dl-Piperidinium-2-carboxylate bis(hydrogen peroxide): unusual hydrogen-bonded peroxide chains
The title compound, C6H11NO2·2H2O2, is the richest (by molar ratio) in hydrogen peroxide among the peroxosolvates of aliphatic α-amino acids. The asymmetric unit contains a zwitterionic pipecolinic acid molecule and two hydrogen peroxide molecules. The two crystallographically independent hydrogen p...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2020-08-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S205698902000972X |
| _version_ | 1818977864105590784 |
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| author | Mger A. Navasardyan Dmitry A. Grishanov Petr V. Prikhodchenko Andrei V. Churakov |
| author_facet | Mger A. Navasardyan Dmitry A. Grishanov Petr V. Prikhodchenko Andrei V. Churakov |
| author_sort | Mger A. Navasardyan |
| collection | DOAJ |
| description | The title compound, C6H11NO2·2H2O2, is the richest (by molar ratio) in hydrogen peroxide among the peroxosolvates of aliphatic α-amino acids. The asymmetric unit contains a zwitterionic pipecolinic acid molecule and two hydrogen peroxide molecules. The two crystallographically independent hydrogen peroxide molecules form a different number of hydrogen bonds: one forms two as donor and two as acceptor ([2,2] mode) and the other forms two as donor and one as acceptor ([2,1] mode). The latter hydrogen peroxide molecule forms infinite hydrogen-bonded hydroperoxo chains running along the c-axis direction, which is unusual for aliphatic α-amino acid peroxosolvates. |
| first_indexed | 2024-12-20T16:34:31Z |
| format | Article |
| id | doaj.art-472db15abb9a4a45933cd3dff37679d0 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-20T16:34:31Z |
| publishDate | 2020-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-472db15abb9a4a45933cd3dff37679d02022-12-21T19:33:11ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902020-08-017681331133510.1107/S205698902000972Xfy2147dl-Piperidinium-2-carboxylate bis(hydrogen peroxide): unusual hydrogen-bonded peroxide chainsMger A. Navasardyan0Dmitry A. Grishanov1Petr V. Prikhodchenko2Andrei V. Churakov3Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii prosp. 31, Moscow 119991, Russian FederationInstitute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii prosp. 31, Moscow 119991, Russian FederationInstitute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii prosp. 31, Moscow 119991, Russian FederationInstitute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii prosp. 31, Moscow 119991, Russian FederationThe title compound, C6H11NO2·2H2O2, is the richest (by molar ratio) in hydrogen peroxide among the peroxosolvates of aliphatic α-amino acids. The asymmetric unit contains a zwitterionic pipecolinic acid molecule and two hydrogen peroxide molecules. The two crystallographically independent hydrogen peroxide molecules form a different number of hydrogen bonds: one forms two as donor and two as acceptor ([2,2] mode) and the other forms two as donor and one as acceptor ([2,1] mode). The latter hydrogen peroxide molecule forms infinite hydrogen-bonded hydroperoxo chains running along the c-axis direction, which is unusual for aliphatic α-amino acid peroxosolvates.http://scripts.iucr.org/cgi-bin/paper?S205698902000972Xperoxosolvatesaliphatic amino acidscharge assisted hydrogen bondsperoxide h-bonded chainscarboxylate anionscrystal structure |
| spellingShingle | Mger A. Navasardyan Dmitry A. Grishanov Petr V. Prikhodchenko Andrei V. Churakov dl-Piperidinium-2-carboxylate bis(hydrogen peroxide): unusual hydrogen-bonded peroxide chains Acta Crystallographica Section E: Crystallographic Communications peroxosolvates aliphatic amino acids charge assisted hydrogen bonds peroxide h-bonded chains carboxylate anions crystal structure |
| title | dl-Piperidinium-2-carboxylate bis(hydrogen peroxide): unusual hydrogen-bonded peroxide chains |
| title_full | dl-Piperidinium-2-carboxylate bis(hydrogen peroxide): unusual hydrogen-bonded peroxide chains |
| title_fullStr | dl-Piperidinium-2-carboxylate bis(hydrogen peroxide): unusual hydrogen-bonded peroxide chains |
| title_full_unstemmed | dl-Piperidinium-2-carboxylate bis(hydrogen peroxide): unusual hydrogen-bonded peroxide chains |
| title_short | dl-Piperidinium-2-carboxylate bis(hydrogen peroxide): unusual hydrogen-bonded peroxide chains |
| title_sort | dl piperidinium 2 carboxylate bis hydrogen peroxide unusual hydrogen bonded peroxide chains |
| topic | peroxosolvates aliphatic amino acids charge assisted hydrogen bonds peroxide h-bonded chains carboxylate anions crystal structure |
| url | http://scripts.iucr.org/cgi-bin/paper?S205698902000972X |
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