The Effect of Ultrasonic Treatment on the Binding of the Inclusion Complex β-Cyclodextrin-peppermint Oil with Cellulose Material
The purpose of the research was to measure the increase in the binding of inclusion complexes β-cyclodextrin-peppermint oil (β-CD_PM) to cellulose in cotton and cotton/polyester material with BTCA as the crosslinking agent by applying an ultrasonic bath at room temperature and a frequency of 80 kHz...
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MDPI AG
2022-01-01
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| Online Access: | https://www.mdpi.com/1996-1944/15/2/470 |
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| author | Sandra Flinčec Grgac Jasna Jablan Sara Inić Rajna Malinar Ivančica Kovaček Ivana Čorak |
| author_facet | Sandra Flinčec Grgac Jasna Jablan Sara Inić Rajna Malinar Ivančica Kovaček Ivana Čorak |
| author_sort | Sandra Flinčec Grgac |
| collection | DOAJ |
| description | The purpose of the research was to measure the increase in the binding of inclusion complexes β-cyclodextrin-peppermint oil (β-CD_PM) to cellulose in cotton and cotton/polyester material with BTCA as the crosslinking agent by applying an ultrasonic bath at room temperature and a frequency of 80 kHz for 10 min. After sonication, the samples were left in a bath for 24 h after which they were dried, thermocondensed and subjected to a number of wash cycles. The treated samples were analysed with Attenuated total reflection (ATR) units heated up to 300 °C (Golden Gate (FTIR-ATR)) to monitor chemical changes indicative of crosslinking, while physico-chemical changes in the samples were monitored by using Fourier transform infrared spectroscopy (FTIR-ATR). Mechanical properties were measured according to EN ISO 13934-1:1999, and coloristic changes were evaluated by the whiteness degree according to CIE (WCIE) and the yellowing index (YI), while antimicrobial activity was determined according to AATCC TM 147-2016. The results show a physico-chemical modification of the UZV-treated cellulosic material. Moreover, partial antimicrobial efficacy on Gram-negative bacteria was confirmed for treated fabrics. |
| first_indexed | 2024-03-10T01:04:23Z |
| format | Article |
| id | doaj.art-4716c6cd8c6649d4a2fbb4037e1db0bc |
| institution | Directory Open Access Journal |
| issn | 1996-1944 |
| language | English |
| last_indexed | 2024-03-10T01:04:23Z |
| publishDate | 2022-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Materials |
| spelling | doaj.art-4716c6cd8c6649d4a2fbb4037e1db0bc2023-11-23T14:29:37ZengMDPI AGMaterials1996-19442022-01-0115247010.3390/ma15020470The Effect of Ultrasonic Treatment on the Binding of the Inclusion Complex β-Cyclodextrin-peppermint Oil with Cellulose MaterialSandra Flinčec Grgac0Jasna Jablan1Sara Inić2Rajna Malinar3Ivančica Kovaček4Ivana Čorak5Department of Textile Chemistry and Ecology, Faculty of Textile Technology, University of Zagreb, HR-10000 Zagreb, CroatiaDepartment of Analytical Chemistry, Faculty of Pharmacy and Biochemistry, University of Zagreb, HR-10000 Zagreb, CroatiaDepartment of Textile Chemistry and Ecology, Faculty of Textile Technology, University of Zagreb, HR-10000 Zagreb, CroatiaDepartment of Textile Chemistry and Ecology, Faculty of Textile Technology, University of Zagreb, HR-10000 Zagreb, CroatiaDivision of Food and Consumer Goods Microbiology, Institute of Public Health “Dr. Andrija Štampar”, HR-10000 Zagreb, CroatiaDepartment of Textile Chemistry and Ecology, Faculty of Textile Technology, University of Zagreb, HR-10000 Zagreb, CroatiaThe purpose of the research was to measure the increase in the binding of inclusion complexes β-cyclodextrin-peppermint oil (β-CD_PM) to cellulose in cotton and cotton/polyester material with BTCA as the crosslinking agent by applying an ultrasonic bath at room temperature and a frequency of 80 kHz for 10 min. After sonication, the samples were left in a bath for 24 h after which they were dried, thermocondensed and subjected to a number of wash cycles. The treated samples were analysed with Attenuated total reflection (ATR) units heated up to 300 °C (Golden Gate (FTIR-ATR)) to monitor chemical changes indicative of crosslinking, while physico-chemical changes in the samples were monitored by using Fourier transform infrared spectroscopy (FTIR-ATR). Mechanical properties were measured according to EN ISO 13934-1:1999, and coloristic changes were evaluated by the whiteness degree according to CIE (WCIE) and the yellowing index (YI), while antimicrobial activity was determined according to AATCC TM 147-2016. The results show a physico-chemical modification of the UZV-treated cellulosic material. Moreover, partial antimicrobial efficacy on Gram-negative bacteria was confirmed for treated fabrics.https://www.mdpi.com/1996-1944/15/2/470inclusion complexes β-cyclodextrin-peppermint essential oilcottoncotton/PES1,2,3,4-butane tetra carboxylic acidultrasonic bathFTIR-ATR |
| spellingShingle | Sandra Flinčec Grgac Jasna Jablan Sara Inić Rajna Malinar Ivančica Kovaček Ivana Čorak The Effect of Ultrasonic Treatment on the Binding of the Inclusion Complex β-Cyclodextrin-peppermint Oil with Cellulose Material Materials inclusion complexes β-cyclodextrin-peppermint essential oil cotton cotton/PES 1,2,3,4-butane tetra carboxylic acid ultrasonic bath FTIR-ATR |
| title | The Effect of Ultrasonic Treatment on the Binding of the Inclusion Complex β-Cyclodextrin-peppermint Oil with Cellulose Material |
| title_full | The Effect of Ultrasonic Treatment on the Binding of the Inclusion Complex β-Cyclodextrin-peppermint Oil with Cellulose Material |
| title_fullStr | The Effect of Ultrasonic Treatment on the Binding of the Inclusion Complex β-Cyclodextrin-peppermint Oil with Cellulose Material |
| title_full_unstemmed | The Effect of Ultrasonic Treatment on the Binding of the Inclusion Complex β-Cyclodextrin-peppermint Oil with Cellulose Material |
| title_short | The Effect of Ultrasonic Treatment on the Binding of the Inclusion Complex β-Cyclodextrin-peppermint Oil with Cellulose Material |
| title_sort | effect of ultrasonic treatment on the binding of the inclusion complex β cyclodextrin peppermint oil with cellulose material |
| topic | inclusion complexes β-cyclodextrin-peppermint essential oil cotton cotton/PES 1,2,3,4-butane tetra carboxylic acid ultrasonic bath FTIR-ATR |
| url | https://www.mdpi.com/1996-1944/15/2/470 |
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