Tetraaquabis[4-(pyrazin-2-ylsulfanylmethyl-κN4)benzoato]cobalt(II)
In the title compound, [Co(C12H9N2O2S)2(H2O)4], the CoII ion, lying on an inversion center, has an octahedral coordination involving two N atoms of two 4-(pyrazin-2-ylsulfanylmethyl)benzoate ligands and four water molecules. In the crystal, O—H...O hydrogen bonds between the coordinate...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810037906 |
| _version_ | 1818906284009717760 |
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| author | Fu-An Li |
| author_facet | Fu-An Li |
| author_sort | Fu-An Li |
| collection | DOAJ |
| description | In the title compound, [Co(C12H9N2O2S)2(H2O)4], the CoII ion, lying on an inversion center, has an octahedral coordination involving two N atoms of two 4-(pyrazin-2-ylsulfanylmethyl)benzoate ligands and four water molecules. In the crystal, O—H...O hydrogen bonds between the coordinated water molecules and uncoordinated carboxylate O atoms, and weak π–π interactions [centroid–centroid distance = 4.105 (2) Å] between the benzene and pyrazine rings lead to a three-dimensional supramolecular network. |
| first_indexed | 2024-12-19T21:36:46Z |
| format | Article |
| id | doaj.art-47327cdb1b454099abf7f042d371af76 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T21:36:46Z |
| publishDate | 2010-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-47327cdb1b454099abf7f042d371af762022-12-21T20:04:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-10-016610m1323m132310.1107/S1600536810037906Tetraaquabis[4-(pyrazin-2-ylsulfanylmethyl-κN4)benzoato]cobalt(II)Fu-An LiIn the title compound, [Co(C12H9N2O2S)2(H2O)4], the CoII ion, lying on an inversion center, has an octahedral coordination involving two N atoms of two 4-(pyrazin-2-ylsulfanylmethyl)benzoate ligands and four water molecules. In the crystal, O—H...O hydrogen bonds between the coordinated water molecules and uncoordinated carboxylate O atoms, and weak π–π interactions [centroid–centroid distance = 4.105 (2) Å] between the benzene and pyrazine rings lead to a three-dimensional supramolecular network.http://scripts.iucr.org/cgi-bin/paper?S1600536810037906 |
| spellingShingle | Fu-An Li Tetraaquabis[4-(pyrazin-2-ylsulfanylmethyl-κN4)benzoato]cobalt(II) Acta Crystallographica Section E |
| title | Tetraaquabis[4-(pyrazin-2-ylsulfanylmethyl-κN4)benzoato]cobalt(II) |
| title_full | Tetraaquabis[4-(pyrazin-2-ylsulfanylmethyl-κN4)benzoato]cobalt(II) |
| title_fullStr | Tetraaquabis[4-(pyrazin-2-ylsulfanylmethyl-κN4)benzoato]cobalt(II) |
| title_full_unstemmed | Tetraaquabis[4-(pyrazin-2-ylsulfanylmethyl-κN4)benzoato]cobalt(II) |
| title_short | Tetraaquabis[4-(pyrazin-2-ylsulfanylmethyl-κN4)benzoato]cobalt(II) |
| title_sort | tetraaquabis 4 pyrazin 2 ylsulfanylmethyl amp 954 n4 benzoato cobalt ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810037906 |
| work_keys_str_mv | AT fuanli tetraaquabis4pyrazin2ylsulfanylmethylamp954n4benzoatocobaltii |