymetalionsandnitratebynanoscalezerovalentironfe0nàmǐjífe0tóngbùchùlǐzhòngjīnshǔlíziyǔxiāosuāngēndeyánjiū AT xuxinhuaxúxīnhuá synchronoustreatmentofheavymetalionsandnitratebynanoscalezerovalentironfe0nàmǐjífe0tóngbùchùlǐzhòngjīnshǔlíziyǔxiāosuāngēndeyánjiū |